不同类型卷烟纸浆原料的热裂解产物分析

张国强; 毛多斌; 黄朝章; 李跃锋; 张颖璞; 陈笃建

doi:10.3969/j.issn.2096-1553.2017.1.007

CN 41-1437/TS ISSN 2096-1553

不同类型卷烟纸浆原料的热裂解产物分析

张国强 , 毛多斌 , 黄朝章 , 李跃锋 , 张颖璞 , 陈笃建

张国强, 毛多斌, 黄朝章, 等. 不同类型卷烟纸浆原料的热裂解产物分析[J]. 轻工学报, 2017, 32(1): 43-49,102. doi: 10.3969/j.issn.2096-1553.2017.1.007

引用本文: 张国强, 毛多斌, 黄朝章, 等. 不同类型卷烟纸浆原料的热裂解产物分析[J]. 轻工学报, 2017, 32(1): 43-49,102. doi: 10.3969/j.issn.2096-1553.2017.1.007

ZHANG Guo-qiang, MAO Duo-bin, HUANG Chao-zhang, et al. Investigation of the pyrolysis products of different materials of pulp for cigarette paper[J]. Journal of Light Industry, 2017, 32(1): 43-49,102. doi: 10.3969/j.issn.2096-1553.2017.1.007

Citation: ZHANG Guo-qiang, MAO Duo-bin, HUANG Chao-zhang, et al. Investigation of the pyrolysis products of different materials of pulp for cigarette paper[J]. Journal of Light Industry, 2017, 32(1): 43-49,102. doi: 10.3969/j.issn.2096-1553.2017.1.007

不同类型卷烟纸浆原料的热裂解产物分析

郑州轻工业学院食品与生物工程学院, 河南郑州 450001;
福建中烟工业有限责任公司技术中心, 福建厦门 361022

通讯作者: 毛多斌

基金项目: 福建中烟技术中心科技项目（JSZXJH2013024）
中图分类号: TS411.2

Investigation of the pyrolysis products of different materials of pulp for cigarette paper

College of Food and Bioengineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China;
Technology Center, China Tobacco Fujian Industrial Co., Ltd., Xiamen 361022, China

Corresponding author: MAO Duo-bin,

Received Date: 2016-04-25
Available Online: 2017-01-15
CLC number: TS411.2

摘要: 采用热裂解-固相微萃取-气相色谱-质谱法（Py-SPME-GC-MS）分析17种常用卷烟纸浆原料的热裂解产物，在空气气氛中，将浆原料分别在300℃，500℃和700℃条件下热裂解后进行固相微萃取，采用HP-5 MS毛细管色谱柱对热裂解产物进行定性分析.结果表明：随着热裂解温度的升高，阔叶木浆、针叶木浆和麻浆3种纸浆的热解产物种类也随之增加，主要是以醛类、酮类化合物为主；在300℃条件下，阔叶木浆的热裂解产物种类最多（7种）.在500℃条件下，阔叶木浆和麻浆的热裂解产物种类相当（13种）；在700℃条件下，3种纸浆的热裂解产物种类基本相当（≈15种）；同一温度下阔叶木浆热裂解产生的酚类物质、巴豆醛和稠环芳烃类物质最多.
- 卷烟纸 /
- 浆原料 /
- 热裂解
Abstract: The pyrolysis products of different materials of pulp for cigarette paper were investigated by using solid phase micro-extraction(SPEM)coupled with pyrolysis gas chromatography mass spectrometry(Py-GC-MS).In air atmosphere,the pulp was pyrolyzed at 300℃,500℃ and 700℃,respectively.The pyrolysis products were extracted by SPME and introduced into GC-MS with HP-5MS capillary column,and were qualitatively analyzed.The results showed that:with the increasing of the pyrolysis temperatures mentioned,the types of the pyrolysis products of hardwood pulp,softwood pulp and hemp pulp were increased,mainly with aldehydes and ketones compounds.And at 300℃ the type and amount of the pyrolysis products of hardwood pulp were most at different pyrolysis temperatures(7 types).While at 500℃ the pyrolysls products of hardwood pulp were the same in amount with that of hemp pulp(13 types).At 700℃ the pyrolysis products of the 3 types of pulp were about the same in amount (about 15 types).
- cigarette paper /
- materials of pulp /
- pyrolysis
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沈阳化工大学材料科学与工程学院沈阳 110142

张国强, 毛多斌, 黄朝章, 等. 不同类型卷烟纸浆原料的热裂解产物分析[J]. 轻工学报, 2017, 32(1): 43-49,102. doi: 10.3969/j.issn.2096-1553.2017.1.007

引用本文: 张国强, 毛多斌, 黄朝章, 等. 不同类型卷烟纸浆原料的热裂解产物分析[J]. 轻工学报, 2017, 32(1): 43-49,102. doi: 10.3969/j.issn.2096-1553.2017.1.007

不同类型卷烟纸浆原料的热裂解产物分析

通讯作者: 毛多斌

郑州轻工业学院食品与生物工程学院, 河南郑州 450001;
福建中烟工业有限责任公司技术中心, 福建厦门 361022

收稿日期: 2016-04-25
网络出版日期: 2017-01-15

基金项目: 福建中烟技术中心科技项目（JSZXJH2013024）

关键词:

卷烟纸 /
浆原料 /
热裂解

摘要: 采用热裂解-固相微萃取-气相色谱-质谱法（Py-SPME-GC-MS）分析17种常用卷烟纸浆原料的热裂解产物，在空气气氛中，将浆原料分别在300℃，500℃和700℃条件下热裂解后进行固相微萃取，采用HP-5 MS毛细管色谱柱对热裂解产物进行定性分析.结果表明：随着热裂解温度的升高，阔叶木浆、针叶木浆和麻浆3种纸浆的热解产物种类也随之增加，主要是以醛类、酮类化合物为主；在300℃条件下，阔叶木浆的热裂解产物种类最多（7种）.在500℃条件下，阔叶木浆和麻浆的热裂解产物种类相当（13种）；在700℃条件下，3种纸浆的热裂解产物种类基本相当（≈15种）；同一温度下阔叶木浆热裂解产生的酚类物质、巴豆醛和稠环芳烃类物质最多.

English Abstract

Investigation of the pyrolysis products of different materials of pulp for cigarette paper

Corresponding author: MAO Duo-bin,

College of Food and Bioengineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China;
Technology Center, China Tobacco Fujian Industrial Co., Ltd., Xiamen 361022, China

Received Date: 2016-04-25
Available Online: 2017-01-15

Abstract: The pyrolysis products of different materials of pulp for cigarette paper were investigated by using solid phase micro-extraction(SPEM)coupled with pyrolysis gas chromatography mass spectrometry(Py-GC-MS).In air atmosphere,the pulp was pyrolyzed at 300℃,500℃ and 700℃,respectively.The pyrolysis products were extracted by SPME and introduced into GC-MS with HP-5MS capillary column,and were qualitatively analyzed.The results showed that:with the increasing of the pyrolysis temperatures mentioned,the types of the pyrolysis products of hardwood pulp,softwood pulp and hemp pulp were increased,mainly with aldehydes and ketones compounds.And at 300℃ the type and amount of the pyrolysis products of hardwood pulp were most at different pyrolysis temperatures(7 types).While at 500℃ the pyrolysls products of hardwood pulp were the same in amount with that of hemp pulp(13 types).At 700℃ the pyrolysis products of the 3 types of pulp were about the same in amount (about 15 types).

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