TiAl合金熔体与铸型界面反应研究进展

樊江磊; 梁柳博; 李莹; 王艳; 吴深; 周向葵; 高红霞; 刘建秀

doi:10.12187/2020.06.009

TiAl合金熔体与铸型界面反应研究进展

郑州轻工业大学机电工程学院, 河南郑州 450002

作者简介: 樊江磊(1983-),男,河南省南阳市人,郑州轻工业大学副教授,博士,主要研究方向为金属材料成型与凝固技术.;

基金项目: 国家自然科学基金项目（51501167，U1904175）；2018年度河南省高等学校青年骨干教师培养计划项目（2018GGJS090）；河南省研究生教育改革与质量提升工程项目（YJS2021AL026）；郑州市重大科技创新专项项目（2019CXZX0065）
中图分类号: TG146.23

Research status of interfacial reaction between TiAl alloy melt and mold materials

College of Mechanical and Electrical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, China
Received Date: 2020-05-06

CLC number: TG146.23

摘要: 通过对精密铸造及定向凝固TiAl合金与型壳材料界面反应的研究现状进行综述，指出石墨型壳、高熔点金属型壳、氧化物型壳、锆酸盐型壳与熔融TiAl合金之间的反应机理及相互作用程度：石墨型壳界面反应程度较剧烈，C污染严重；高熔点金属型壳制备成本较高，实际使用中对环境条件要求苛刻；氧化物型壳材料来源广泛，相对成本较低，对比常用的CaO、Al₂O₃、ZrO₂型壳，Y₂O₃型壳与熔融TiAl合金界面反应程度最微弱；锆酸盐型壳界面反应程度较微弱，展现出相当大的应用潜力.未来应重点研究氧化物型壳和锆酸盐型壳在铸造TiAl合金领域的应用，可侧重于改良型壳材料的内部构造、开发更为稳定的粘接剂材料等方面.
- TiAl合金 /
- 铸型材料 /
- 界面反应 /
- 定向凝固
Abstract: By reviewing the current research status of the interface reaction between the precision casting and directionally solidified TiAl alloy and the shell material, it was pointed out that the reaction mechanism and degree of interaction between graphite shell, high melting point metal shell, oxide shell, zirconate shell and molten TiAl alloy were as follows: The graphite shell had more severe interface reactions and serious C pollution; the preparation cost of high melting point metal shells was relatively high, and its actual use required harsh environmental conditions; oxide shell materials had a wide range of sources and relatively low cost. Compared with the commonly used CaO, Al₂O₃, and ZrO₂ shells, the interface reaction between the Y₂O₃ shell and the molten TiAl alloy was the weakest; the zirconate shell had a weaker interface reaction, showing considerable application potential. In the future, the application of oxide shells and zirconate shells in the field of cast TiAl alloys should be researched.Focus could be put on optimizing the structure of the shell materials and developing more stable adhesive materials.
- TiAl alloy /
- mold material /
- interfacial reaction /
- directional solidification
1. [1]
  LORIA E A.Gamma titanium aluminides as prospective structural materials[J].Intermetallics,2000,8(9/10/11):1339.
2. [2]
  YOO M H,FU C L,LEE J K.Deformation twinning in metals and ordered intermetallics-Ti and Ti-aluminides[J].Journal de Physique Ⅲ,1991,1(6):1065.
3. [3]
  GNANAMOORTHY R,MUTOH Y,MASAHASHI N,et al.High-temperature strength and fracture toughness in γ-phase titanium aluminides[J].Journal of Materials Science,1993,28(24):6631.
4. [4]
  HAMZAH E,KANNIAH M,HARUN M.Effect of beta phase on room to high temperature mechanical properties of as-cast gamma titanium aluminide[J].Mechanics of Advanced Materials and Structures,2009,16(5):384.
5. [5]
  PLANCK S K,ROSENBERGER A H.The influence of high temperature exposure on the mechanical performance of a γ titanium aluminide alloy[J].Materials Science and Engineering(A),2002,325(1/2):270.
6. [6]
  李中权,肖旅,李宝辉,等.航天先进轻合金材料及成形技术研究综述[J].上海航天,2019,36(2):9.
7. [7]
  MCCULLOUGH C,VALENCIA J J,LEVI C G,et al.Phase equilibria and solidification in Ti-Al alloys[J].Acta Metallurgica,1989,37(5):1321.
8. [8]
  TSUYAMA S,MITAO S,MINAKAWA K.Alloy modification of γ-base titanium aluminide for improved oxidation resistance,creep strength and fracture toughness[J].Materials Science and Engineering(A),1992,153(1/2):451.
9. [9]
  DIMIDUK D M.Gamma titanium aluminide alloys:An assessment within the competition of aerospace structural materials[J].Materials Science and Engineering(A),1999,263(2):281.
10. [10]
  KISHIDA K,INUI H,YAMAGUCHI M.Deformation of lamellar structure in TiAl-Ti₃Al two-phase alloys[J].Philosophical Magazine A,1998,78(1):1.
11. [11]
  傅恒志,丁宏升,陈瑞润,等.钛铝合金电磁冷坩埚定向凝固技术的研究[J].稀有金属材料与工程,2008,37(4):565.
12. [12]
  苏鹏,刘鸿羽,赵军,等.钛合金熔模铸造型壳制备技术研究现状[J].铸造,2012,61(12):1401.
13. [13]
  BARBOSA J J,RIBEIRO C S.Influence of crucible material on the level of contamination in TiAl using induction melting[J].International Journal of Cast Metals Research,2000,12(5):293.
14. [14]
  EGAN T,SZURMAN I,KURSA M,et al.Preparation of TiAl-based alloys by induction melting in graphite crucibles[J].Kovove Materialy,2015,53(2):69.
15. [15]
  KAMYSHNYKOVA K,LAPIN J.Vacuum induction melting and solidification of TiAl-based alloy in graphite crucibles[J].Vacuum,2018,154:218.
16. [16]
  罗文忠,沈军,闵志先,等.TiAl合金定向凝固过程中与坩埚材料的界面反应研究[J].稀有金属材料与工程,2009,38(8):1441.
17. [17]
  PERDRIX F,TRICHET M F,BONNENTIEN J L,et al.Relationships between interstitial content,microstructure and mechanical properties in fully lamellar Ti-48Al alloys,with special reference to carbon[J].Intermetallics,2001,9(9):807.
18. [18]
  MCCULLOUGH C,VALENCIA J J,LEVI C G,et al.Microstructural analysis of rapidly solidified Ti-Al-X powders[J].Materials Science and Engineering(A),1990,124(1):83.
19. [19]
  BROWN R A,BROWN C A.Investment shell molds for the high integrity precision casting of reactive and refractory metals,and methods for their manufacture:US3537949A[P].1970-11-03[2020-03-10].
20. [20]
  BROWN R A.Investment shell mold,for use in casting of reacting and refractory metals:US3994346[P].1976-11-30[2020-03-15].
21. [21]
  DONACHIE M J.Titanium:A technical guide[M].New York:The Materials Information Society,2000:41.
22. [22]
  刘爱辉.钛合金熔体与陶瓷铸型界面反应规律及微观机理研究[D].哈尔滨:哈尔滨工业大学,2007.
23. [23]
  JIA Q,CUI Y Y,YANG R.Intensified interfacial reactions between gamma titanium aluminide and CaO stabilised ZrO₂[J].International Journal of Cast Metals Research,2004,17(1):23.
24. [24]
  ZHU Y,YANG Y Q,SUN J.Calculation of activity coefficients for components in ternary Ti alloys and intermetallics as matrix of composites[J].Transactions of Nonferrous Metals Society of China,2004,14(5):875.
25. [25]
  DING X,FAN P,HAN Q Y.Models of activity and activity interaction parameter in ternary metallic melt[J].Acta Metallrugica Sinica,1994,30(14):49.
26. [26]
  KOSTOV A,FRIEDRICH B.Predicting thermodynamic stability of crucible oxides in molten titanium and titanium alloys[J].Computational Materials Science,2006,38(2):374.
27. [27]
  崔仁杰.TiAl合金与氧化钇耐火材料的相互作用规律及微观机理研究[D].北京:北京航空航天大学,2011.
28. [28]
  KUANG J P,HARDING R A,CAMPBELL J.Investigation into refractories as crucible and mould materials for melting and casting γ-TiAl alloys[J].Materials Science and Technology,2000,16(9):1007.
29. [29]
  LASALLE J C,FANELLI A J,BARRY E J,et al.Inert calcia facecoats for investment casting of titanium and titanium-aluminide alloys:US5766329[P].1998-06-16[2020-04-18].
30. [30]
  LIU K,MA Y C,GAO M,et al.Single step centrifugal casting TiAl automotive valves[J].Intermetallics,2005,13(9):925.
31. [31]
  CHEN B,MA Y C,GAO M,et al.Changes of oxygen content in molten TiAl alloys as a function of superheat during vacuum induction melting[J].Journal of Materials Science & Technology,2010,26(10):900.
32. [32]
  GOMES F,BARBOSA J,RIBEIRO C S.Induction melting of γ-TiAl in CaO crucibles[J].Intermetallics,2008,16(11/12):1292.
33. [33]
  FU B G,WANG H W,ZOU C M,et al.Interfacial reactions between Ti-1100 alloy and CaO crucible during casting process[J].Transactions of Nonferrous Metals Society of China,2014,24(10):3118.
34. [34]
  KUANG J P,HARDING R A,CAMPBELL J.A study of refractories as crucible and mould materials for melting and casting γ-TiAl alloys[J].International Journal of Cast Metals Research,2001,13(5):277.
35. [35]
  LIN X D,XUE X Y,ZHONG H,et al.Interface reaction between ceramic moulds and high Nb-TiAl alloys[J].Rare Metal Materials and Engineering,2013,42(8):1568.
36. [36]
  CHENG X,YUAN C,SHEVCHENKO D,et al.The influence of mould pre-heat temperature and casting size on the interaction between a Ti-46Al-8Nb-1B alloy and the mould comprising an Al₂O₃ face coat[J].Materials Chemistry and Physics,2014,146(3):295.
37. [37]
  王家芳,王健农,杨杰.TiAl基合金与陶瓷界面反应的研究[J].特种铸造及有色合金,2002(5):40.
38. [38]
  SUNG S Y,KIM Y J.Alpha-case formation mechanism on titanium investment castings[J].Materials Science and Engineering(A),2005,405(1/2):173.
39. [39]
  FAN J L,GUO J J,WANG S Y,et al.Microstructure evolution and interfacial reaction of TiAl-Si alloy solidified in alumina crucible[J].Materials Science and Technology,2015,31(14):1727.
40. [40]
  ZHANG H R,TANG X X,ZHOU C G,et al.Comparison of directional solidification of γ-TiAl alloys in conventional Al₂O₃ and novel Y₂O₃-coated Al₂O₃ crucibles[J].Journal of the European Ceramic Society,2013,33(5):925.
41. [41]
  ZHANG H R,TANG X X,ZHOU L,et al.Interactions between Ni-44Ti-5Al-2Nb-Mo alloy and oxide ceramics during directional solidification process[J].Journal of Materials Science,2012,47(17):6451.
42. [42]
  蒋海燕,李邦盛,李志强,等.液钛与氧化锆陶瓷型壳的相互作用[J].中国有色金属学报,1999,9(2):65.
43. [43]
  李邦盛,蒋海燕,李志强,等.钛合金熔模精铸氧化锆陶瓷型壳/金属界面反应研究[J].航空材料学报,1999(2):45.
44. [44]
  JIA Q,CUI Y Y,YANG R.A study of two refractories as mould materials for investment casting TiAl based alloys[J].Journal of Materials Science,2006,41(10):3045.
45. [45]
  刘爱辉,李邦盛,南海,等.TiAl基合金熔体与氧化物铸型界面的相互作用[J].稀有金属材料与工程,2007,36(11):1975.
46. [46]
  隋艳伟,程成,冯坤,等.定向凝固钛铝合金熔体与铸型界面反应研究展望[J].材料科学与工艺,2016,24(2):91.
47. [47]
  CUI Y S,TANG X X,GAO M,et al.Interactions between TiAl alloy and different oxide moulds under high-temperature and long-time condition[J].High Temperature Materials and Processes,2013,32(3):295.
48. [48]
  SAARI H,BEDDOES J,SEO D Y,et al.Development of directionally solidified γ-TiAl structures[J].Intermetallics,2005,13(9):937.
49. [49]
  BARBOSA J,RIBEIRO C S,MONTEIRO A C.Influence of superheating on casting of γ-TiAl[J].Intermetallics,2007,15(7):945.
50. [50]
  CUI R J,GAO M,ZHANG H,et al.Interactions between TiAl alloys and yttria refractory material in casting process[J].Journal of Materials Processing Technology,2010,210(9):1190.
51. [51]
  张花蕊,高明,唐晓霞,等.定向凝固过程中Ti-47Al-2Cr-2Nb合金与Y₂O₃陶瓷的相互作用[J].金属学报,2010,46(7):890.
52. [52]
  KIM M G,KIM S K,KIM Y J.Effect of mold material and binder on metal-mold interfacial reaction for investment castings of titanium alloys[J].Materials Transactions,2002,43(4):745.
53. [53]
  KIM S K,KIM T K,KIM M G,et al.Investment casting of titanium alloys with CaO Crucible and CaZrO₃ mold[M]//JATA K,LEE E W,FRAZIER W F,et al.Lightweight alloys for aerospace application.[S.l:s.n.],2001:251-260.
54. [54]
  SCHAFFÖNER S,ANEZIRIS C G,BEREK H,et al.Corrosion behavior of calcium zirconate refractories in contact with titanium aluminide melts[J].Journal of the European Ceramic Society,2015,35(3):1097.
55. [55]
  KLOTZ U E,LEGNER C,BULLING F,et al.Investment casting of titanium alloys with calcium zirconate moulds and crucibles[J].The International Journal of Advanced Manufacturing Technology,2019,103:343.
56. [56]
  LI K,XIONG F H,CHEN G Y,et al.Directional solidification of Ti-46Al-8Nb alloy in BaZrO₃ coated Al₂O₃ composite mould[J].Intermetallics,2018,102:106.
57. [57]
  CHEN G Y,KANG J Y,GAO P Y,et al.Effect of CaO additive on the interfacial reaction between the BaZrO₃ refractory and titanium enrichment melt[C]//Proceedings of TMS Annual Meeting & Exhibition.Heidelberg:Springer,2018:235-244.
58. [58]
  张钊,朱凯亮,刘岚洁,等.BaZrO₃坩埚的制备及与钛合金熔体的界面反应[J].硅酸盐学报,2013,41(9):1278.
59. [59]
  贺进,魏超,李明阳,等.BaZrO₃耐火材料与TiAl合金熔体的界面反应[J].中国有色金属学报,2015,25(6):1505.
60. [60]
  CHEN G Y,LAN B B,XIONG F H,et al.Pilot-scale experimental evaluation of induction melting of Ti-46Al-8Nb alloy in the fused BaZrO₃ crucible[J].Vacuum,2019,159:293.
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沈阳化工大学材料科学与工程学院沈阳 110142

TiAl合金熔体与铸型界面反应研究进展

作者简介: 樊江磊(1983-),男,河南省南阳市人,郑州轻工业大学副教授,博士,主要研究方向为金属材料成型与凝固技术.;

Research status of interfacial reaction between TiAl alloy melt and mold materials

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通讯作者: 陈斌, bchen63@163.com

TiAl合金熔体与铸型界面反应研究进展

作者简介:樊江磊(1983-),男,河南省南阳市人,郑州轻工业大学副教授,博士,主要研究方向为金属材料成型与凝固技术.

English Abstract

Research status of interfacial reaction between TiAl alloy melt and mold materials

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TiAl合金熔体与铸型界面反应研究进展

作者简介: 樊江磊(1983-),男,河南省南阳市人,郑州轻工业大学副教授,博士,主要研究方向为金属材料成型与凝固技术.;

Research status of interfacial reaction between TiAl alloy melt and mold materials

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通讯作者: 陈斌, bchen63@163.com

TiAl合金熔体与铸型界面反应研究进展

作者简介:樊江磊(1983-),男,河南省南阳市人,郑州轻工业大学副教授,博士,主要研究方向为金属材料成型与凝固技术.

English Abstract

Research status of interfacial reaction between TiAl alloy melt and mold materials

目录