JOURNAL OF LIGHT INDUSTRY

CN 41-1437/TS  ISSN 2096-1553

Volume 36 Issue 6
December 2021
Article Contents
CHEN Fenghua, SHI Xiangdong, LIANG Weiwei, et al. Study on the synthesis of CC/TiO2/Ag@AgCl composite material and its photocatalytic performance[J]. Journal of Light Industry, 2021, 36(6): 91-101,109. doi: 10.12187/2021.06.011
Citation: CHEN Fenghua, SHI Xiangdong, LIANG Weiwei, et al. Study on the synthesis of CC/TiO2/Ag@AgCl composite material and its photocatalytic performance[J]. Journal of Light Industry, 2021, 36(6): 91-101,109. doi: 10.12187/2021.06.011 shu

Study on the synthesis of CC/TiO2/Ag@AgCl composite material and its photocatalytic performance

  • Received Date: 2021-06-10
  • With carbon cloth (CC) as a substrate, the composite of CC/TiO2/Ag@AgCl was successfully prepared via a successive chemically coupled method, in-situ deposition method and the followed photogenic reduction method. The adsorption-photocatalytic degradation activities and the photoelectric properties of CC/TiO 2/Ag@AgCl were further studied. The results indicated that 96. 9% of RhB could be captured and degraded in the presence of CC/TiO2/Ag@AgCl composites under 120 min UV-vis irradiation, which was higher than those of pure TiO2(83. 8%) and Ag@AgCl (78. 6%). It was verified that CC/TiO2/Ag@AgCl catalyst broadened the light absorption range and showed more efficient photocarrier separation and transfer efficiency, which was beneficial to inhibit the electron-hole pair recombination and the improvement of photocatalytic activity. The capture of active pieces experiments indicated that the free ·OH radicals and ·O2- radicals were the main active oxidizing species involved in the RhB photoreaction process of CC/TiO2/Ag@AgCl.
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    1. [1]

      LI C,YANG W Y,LI Q. TiO2-based photocatalysts prepared by oxidation of TiN nanoparticles and their photocatalytic activities under visible light illumination[J]. Journal of Materials Science and Technology,2018,34(6):969.

    2. [2]

      XING Z P,ZHANG J Q,CUI J Y, et al. Recent advances in floating TiO2-based photocatalysts for environmental application[J]. Applied Catalysis B:Environmental,2018,225:452.

    3. [3]

      李平,张孝贤,斯颖,等. TiO2/Ag/TiO2复合材料的构筑及其光催化性能[J]. 无机化学学报,2020,36(3):566.

    4. [4]

      梅邱峰,张飞燕,王宁,等. 二氧化钛基Z型异质结光催化剂[J]. 无机化学学报,2019,35(8):1321.

    5. [5]

      刘朝晖,缪菊红,沈新元. 纳米TiO2的多相光催化应用研究进展[J]. 郑州轻工业学院学报(自然科学版), 2002,17(3):43.

    6. [6]

      SHAHINI P,ASHKARRAN A A. Immobilization of plasmonic Ag-Au NPs on the TiO2 nanofibers as an efficient visible-light photocatalyst[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2018,537:155.

    7. [7]

      JIANG X D,WANG Z X,ZHANG X H,et al. Enhanced photocatalytic activity of biosynthesized Au-Ag/TiO2 catalyst by removing excess anchored biomolecules[J]. Journal of Nanoparticle Research,2019,21(10):211.

    8. [8]

      SU K Y,CHEN C Y,WU R J. Preparation of Pd/TiO2 nanowires for the photoreduction of CO2 into renewable hydrocarbon fuels[J]. Journal of the Taiwan Institute of Chemical Engineers,2019,96:409.

    9. [9]

      ZHANG M M,LIU M,JIANG Y,et al. Synthesis of immobilized CdS/TiO2 nanofiber heterostructure photocatalyst for efficient degradation of toluene[J]. Water Air and Soil Pollution,2020, 231(3):92.

    10. [10]

      TEKIN D, KIZILTAS H, UNGAN H. Kinetic evaluation of ZnO/TiO2 thin film photocatalyst in photocatalytic degradation of Orange G[J]. Journal of Molecular Liquids,2020,306:112905.

    11. [11]

      WANG Q,ZHANG W M,HU X R,et al. Hollow spherical WO3/TiO2 heterojunction for enhancing photocatalytic performance in visible-light[J]. Journal of Water Process Engineering, 2021,40:101943.

    12. [12]

      XIAO Y G,SUN X D,LI L Y,et al. Simultane- ous formation of a C/N-TiO2 hollow photocatalyst with efficient photocatalytic performance and recyclability[J]. Chinese Journal of Catalysis,2019,40(5):765.

    13. [13]

      于滢慧,姜艳丽,田玫,等. 离子液体辅助阳极氧化法制备N掺杂TiO2纳米管阵列及其光催化性能研究[J]. 稀有金属材料与工程, 2016,45(3):561.

    14. [14]

      KUO C Y,WU C H,WU J T,et al. Synthesis and characterization of a phosphorus-doped TiO2 immobilized bed for the photodegradation of bisphenol A under UV and sunlight irradiation[J]. Reaction Kinetics Mechanisms and Catalysis,2015,114(2):753.

    15. [15]

      ZAIDAN L E M C,SALES R V D,SALGADO J B D,et al. Photodegradation applied to the treatment of phenol and derived substances catalyzed by TiO2/BiPO4 and biological toxicity analysis[J]. Environmental Science and Pollution Research, 2017,24(7):6002.

    16. [16]

      LIU Z Y,WANG Q Y,TAN X Y,et al. Solvothermal preparation of Bi/Bi2O3 nanoparticles on TiO2 NTs for the enhanced photoelectrocatalytic degradation of pollutants[J]. Journal of Alloys and Compounds,2020,815,152478.

    17. [17]

      BADUROVA K, MOTOLA M, JANCZURA A, et al. Structural transformation of Ag3PO4 and Ag3PO4/TiO2 induced by visible light and Cl-ions:its impact on their photocatalytic,antimicrobial, and antifungal performance[J]. Chemical Papers,2020,74(9):2785.

    18. [18]

      AN Y,ZHENG P W,MA X F. Preparation and visible-light photocatalytic properties of the floating hollow glass microspheres-TiO2/Ag3PO4 composites[J]. RSC Advances, 2019, 9(2):721.

    19. [19]

      TONG Q,DONG Y M,YAN L,et al. High-efficient synthesis and photocatalytic properties of Ag/AgBr/TiO2 monolithic photocatalysts using sodium alginate as substrate[J]. Journal of Inorganic Materials,2017,32(6):637.

    20. [20]

      庞秋虎,廖光福,胡晓宇,等. 多孔竹炭/二氧化钛纳米复合材料制备及其光催化作用[J]. 无机材料学报,2019,34(2):219.

    21. [21]

      王丹军,申会东,付梦溪,等. Bi2WO6量子点(QDs)修饰Bi2MoO(6-x)F(2x)异质结的构筑及其催化活性增强机理[J]. 无机化学学报, 2018,34(1):73.

    22. [22]

      SHEN X F,ZHANG Y,SHI Z,et al. Construction of C3N4/CdS nanojunctions on carbon fiber cloth as a filter-membrane-shaped photocatalyst for degrading flowing wastewater[J]. Journal of Alloys and Compounds,2021,851:156743.

    23. [23]

      LIU Y,WANG W G,SI M Z,et al. Carbon clothsupported MoS2/Ag2S/Ag3PO4 composite with high photocatalytic activity and recyclability[J]. Chem Cat Chem,2019,11(3):1017.

    24. [24]

      孙慕瑾,笪有仙,张志谦. 碳纤维表面硝酸氧化处理[J]. 合成纤维,1988(1):15.

    25. [25]

      许嘉敏,李军. 碳纤维表面化学改性及其表征的研究[J]. 高分子材料科学与工程,1990(1):66.

    26. [26]

      TONG Q, DONG Y M, YAN L, et al. Highefficient synthesis and photocatalytic properties of Ag/AgBr/TiO2 monolithic photocatalysts using sodium alginate as substrate[J]. Journal of Inorganic Materials,2017,32(6):637.

    27. [27]

      YUAN H M,LIU J L,LI J,et al. Designed synthesis of a novel BiVO4-Cu2O-TiO2as an efficient visible-light-responding photocatalyst[J]. Journal of Colloid and Interface Science,2015,444:58.

    28. [28]

      FEIZPOOR S,HABIBI-YANGJEH A,VADIVEL S. Novel TiO2/Ag2CrO4 nanocomposites:efficient visible-light-driven photocatalysts with n-nheterojunctions[J]. Journal of Photochemistry and Photobiology A-Chemistry,2017,341:57.

    29. [29]

      MEI Y,SU Y H, LI Z, et al. BiOBr nanoplates@TiO2 nanowires/carbon fiber cloth as a functional water transport network for continuous flow water purification[J]. Dalton Transactions, 2017,46(2):347.

    30. [30]

      CUI W Q,AN W J,LIU L,et al. Novel Cu2O quantum dots coupled flower-like BiOBr for enhanced photocatalytic degradation of organic contaminant[J]. Journal of Hazardous Materials,2014,280:417.

    31. [31]

      WEN X J,NIU C G,ZHANG L,et al. Photocatalytic degradation of ciprofloxacin by a novel Z-scheme CeO2-Ag/AgBr photocatalyst:influencing factors, possible degradation pathways, and mechanism insight[J]. Journal of Catalysis, 2018,358:141.

    32. [32]

      SHEN X F,ZHANG T Y,XU P F,et al. Growth of C3N4 nanosheets on carbon-fiber cloth as flexible andmacroscale filter-membrane-shaped photocatalyst for degrading theflowing wastewater[J]. Applied Catalysis B:Environmental,2017,219:425.

    33. [33]

      JIA S L,XU M Z,CHEN S F,et al. A hierarchical sandwich-structured MoS2/SnO2/CC heterostructure for high photocatalysis performance[J]. Materials Letters,2019,236:697.

    34. [34]

      XU Y X,LIN D F,LIU X P,et al. TiO2 hollow nanofibers grafted Ag/AgCl with more AgCl {111} facet for enhanced photocatalytic activity[J]. Materials Letters,2018,215:250.

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