碳酸锰纳米片阵列的制备及其电化学性能研究

张凯扬; 肖元化; 吴诗德; 苏当成; 方少明

doi:10.12187/2022.02.016

May 2022

Article Contents

ZHANG Kaiyang, XIAO Yuanhua, WU Shide, et al. Preparation and electrochemical properties of manganese carbonate nanoplate arrays[J]. Journal of Light Industry, 2022, 37(2): 119-126. doi: 10.12187/2022.02.016

Citation: ZHANG Kaiyang, XIAO Yuanhua, WU Shide, et al. Preparation and electrochemical properties of manganese carbonate nanoplate arrays[J]. Journal of Light Industry, 2022, 37(2): 119-126. doi: 10.12187/2022.02.016 shu

Preparation and electrochemical properties of manganese carbonate nanoplate arrays

ZHANG Kaiyang ^1,2 ,
XIAO Yuanhua ^1,2 ,
WU Shide ^1,2 ,
SU Dangcheng ^1,3 ,
FANG Shaoming ^1,2

1. College of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China;
2. Key Laboratory of Surface and Interface Science and Technology, Zhengzhou 450001, China;
3. College of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China

Received Date: 2021-04-14
Accepted Date: 2021-05-25

Abstract

In order to increase the working voltage of the aqueous zinc ion batteries with manganese-based material as the positive electrode material, an ultrathin nanosheet array (MnCO₃ NA) was grown on a nickel foam substrate by a one-step solvothermal method. The structure, morphology and electrochemical properties of MnCO₃ NA were characterized by X-ray diffraction (XRD), scanning electron microscope, transmission electron microscope and battery performance tester. The experiments results showed that the thickness of the MnCO₃ NA was about 30 nm and the height was about 500 nm. It was directly applied to the zinc ion battery in the alkaline electrolyte, delivering a high working voltage of 1.73 V, a specific discharge capacity of 255.41 mAh/g at 0.1 A/g, and a capacity retention of 83.1% after 270 charge-discharge cycles at 0.5 A/g. In addition, the zinc storage mechanism of the electrode was a mono-phase reaction from Mn²⁺ to Mn³⁺, which was analyzed by ex-situ XRD and photoelectron spectroscopy at different potential states.
- aqueous zinc ion battery,
- MnCO₃,
- nanosheet array
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Preparation and electrochemical properties of manganese carbonate nanoplate arrays

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