NaCl对吐温20与海藻酸钠相互作用的影响

白燕; 宋爽; 朱蓓薇; 孙宏元; 左文健; 胡梅

doi:10.12187/2022.01.004

CN 41-1437/TS ISSN 2096-1553

白燕 , 宋爽 , 朱蓓薇 , 孙宏元 , 左文健 , 胡梅

白燕, 宋爽, 朱蓓薇, 等. NaCl对吐温20与海藻酸钠相互作用的影响[J]. 轻工学报, 2022, 37(1): 26-32. doi: 10.12187/2022.01.004

引用本文: 白燕, 宋爽, 朱蓓薇, 等. NaCl对吐温20与海藻酸钠相互作用的影响[J]. 轻工学报, 2022, 37(1): 26-32. doi: 10.12187/2022.01.004

BAI Yan, SONG Shuang, ZHU Beiwei, et al. The effect of NaCl on the interaction between Tween 20 and sodium alginate[J]. Journal of Light Industry, 2022, 37(1): 26-32. doi: 10.12187/2022.01.004

Citation: BAI Yan, SONG Shuang, ZHU Beiwei, et al. The effect of NaCl on the interaction between Tween 20 and sodium alginate[J]. Journal of Light Industry, 2022, 37(1): 26-32. doi: 10.12187/2022.01.004

NaCl对吐温20与海藻酸钠相互作用的影响

1. 大连工业大学食品学院, 辽宁大连 116034;
2. 海南省院士团队创新中心, 海南三亚 572022;
3. 海南热带海洋学院食品科学与工程学院, 海南三亚 572022

作者简介: 白燕(1982-),女,山东省淄博市人,大连工业大学博士后,海南热带海洋学院副教授,主要研究方向为表面活性剂与大分子的相互作用。E-mail:baiyan416@126.com;

基金项目: 国家重点研发计划重点专项子项目（2019YFD0902005）
中图分类号: TS201.7

The effect of NaCl on the interaction between Tween 20 and sodium alginate

1. School of Food Science and Technology, Dalian Polytechnic University, Dalian 116034, China;
2. Hainan Provincial Academician Team Innovation Center, Sanya 572022, China;
3. College of Food Science and Engineering, Hainan Tropical Ocean University, Sanya 572022, China
Received Date: 2021-11-11

CLC number: TS201.7

摘要: 作为一种阴离子聚电解质，海藻酸钠在溶液中的状态易受电解质的影响。通过测定表面张力、荧光光谱和黏度，研究了非离子表面活性剂吐温20与海藻酸钠的相互作用，以及NaCl对该相互作用的影响。结果表明：吐温20-海藻酸钠复合溶液的表面张力在cmc之前高于不添加海藻酸钠的吐温20溶液，海藻酸钠的质量分数越大，表面张力升高越多；加入NaCl溶液后，吐温20-海藻酸钠-NaCl复合溶液的表面张力下降；较高质量分数（0.10%）的海藻酸钠会使吐温20-海藻酸钠复合溶液的I₁/I₃下降；在cpc之前加入NaCl溶液，吐温20-海藻酸钠-NaCl复合溶液的I₁/I₃升高；在吐温20浓度大于cmc^*时，吐温20-海藻酸钠复合溶液的黏度略微降低；在吐温20达到一定浓度后，NaCl会促使复合溶液的黏度略微升高。
- 吐温20 /
- 海藻酸钠 /
- 表面张力 /
- 荧光光谱 /
- 黏度
Abstract: As an anionic polyelectrolyte, the behavior of sodium alginate solution was easy to be affected by electrolyte. The interaction between non-ionic surfactant Tween 20 and sodium alginate and the effect of NaCl on the interaction were studied by surface tension, fluorescence spectrum and viscosity measurements. The results showed that the surface tension of Tween 20-sodium alginate complexes was higher than that without sodium alginate before cmc. The higher the mass fraction of sodium alginate, the higher the surface tension. The surface tension of Tween 20-sodium alginate-NaCl complexes decreased in the presence of NaCl. The I₁/I₃ of Tween 20-sodium alginate complexes decreased when the concentration of sodium alginate increased. Before cpc, I₁/I₃ of Tween 20-sodium alginate-NaCl complexes increased in the presence of NaCl. When the concentration of Tween 20 was higher than cmc^*, the viscosity of Tween 20-sodium alginate complexes decreased slightly. The viscosity of Tween 20-alginate complexes increased slightly in the presence of NaCl when Tween 20 reached a certain concentration.
- Tween 20 /
- sodium alginate /
- surface tension /
- fluorescence /
- viscosity
1. [1]
  RUB M A, HOQUE M A, AZUM N, et al.Investigation of the aggregation, clouding and thermodynamics of the mixture of sodium alginate with sodium dodecyl sulfate and triton X-100 in aqueous and aqua-organic mixed solvents media[J].Journal of Molecular Liquids, 2022, 346:117109.
2. [2]
  白艳红, 吴晓丽, 张相生, 等.海藻酸钠可食性膜对酱卤鸡腿的保鲜效果[J].郑州轻工业学院学报(自然科学版), 2015, 30(1):1-5.
3. [3]
  邓小丽, 胡明娟, 金志刚, 等.海藻酸钠薰衣草精油微胶囊的制备及其性能研究[J].食品工业科技, 2019, 40(23):47-53.
4. [4]
  苑再武, 苑敬, 吕鑫, 等.多糖类大分子与表面活性剂相互作用的研究进展[J].物理化学学报, 2013, 29(3):449-459.
5. [5]
  DAVARCI F, TURAN D, OZCELIK B, et al.The influence of solution viscosities and surface tension on calcium-alginate microbead formation using dripping technique[J].Food Hydrocolloids, 2017, 62:119-127.
6. [6]
  MIRTIAC J, PAUDEL A, LAGGNER P, et al.Polyelectrolyte-surfactant-complex nanoparticles as a delivery platform for poorly soluble drugs:A case study of ibuprofen loaded cetylpyridinium-alginate system[J].International Journal of Pharmaceutics, 2020, 580:119199.
7. [7]
  ALAMIN N U, KHAN A S, NASRULLAH A, et al.Activated carbon-alginate beads impregnated with surfactant as sustainable adsorbent for efficient removal of methylene blue[J].International Journal of Biological Macromolecules, 2021, 176:233-243.
8. [8]
  赵国玺, 朱步瑶.表面活性剂作用原理[M].北京:中国轻工业出版社, 2003.
9. [9]
  REHM B H.Alginates:Biology and applications[M].Berlin:Springer, 2009.
10. [10]
  黄俊浩.两亲性海藻酸钠衍生物和糖苷表面活性剂的相互作用的研究[D].海口:海南大学, 2015.
11. [11]
  KAMP J, EMONDS S, SEIDENFADEN M, et al.Tuning the excess charge and inverting the salt rejection hierarchy of polyelectrolyte multilayer membranes[J]. Journal of Membrane Science, 2021, 639:119636.
12. [12]
  王军, 李迎宾, 杨许召, 等.咪唑基离子液体表面活性剂与牛血清蛋白混合体系相互作用研究[J].轻工学报, 2019, 34(3):21-27.
13. [13]
  SZYMCZYK K, TARABA A, SZANIAWSKA M.Interactions of Tween 20, 60 and 80 with dye molecules:Spectroscopic analysis[J].Journal of Molecular Liquids, 2019, 290:111227.
14. [14]
  MILANOVIĆ M, ĆIRIN D, KRSTONOŠIĆ V.The interactions in ternary system made of xanthan gum, Carbopol 940 and anionic/nonionic surfactant[J].Journal of Molecular Liquids, 2021, 344:117696.
15. [15]
  BAI Y, XU G, XIN X, et al.Interaction between cetyltrimethylammonium bromide and β-cyclodextrin:Surface tension and interfacial dilational viscoelasticity studies[J].Colloid and Polymer Science, 2008, 286(13):1475-1484.
16. [16]
  BODNÁR K, FEGYVER E, NAGY M, et al.Impact of polyelectrolyte chemistry on the thermodynamic stability of oppositely charged macromolecule/surfactant mixtures[J].Langmuir, 2016, 32(5):1259-1268.
17. [17]
  KANCHARLA S, JAHAN R, BEDROV D, et al. Role of chain length and electrolyte on the micellization of anionic fluorinated surfactants in water[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2021, 628:127313.
18. [18]
  吉林大学, 四川大学.物理化学与胶体化学[M].北京:人民教育出版社, 1983.
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白燕, 宋爽, 朱蓓薇, 等. NaCl对吐温20与海藻酸钠相互作用的影响[J]. 轻工学报, 2022, 37(1): 26-32. doi: 10.12187/2022.01.004

引用本文: 白燕, 宋爽, 朱蓓薇, 等. NaCl对吐温20与海藻酸钠相互作用的影响[J]. 轻工学报, 2022, 37(1): 26-32. doi: 10.12187/2022.01.004

BAI Yan, SONG Shuang, ZHU Beiwei, et al. The effect of NaCl on the interaction between Tween 20 and sodium alginate[J]. Journal of Light Industry, 2022, 37(1): 26-32. doi: 10.12187/2022.01.004

NaCl对吐温20与海藻酸钠相互作用的影响

作者简介:白燕(1982-),女,山东省淄博市人,大连工业大学博士后,海南热带海洋学院副教授,主要研究方向为表面活性剂与大分子的相互作用。E-mail:baiyan416@126.com

1. 大连工业大学食品学院, 辽宁大连 116034;
2. 海南省院士团队创新中心, 海南三亚 572022;
3. 海南热带海洋学院食品科学与工程学院, 海南三亚 572022

收稿日期: 2021-11-11

基金项目: 国家重点研发计划重点专项子项目（2019YFD0902005）

关键词:

摘要: 作为一种阴离子聚电解质，海藻酸钠在溶液中的状态易受电解质的影响。通过测定表面张力、荧光光谱和黏度，研究了非离子表面活性剂吐温20与海藻酸钠的相互作用，以及NaCl对该相互作用的影响。结果表明：吐温20-海藻酸钠复合溶液的表面张力在cmc之前高于不添加海藻酸钠的吐温20溶液，海藻酸钠的质量分数越大，表面张力升高越多；加入NaCl溶液后，吐温20-海藻酸钠-NaCl复合溶液的表面张力下降；较高质量分数（0.10%）的海藻酸钠会使吐温20-海藻酸钠复合溶液的I₁/I₃下降；在cpc之前加入NaCl溶液，吐温20-海藻酸钠-NaCl复合溶液的I₁/I₃升高；在吐温20浓度大于cmc^*时，吐温20-海藻酸钠复合溶液的黏度略微降低；在吐温20达到一定浓度后，NaCl会促使复合溶液的黏度略微升高。

English Abstract

The effect of NaCl on the interaction between Tween 20 and sodium alginate

1. School of Food Science and Technology, Dalian Polytechnic University, Dalian 116034, China;
2. Hainan Provincial Academician Team Innovation Center, Sanya 572022, China;
3. College of Food Science and Engineering, Hainan Tropical Ocean University, Sanya 572022, China

Received Date: 2021-11-11

Abstract: As an anionic polyelectrolyte, the behavior of sodium alginate solution was easy to be affected by electrolyte. The interaction between non-ionic surfactant Tween 20 and sodium alginate and the effect of NaCl on the interaction were studied by surface tension, fluorescence spectrum and viscosity measurements. The results showed that the surface tension of Tween 20-sodium alginate complexes was higher than that without sodium alginate before cmc. The higher the mass fraction of sodium alginate, the higher the surface tension. The surface tension of Tween 20-sodium alginate-NaCl complexes decreased in the presence of NaCl. The I₁/I₃ of Tween 20-sodium alginate complexes decreased when the concentration of sodium alginate increased. Before cpc, I₁/I₃ of Tween 20-sodium alginate-NaCl complexes increased in the presence of NaCl. When the concentration of Tween 20 was higher than cmc^*, the viscosity of Tween 20-sodium alginate complexes decreased slightly. The viscosity of Tween 20-alginate complexes increased slightly in the presence of NaCl when Tween 20 reached a certain concentration.