JOURNAL OF LIGHT INDUSTRY

CN 41-1437/TS  ISSN 2096-1553

三嗪基共价有机骨架/石墨烯复合材料的合成及其电化学性能研究

孙淑敏 ,  周超 ,  吴琼 ,  王培远

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孙淑敏, 周超, 吴琼, 等. 三嗪基共价有机骨架/石墨烯复合材料的合成及其电化学性能研究[J]. 轻工学报, 2018, 33(1): 43-48. doi: 10.3969/j.issn.2096-1553.2018.01.006
引用本文: 孙淑敏, 周超, 吴琼, 等. 三嗪基共价有机骨架/石墨烯复合材料的合成及其电化学性能研究[J]. 轻工学报, 2018, 33(1): 43-48. doi: 10.3969/j.issn.2096-1553.2018.01.006
shu
SUN Shumin, ZHOU Chao, WU Qiong and et al. Study on synthesis and electrochemical performance of triazine-linked covalent organic framework/graphene composite[J]. Journal of Light Industry, 2018, 33(1): 43-48. doi: 10.3969/j.issn.2096-1553.2018.01.006
Citation: SUN Shumin, ZHOU Chao, WU Qiong and et al. Study on synthesis and electrochemical performance of triazine-linked covalent organic framework/graphene composite[J]. Journal of Light Industry, 2018, 33(1): 43-48. doi: 10.3969/j.issn.2096-1553.2018.01.006
shu

三嗪基共价有机骨架/石墨烯复合材料的合成及其电化学性能研究

  • 郑州轻工业学院 材料与化学工程学院, 河南 郑州 450001

  • 基金项目: 国家自然科学基金项目（21301159）；河南省教育厅重点项目（15A150083）

  • 中图分类号: O631.1

Study on synthesis and electrochemical performance of triazine-linked covalent organic framework/graphene composite

  • College of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China

  • Received Date: 2017-09-20
    Available Online: 2018-01-15

    CLC number: O631.1

  • 摘要: 以对苯二腈、氧化石墨烯（GO）为原料，通过简单离子热的方法合成三嗪基共价有机骨架/石墨烯（CTFs/G）复合材料，并将其用作超级电容器电极材料，通过电化学工作站对其电化学性能进行了分析.结果表明：CTFs/G复合材料具有较好的倍率特性，表现出优良的电化学性能，在0.2 A/g的电流密度下，其比电容可以达到372 F/g，高于CTFs材料的166 F/g，经1000次循环后其比电容仍维持在168 F/g，循环稳定性较好.
    Abstract: With phthalonitrile,graphene oxide(GO) as raw material,triazine-linked covalent organic framework/graphene composite was synthesized by a simple ion thermal method.As supercapacitor electrode material,the electrochemical performance of the CTFs/G composites was analyzed by electrochemical workstation. The results showed that the CTFs/G composites had good rate capability and excellent electrochemical performance.The composites displayed specific capacitance of 372 F/g at current density of 0.2 A/g,which is much higher than that of pure CTFs (166 F/g).It could be remained at 168 F/g after 1000 cycles,and the cycle stablity was good.
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  • 收稿日期:  2017-09-20
  • 刊出日期:  2018-01-15
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孙淑敏, 周超, 吴琼, 等. 三嗪基共价有机骨架/石墨烯复合材料的合成及其电化学性能研究[J]. 轻工学报, 2018, 33(1): 43-48. doi: 10.3969/j.issn.2096-1553.2018.01.006
引用本文: 孙淑敏, 周超, 吴琼, 等. 三嗪基共价有机骨架/石墨烯复合材料的合成及其电化学性能研究[J]. 轻工学报, 2018, 33(1): 43-48. doi: 10.3969/j.issn.2096-1553.2018.01.006
shu
SUN Shumin, ZHOU Chao, WU Qiong and et al. Study on synthesis and electrochemical performance of triazine-linked covalent organic framework/graphene composite[J]. Journal of Light Industry, 2018, 33(1): 43-48. doi: 10.3969/j.issn.2096-1553.2018.01.006
Citation: SUN Shumin, ZHOU Chao, WU Qiong and et al. Study on synthesis and electrochemical performance of triazine-linked covalent organic framework/graphene composite[J]. Journal of Light Industry, 2018, 33(1): 43-48. doi: 10.3969/j.issn.2096-1553.2018.01.006
shu

三嗪基共价有机骨架/石墨烯复合材料的合成及其电化学性能研究

  • 郑州轻工业学院 材料与化学工程学院, 河南 郑州 450001
  • 收稿日期: 2017-09-20
  • 网络出版日期: 2018-01-15
基金项目:  国家自然科学基金项目（21301159）；河南省教育厅重点项目（15A150083）

摘要: 以对苯二腈、氧化石墨烯（GO）为原料，通过简单离子热的方法合成三嗪基共价有机骨架/石墨烯（CTFs/G）复合材料，并将其用作超级电容器电极材料，通过电化学工作站对其电化学性能进行了分析.结果表明：CTFs/G复合材料具有较好的倍率特性，表现出优良的电化学性能，在0.2 A/g的电流密度下，其比电容可以达到372 F/g，高于CTFs材料的166 F/g，经1000次循环后其比电容仍维持在168 F/g，循环稳定性较好.

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