基于高分辨质谱-相依成分分析的怀菊花泡饮过程分析

董春红; 李振兴; 赵绍伟; 刘应凡; 孙雨安; 王国庆

doi:10.3969/j.issn.2095-476X.2013.02.012

CN 41-1437/TS ISSN 2096-1553

董春红 , 李振兴 , 赵绍伟 , 刘应凡 , 孙雨安 , 王国庆

董春红, 李振兴, 赵绍伟, 等. 基于高分辨质谱-相依成分分析的怀菊花泡饮过程分析[J]. 轻工学报, 2013, 28(2): 49-53. doi: 10.3969/j.issn.2095-476X.2013.02.012

引用本文: 董春红, 李振兴, 赵绍伟, 等. 基于高分辨质谱-相依成分分析的怀菊花泡饮过程分析[J]. 轻工学报, 2013, 28(2): 49-53. doi: 10.3969/j.issn.2095-476X.2013.02.012

DONG Chun-hong, LI Zhen-xing, ZHAO Shao-wei, et al. Analysis of brewing process of Huai chrysanthemum based on high resolution mass spectrometry and dependent component analysis[J]. Journal of Light Industry, 2013, 28(2): 49-53. doi: 10.3969/j.issn.2095-476X.2013.02.012

Citation: DONG Chun-hong, LI Zhen-xing, ZHAO Shao-wei, et al. Analysis of brewing process of Huai chrysanthemum based on high resolution mass spectrometry and dependent component analysis[J]. Journal of Light Industry, 2013, 28(2): 49-53. doi: 10.3969/j.issn.2095-476X.2013.02.012

基于高分辨质谱-相依成分分析的怀菊花泡饮过程分析

郑州轻工业学院材料与化学工程学院, 河南郑州 450001;
焦作大学怀药研究中心, 河南焦作 454003

通讯作者: 王国庆

基金项目: 河南省科技攻关项目(102102310071)
国家自然科学基金项目(21075113,21171150)
中图分类号: O657;Q944.5

Analysis of brewing process of Huai chrysanthemum based on high resolution mass spectrometry and dependent component analysis

College of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China;
Research Center of Huaiqing Chinese Medicine, Jiaozuo University, Jiaozuo 454003, China

Corresponding author: WANG Guo-qing,

Received Date: 2013-02-22

CLC number: O657;Q944.5

摘要: 采用高分辨质谱法(HRMS)对菊花泡饮过程分析,以准确分子量直接定性菊花泡饮过程中27种典型成分,结合其典型成分质谱响应强度,得到菊花泡饮过程的高分辨质谱指纹图.进一步以相依成分分析(DCA)解析,得到能够体现菊花泡饮过程典型化学成分特征的3组相依组分(DC),并以DC相对浓度变化表征菊花泡饮过程.研究结果表明,3组DC与挥发油、氨基酸、黄酮类为主要特征的菊花中典型成分相对应,不同类型的化合物质谱相应值具有较大的差异,菊花泡饮时前2次相依组分相对含量变化较大;冲泡5次后菊花中溶于水的活性成分的种类明显减少、相对含量也明显降低而不再具有饮用价值.HRMS-DCA为菊花泡饮过程高分辨质谱指纹图谱解析利用提供了新途径.
- 高分辨质谱 /
- 相依成分分析 /
- 怀菊花 /
- 泡饮过程分析
Abstract: Using high resolution mass spectrometry (HRMS) to analyze the brewing process of Huai chrysanthemum,27 typical components in drinking process were directly qualified with accurate molecular weight,and the high resolution mass spectrometric (MS) fingerprints of chrysanthemum tea process were obtained combined with the mass spectrometric response strength of the components. The fingerprints were processed by dependent component analysis (DCA),and 3 groups of dependent components (DCs) that can used to characterize the characteristics of the typical components in the drink chrysanthemum bubble and the brewing process. Research results showed that the 3 groups of DCs are corresponding to volatile oil, amino acids,and flavonoids as the main components of the Huai chrysanthemum,there are great differences among the response MS values of of different components. The relative concentration of DCs obviously de-creased during the first 2 times of the brewing process; while after 5 times brewing,the variation of DCs are negligible and there is no drinking value. HRMS-DCA provides a new way to resolve HRMS fingerprints of chrysanthemum brewing process.
- high resolution mass spectrometry /
- dependent component analysis (DCA) /
- Huai chrysanthemum /
- analysis of brewing process
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沈阳化工大学材料科学与工程学院沈阳 110142

董春红, 李振兴, 赵绍伟, 等. 基于高分辨质谱-相依成分分析的怀菊花泡饮过程分析[J]. 轻工学报, 2013, 28(2): 49-53. doi: 10.3969/j.issn.2095-476X.2013.02.012

基于高分辨质谱-相依成分分析的怀菊花泡饮过程分析

通讯作者: 王国庆

郑州轻工业学院材料与化学工程学院, 河南郑州 450001;
焦作大学怀药研究中心, 河南焦作 454003

收稿日期: 2013-02-22

基金项目: 河南省科技攻关项目(102102310071)国家自然科学基金项目(21075113,21171150)

关键词:

摘要: 采用高分辨质谱法(HRMS)对菊花泡饮过程分析,以准确分子量直接定性菊花泡饮过程中27种典型成分,结合其典型成分质谱响应强度,得到菊花泡饮过程的高分辨质谱指纹图.进一步以相依成分分析(DCA)解析,得到能够体现菊花泡饮过程典型化学成分特征的3组相依组分(DC),并以DC相对浓度变化表征菊花泡饮过程.研究结果表明,3组DC与挥发油、氨基酸、黄酮类为主要特征的菊花中典型成分相对应,不同类型的化合物质谱相应值具有较大的差异,菊花泡饮时前2次相依组分相对含量变化较大;冲泡5次后菊花中溶于水的活性成分的种类明显减少、相对含量也明显降低而不再具有饮用价值.HRMS-DCA为菊花泡饮过程高分辨质谱指纹图谱解析利用提供了新途径.

English Abstract

Analysis of brewing process of Huai chrysanthemum based on high resolution mass spectrometry and dependent component analysis

Corresponding author: WANG Guo-qing,

College of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China;
Research Center of Huaiqing Chinese Medicine, Jiaozuo University, Jiaozuo 454003, China

Received Date: 2013-02-22

Abstract: Using high resolution mass spectrometry (HRMS) to analyze the brewing process of Huai chrysanthemum,27 typical components in drinking process were directly qualified with accurate molecular weight,and the high resolution mass spectrometric (MS) fingerprints of chrysanthemum tea process were obtained combined with the mass spectrometric response strength of the components. The fingerprints were processed by dependent component analysis (DCA),and 3 groups of dependent components (DCs) that can used to characterize the characteristics of the typical components in the drink chrysanthemum bubble and the brewing process. Research results showed that the 3 groups of DCs are corresponding to volatile oil, amino acids,and flavonoids as the main components of the Huai chrysanthemum,there are great differences among the response MS values of of different components. The relative concentration of DCs obviously de-creased during the first 2 times of the brewing process; while after 5 times brewing,the variation of DCs are negligible and there is no drinking value. HRMS-DCA provides a new way to resolve HRMS fingerprints of chrysanthemum brewing process.

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