JOURNAL OF LIGHT INDUSTRY

CN 41-1437/TS  ISSN 2096-1553

基于非共价键作用构筑的白光凝胶研究进展

樊凯奇 苏振宁 王书元 赵帅 韩光鲁 余述燕 张宝浩 尹志刚 宋健

樊凯奇, 苏振宁, 王书元, 等. 基于非共价键作用构筑的白光凝胶研究进展[J]. 轻工学报, 2018, 33(1): 56-71. doi: 10.3969/j.issn.2096-1553.2018.01.008
引用本文: 樊凯奇, 苏振宁, 王书元, 等. 基于非共价键作用构筑的白光凝胶研究进展[J]. 轻工学报, 2018, 33(1): 56-71. doi: 10.3969/j.issn.2096-1553.2018.01.008
FAN Kaiqi, SU Zhenning, WANG Shuyuan, et al. Research progress of white light gel construction based on non-covalent bond[J]. Journal of Light Industry, 2018, 33(1): 56-71. doi: 10.3969/j.issn.2096-1553.2018.01.008
Citation: FAN Kaiqi, SU Zhenning, WANG Shuyuan, et al. Research progress of white light gel construction based on non-covalent bond[J]. Journal of Light Industry, 2018, 33(1): 56-71. doi: 10.3969/j.issn.2096-1553.2018.01.008

基于非共价键作用构筑的白光凝胶研究进展

  • 基金项目: 国家自然科学基金项目(21276188,21606211);河南省高等学校重点科研项目(16A530010);郑州轻工业学院科研基金项目(2015XJJZ032);郑州轻工业学院博士基金项目(2014BSJJ061)

  • 中图分类号: O645

Research progress of white light gel construction based on non-covalent bond

  • Received Date: 2017-11-30
    Available Online: 2018-01-15

    CLC number: O645

  • 摘要: 从白光凝胶形成的作用方式出发,综述了以氢键作用、π-π堆积作用和金属配位作用等非共价作用来构筑白光凝胶的研究现状,指出,基于非共价键作用构筑的白光凝胶可使不同发色团化合物产生动态和可逆的一维组装,自组装形成的聚集体有助于调节供、受体分子间的距离和偶极方向,提高分子间的能量转移效率,获得可调控的白光凝胶发射材料,该白光凝胶具有对外界明显的刺激响应特性和灵活的相转变过程,以及良好的可塑加工性,在显示材料、照明设备等领域有巨大的潜在应用前景.然而,已经获得的白光凝胶体系存在着在强机械力或高温下会被破坏、凝胶强度低、干凝胶的制备周期长等问题,未来应加强凝胶因子结构和供、受体能量转移效率之间的构效关系研究,以促进白光凝胶工业化应用的尽早实现.
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  • 收稿日期:  2017-11-30
  • 刊出日期:  2018-01-15
通讯作者: 陈斌, bchen63@163.com
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樊凯奇, 苏振宁, 王书元, 等. 基于非共价键作用构筑的白光凝胶研究进展[J]. 轻工学报, 2018, 33(1): 56-71. doi: 10.3969/j.issn.2096-1553.2018.01.008
引用本文: 樊凯奇, 苏振宁, 王书元, 等. 基于非共价键作用构筑的白光凝胶研究进展[J]. 轻工学报, 2018, 33(1): 56-71. doi: 10.3969/j.issn.2096-1553.2018.01.008
FAN Kaiqi, SU Zhenning, WANG Shuyuan, et al. Research progress of white light gel construction based on non-covalent bond[J]. Journal of Light Industry, 2018, 33(1): 56-71. doi: 10.3969/j.issn.2096-1553.2018.01.008
Citation: FAN Kaiqi, SU Zhenning, WANG Shuyuan, et al. Research progress of white light gel construction based on non-covalent bond[J]. Journal of Light Industry, 2018, 33(1): 56-71. doi: 10.3969/j.issn.2096-1553.2018.01.008

基于非共价键作用构筑的白光凝胶研究进展

  • 郑州轻工业学院 材料与化学工程学院, 河南 郑州 450001;
  • 天津大学 化工学院, 天津 300072
基金项目:  国家自然科学基金项目(21276188,21606211);河南省高等学校重点科研项目(16A530010);郑州轻工业学院科研基金项目(2015XJJZ032);郑州轻工业学院博士基金项目(2014BSJJ061)

摘要: 从白光凝胶形成的作用方式出发,综述了以氢键作用、π-π堆积作用和金属配位作用等非共价作用来构筑白光凝胶的研究现状,指出,基于非共价键作用构筑的白光凝胶可使不同发色团化合物产生动态和可逆的一维组装,自组装形成的聚集体有助于调节供、受体分子间的距离和偶极方向,提高分子间的能量转移效率,获得可调控的白光凝胶发射材料,该白光凝胶具有对外界明显的刺激响应特性和灵活的相转变过程,以及良好的可塑加工性,在显示材料、照明设备等领域有巨大的潜在应用前景.然而,已经获得的白光凝胶体系存在着在强机械力或高温下会被破坏、凝胶强度低、干凝胶的制备周期长等问题,未来应加强凝胶因子结构和供、受体能量转移效率之间的构效关系研究,以促进白光凝胶工业化应用的尽早实现.

English Abstract

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