离子液体溶解天然高分子材料及绿色纺丝技术研究综述

张锁江; 刘艳荣; 聂毅

doi:10.3969/j.issn.2096-1553.2016.2.001

离子液体溶解天然高分子材料及绿色纺丝技术研究综述

中国科学院过程工程研究所, 中国科学院绿色过程与工程重点实验室, 北京 100090
基金项目: 973国家重点基础研究发展计划项目(2015CB251403)
国家自然科学基金委重大研究计划重点支持项目(91434203)
国家自然科学基金项目(21576262)
2014年中科院"引进杰出技术人才"支持项目
中图分类号: O645.13;O635;TS102

Research review of dissolving natural polymer materials with ionic liquids and green spinning technology

Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100090, China
Received Date: 2016-01-12
Available Online: 2016-03-15
CLC number: O645.13;O635;TS102

摘要: 针对离子液体溶解纤维素、甲壳素/壳聚糖、角蛋白及其他天然高分子化合物的构效关系、溶解机理及纺丝过程的研究现状进行了综述,认为,离子液体在溶解天然高分子材料及干喷湿纺纺丝方面显示出独特的优势,为发展新一代绿色纺丝技术提供了新途径.然而离子液体溶解纺丝要实现大规模工业化应用,尚需解决一些关键问题,如溶解机理的深入研究、功能化离子液体的设计、溶液流变性及可纺性的研究、离子液体的再生纯化等.
- 离子液体 /
- 天然高分子材料 /
- 溶解机理 /
- 干喷湿纺工艺
Abstract: The structure-activity relationship, dissolution mechanism and spinning processes of dissolving cellulose, chitin/chitisan, keratin and other natural spinning polymer materials in ionic liquids (ILs) were reviewed. It was concluded that ILs as a class of green and prominent solvents in dissolving natural spinning polymer materials and dry-jet wet spinning provided a new approach to the new generation of green spinning technology. But in order to realize wide industrial application some key scientific problems of ILs spinning should be solvedincluding thorough research of the dissolution mechanism, further design of the functionalized ILs, exploration of the conditions of rheological properties and spinnability, and the recycling of ILs.
- ionic liquid /
- natural polymer material /
- dissolution mechanism /
- dry jet-wet spinning process
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沈阳化工大学材料科学与工程学院沈阳 110142

离子液体溶解天然高分子材料及绿色纺丝技术研究综述

Research review of dissolving natural polymer materials with ionic liquids and green spinning technology

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通讯作者: 陈斌, bchen63@163.com

离子液体溶解天然高分子材料及绿色纺丝技术研究综述

English Abstract

Research review of dissolving natural polymer materials with ionic liquids and green spinning technology

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离子液体溶解天然高分子材料及绿色纺丝技术研究综述

Research review of dissolving natural polymer materials with ionic liquids and green spinning technology

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通讯作者: 陈斌, bchen63@163.com

离子液体溶解天然高分子材料及绿色纺丝技术研究综述

English Abstract

Research review of dissolving natural polymer materials with ionic liquids and green spinning technology

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