摘要:
采用静置吸附法,以芹菜渣为吸附剂,研究其对Cu2+的吸附特性与吸附机理,结果显示:芹菜渣对Cu2+的吸附率随其粒径的减小而增大;Cu2+溶液初始浓度相同时,吸附率随芹菜渣用量增加而增大,而当用量相同时,对不同浓度的Cu2+溶液吸附率在15 mg/L均出现1次极大值.正交试验得到3因素对吸附效果的影响程度顺序为pH>温度>时间,最优吸附条件是pH=6,吸附温度为30℃,吸附时间为3 h.吸附以单分子层的物理吸附为主,Freundlich吸附等温式能更好地描述芹菜渣对Cu2+的吸附热力学情况,标准状态下芹菜渣对Cu2+的吸附热为10.49 kJ/mol;吸附过程是先快速吸附,当吸附时间超过60 min时,吸附量的增加趋于平缓,吸附动力学用-级动力学模型描述更合适.
Abstract:
By adsorption method,adsorption character and mechanism of Cu2+ by celery residue were studied.The results showed that with the smaller size of celery residue,Cu2+ adsorption rate increases.Under the same Cu2+ initial concentration,with the addition of more celery residue,Cu2+ adsorption rate increases.Under the same addition amount of celery residue,Cu2+ adsorption rate all has once maximum value,as initial concentration is 15 mg/L.Orthogonal tests showed that the optimum adsorption conditions are the wastewater pH=6,temperature 30℃ and soaking time 3 h,and influence degree for 3 factors from big to small is pH,temperature and soaking time.Single molecule layer absorption dominant is Cu2+ adsorption,and adsorption isotherm is fit to Freundlich adsorption isotherm.Under standard condition,the adsorption heat for celery residue on Cu2+ is 10.49 kJ/mol.The adsorption rate for celery residue to Cu2+ is quick first,and then become slow after more than 60 min.First kinetic model can describe the adsorption kinetics of celery residue more better.