JOURNAL OF LIGHT INDUSTRY

CN 41-1437/TS  ISSN 2096-1553

Volume 38 Issue 4
August 2023
Article Contents
LIU Xiaoli, GUO Caoyu, LIN Kaili, et al. Preparation and properties of chitosan-based antibacterial and antioxidative composite films[J]. Journal of Light Industry, 2023, 38(4): 27-36. doi: 10.12187/2023.04.004
Citation: LIU Xiaoli, GUO Caoyu, LIN Kaili, et al. Preparation and properties of chitosan-based antibacterial and antioxidative composite films[J]. Journal of Light Industry, 2023, 38(4): 27-36. doi: 10.12187/2023.04.004 shu

Preparation and properties of chitosan-based antibacterial and antioxidative composite films

  • Received Date: 2022-11-05
    Accepted Date: 2023-02-22
  • In order to obtain chitosan (CS) based composite film materials with satisfactory functional properties, CS based antibacterial and antioxidant composite films (CS/nBC/KA/CUR) containing nanobacterium cellulose (nBC), curcumin (CUR) and kojic acid (KA) was prepared by mixed solution casting method. The barrier properties, mechanical properties, optical properties, antibacterial activity, and antioxidant activity of different component composite films were investigated.The results showed that the components of CS/nBC/KA/CUR composite film interacted with each other mainly by hydrogen bonding and van der Waals force, and the interior of the film showed a relatively enhanced crystallinity. Compared with the other composite films, the water solubility of CS/nBC/KA/CUR composite films was decreased significantly. The water vapor transmission rate was increased by nearly 24% compared with CS/nBC composite films. The tensile strength was increased by nearly 3 times, and the elongation at break was increased by about 1.8% compared with CS/nBC/KA composite films. The antibacterial effect against E.coli was increased by about 12.2% compared with the other composite films, and the ABTS free radical scavenging rate was most greatly increased by 35.2% compared with CS/nBC composite films. Therefore, CS/nBC/KA/CUR composite films combined the advantages of each components and showed a certain potential value in the development of active food packaging materials.
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    1. [1]

      苏小波.生物基可降解食品包装材料关键技术研究[J].科技风, 2021(19):12-13.

    2. [2]

      叶新友."限塑令"背景下可降解塑料的研究进展[J].塑料助剂, 2022(1):62-66.

    3. [3]

      AYRANCI E, TUNC S.The effect of fatty acid content on water vapour and carbon dioxide transmissions of cellulose-based edible films[J].Food Chemistry, 2001, 72(2):231-236.

    4. [4]

      WEN Y Y, LIU J, JIANG L, et al.Development of intelligent/active food packaging film based on tempo-oxidized bacterial cellulose containing thymol and anthocyanin-rich purple potato extract for shelf life extension of shrimp[J].Food Packaging and Shelf Life, 2021, 29:1-9.

    5. [5]

      ELSABEE M Z, NAGUIB H F, MORSI R E.Chitosan based nanofibers, review[J].Materials Science and Engineering C, 2012, 32(7):1711-1726.

    6. [6]

      GAO L L, ZHANG H, YU B, et al.Chitosan composite hydrogels cross-linked by multifunctional diazo resin as antibacterial dressings for improved wound healing[J].Journal of Biomedical Materials Research Part A, 2020, 108(9):1890-1898.

    7. [7]

      杨焕彬, 曾庆培, 林光明, 等.生物保鲜剂在禽肉保鲜中的应用研究进展[J].轻工学报, 2021, 36(6):38-46.

    8. [8]

      甄洪鹏, 聂俊, 孙俊峰, 等.壳聚糖/聚乙烯醇共混超细纤维的制备及紫外光交联研究[J].高分子学报, 2007(3):230-234.

    9. [9]

      NAGHDI T, GOLMOHAMMADI H, VOSOUGH M, et al.Lab-on-nanopaper:An optical sensing bioplatform based on curcumin embedded in bacterial nanocellulose as an albumin assay kit[J].Analytica Chimica Acta, 2019, 1070:104-111.

    10. [10]

      XIANG Z Y, JIN X C, LIU Q G, et al.The reinforcement mechanism of bacterial cellulose on paper made from woody and non-woody fiber sources[J].Cellulose, 2017, 24(11):5147-5156.

    11. [11]

      KUNANOPPARAT T, MENUT P, MOREL M H, et al.Reinforcement of plasticized wheat gluten with natural fibers:From mechanical improvement to deplasticizing effect[J].Composites Part A(Applied Science and Manufacturing), 2008, 39(5):777-785.

    12. [12]

      刘小静.细菌纤维素在包装领域的研究进展[J].包装工程, 2021, 42(19):1-11.

    13. [13]

      LEE K Y, BLAKER J J, BISMARCK A.Surface functionalisation of bacterial cellulose as the route to produce green polylactide nanocomposites with improved properties[J].Composites Science and Technology, 2009, 69(15/16):2724-2733.

    14. [14]

      PORTES E, GARDRAT C, CASTELLAN A, et al.Environmentally friendly films based on chitosan and tetrahydrocurcuminoid derivatives exhibiting antibacterial and antioxidative properties[J].Carbohydrate Polymers, 2008, 76(4):578-584.

    15. [15]

      谢玉梅.含细菌纤维素与姜黄素的马铃薯皮活性膜的制备与表征[D].咸阳:西北农林科技大学, 2019.

    16. [16]

      XU Y X, LIU X L, JIANG Q X, et al.Development and properties of bacterial cellulose, curcumin, and chitosan composite biodegradable films for active packaging materials[J].Carbohydrate Polymers, 2021, 260:117778.

    17. [17]

      何世微, 陶毅明, 王贵平, 等.曲酸对菠萝蜜多酚氧化酶的抑制作用和抑菌实验[J].食品工业科技, 2015, 36(11):159-161
      , 166.

    18. [18]

      蒋利亚.不同浓度的曲酸溶液对藕带褐变的抑制及抗菌作用[J].广东化工, 2021, 48(19):38-40.

    19. [19]

      SUKHTEZARI S, ALMASI H, PIRSA S, et al.Development of bacterial cellulose based slow-release active films by incorporation of Scrophularia striata Boiss.extract[J].Carbohydrate Polymers, 2017, 156:340-350.

    20. [20]

      ZHOU X Y, LIU X L, WANG Q, et al.Antimicrobial and antioxidant films formed by bacterial cellulose, chitosan and tea polyphenol-Shelf life extension of grass carp[J].Food Packaging and Shelf Life, 2022, 33:1-10.

    21. [21]

      WANG H P, GONG X C, MIAO Y L, et al.Preparation and characterization of multilayer films composed of chitosan, sodium alginate and carboxymethyl chitosan-ZnO nanoparticles[J].Food Chemistry, 2019, 283:397-403.

    22. [22]

      LIU J, LIU S, CHEN Y, et al.Physical, mechanical and antioxidant properties of chitosan films grafted with different hydroxybenzoic acids[J].Food Hydrocolloids, 2017, 71:176-186.

    23. [23]

      谭才邓, 朱美娟, 杜淑霞, 等.抑菌试验中抑菌圈法的比较研究[J].食品工业, 2016, 37(11):122-125.

    24. [24]

      GAN M Y, GUO C Y, LIAO W Y, et al.Development and characterization of chitosan/bacterial cellulose/pullulan bilayer film with sustained release curcumin[J].International Journal of Biological Macromolecules, 2023, 226:301-311.

    25. [25]

      张伸.基于海藻酸钠可食用抗菌复合膜的制备与性能研究[D].哈尔滨:哈尔滨工业大学, 2018.

    26. [26]

      SUN T, WU C L, HAO H, et al.Preparation and preservation properties of the chitosan coatings modified with the in situ synthesized nano SiOx[J].Food Hydrocolloids, 2016, 54:130-138.

    27. [27]

      MA X X, CHEN Y J, HUANG J Y, et al.In situ formed active and intelligent bacterial cellulose/cotton fiber composite containing curcumin[J].Cellulose, 2020, 27(16):9371-9382.

    28. [28]

      CHIAOPRAKOBKIJ N, SUWANMAJO T, SANCHAVANAKIT N, et al.Curcumin-loaded bacterial cellulose/alginate/gelatin as a multifunctional biopolymer composite film[J].Molecules, 2020, 25(17):3800-3818.

    29. [29]

      LIU X L, JIANG Q, XIA W S.One-step procedure for enhancing the antibacterial and antioxidant properties of a polysaccharide polymer:Kojic acid grafted onto chitosan[J].International Journal of Biological Macromolecules, 2018, 113:1125-1133.

    30. [30]

      刘晓丽.壳寡糖-曲酸衍生物的制备及其抗菌活性研究[D].无锡:江南大学, 2015.

    31. [31]

      GUZ L, FAMÁ L, CANDAL R, et al.Size effect of ZnO nanorods on physicochemical properties of plasticized starch composites[J].Carbohydrate Polymers, 2017, 157:1611-1619.

    32. [32]

      SABLANI S S, DASSE F, BASTARRACHEA L, et al.Apple peel-based edible film development using a high-pressure homogenization[J].Journal of Food Science, 2009, 74(7):E372-E381.

    33. [33]

      席丽娟.N-琥珀酰壳聚糖固载溶菌酶抑菌膜的制备、性能及应用研究[D].长春:吉林大学, 2017.

    34. [34]

      于金珅, 张芳.姜黄素介导的光动力技术对鲜切马铃薯的杀菌效果[J].食品工业科技, 2021, 42(4):259-263
      , 270.

    35. [35]

      陈玉芹, 李仲佰, 姚敏, 等.明胶-壳聚糖-肉桂精油天然涂膜液的制备及其抑菌效果研究[J].轻工学报, 2021, 36(4):9-17.

    36. [36]

      李凤梅.曲酸对大肠杆菌和金黄色葡萄球菌的抑制作用研究[J].食品研究与开发, 2008(6):190-192.

    37. [37]

      PENHA C B, BONIN E, SILVA A F D, et al.Photodynamic inactivation of foodborne and food spoilage bacteria by curcumin[J].LWT-Food Science and Technology, 2017, 76:198-202.

    38. [38]

      李雪娜.姜黄素介导的光动力杀菌在食品中的潜在应用[J].现代食品, 2021(9):29-31.

    39. [39]

      陈春涛, 程卫国, 李元, 等.天然防腐剂壳聚糖的研究与应用[J].郑州轻工业学院学报, 1998(1):4-7.

    40. [40]

      KIM D O, LEE K W, LEE H J, et al.Vitamin C equivalent antioxidant capacity (VCEAC) of phenolic phytochemicals[J].Journal of Agricultural and Food Chemistry, 2002, 50(13):3713-3717.

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