FAN Ya-ling, WANG Da-feng, HE Yu-ping, et al. Determination of di(ethylene glycol) dibenzoate in water-based emulsion adhesives for cigarette with GC-MS method[J]. Journal of Light Industry, 2014, 29(2): 27-30. doi: 10.3969/j.issn.2095-476X.2014.02.008
Citation:
FAN Ya-ling, WANG Da-feng, HE Yu-ping, et al. Determination of di(ethylene glycol) dibenzoate in water-based emulsion adhesives for cigarette with GC-MS method[J]. Journal of Light Industry, 2014, 29(2): 27-30.
doi:
10.3969/j.issn.2095-476X.2014.02.008
Determination of di(ethylene glycol) dibenzoate in water-based emulsion adhesives for cigarette with GC-MS method
-
FAN Ya-ling
1,2
,
-
WANG Da-feng
1,2
,
-
HE Yu-ping
1,2
,
-
LYU Juan
2
,
-
CAO Jie-qiong
1,3
,
-
HE Yuan
2
,
-
PENG Jun-cang
2,,
-
College of Food and Bioengineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China;
-
Technology Center, China Tobacco Shaanxi Industrial Co., Ltd., Baoji 721000, China;
-
Baoji Cigarette Factory, China Tobacco Shaanxi Industrial Co., Ltd., Baoji 721000, China
-
Corresponding author:
PENG Jun-cang,
-
Received Date:
2014-01-02
Available Online:
2014-03-15
-
Abstract
In order to determine the content of di(ethylene glycol) dibenzoate(DEDB) in water-based emulsion adhesives for tobacco,the adhesives were extracted separately with n-hexane,cyclohexane,ethyl ether,2,2,4-trimethylpentane,and determined by GC-MS under selected ion monitoring mode.The results showed that oscillating time 40 min and extraction volume 10 mL were preferable duration for n-hexane extraction by adding 1 mL water into the sample;the calibration curves of the DEDB exhibited good linear relations(R2=0.999 4), the limits of detection 0.04 μg/mL,RSD=4.98%,and the recoveries ranged from 97%~101%.
-
-
References
-
[1]
林国良,陈登龙,黄宝铨,等.邻苯二甲酸酯类增塑剂替代品的研究进展[J].塑料助剂,2007(5):1.
-
[2]
杨斌,陈超英,吴达,等.气相色谱/质谱联用法测定烟用水基型乳胶中的邻苯二甲酸酯[J].烟草科技,2011(7):48.
-
[3]
崔军.二甘醇二苯甲酸酯的合成研究进展[J].精细化工原料及中间体,2012(2):16.
-
[4]
石万聪.增塑剂的毒性及相关法规[J].塑料助剂,2010(3):43.
-
[5]
巩玉红.邻苯二甲酸酯类增塑剂替代品及现状分析[J].山东化工,2011,40(3):75.
-
[6]
王颖.二甘醇二苯甲酸酯的合成研究[J].沈阳教育学院学报,2005,7(2):108.
-
[7]
张含平.二甘醇二苯甲酸酯的合成研究[D].哈尔滨:哈尔滨工程大学,2005.
-
[8]
李凌阁,许绍东,周绍海,等.一缩二乙二醇双苯甲酸酯增塑剂的气相色谱分析[J].化学通报,1989(2):40.
-
[9]
货春霞.烟用水基胶中两类有害物质的分析研究与应用[D].湘潭:湘潭大学,2010.
-
[10]
姬厚伟,刘建,叶冲,等.静态顶空-气相色谱质谱法测定烟用水基胶中残余的乙酸乙烯酯[J].烟草科技,2011(11):32.
-
[11]
李国智,杨仁礼,师建全,等.烟用水基型乳胶中苯系物的GC/MS/SIM测定[J].烟草科技,2011(11):32.
-
[12]
廖惠云,张映,熊晓敏,等.微波消解-石墨炉原子吸收光谱法测定水基胶中的铅和砷[J].烟草科技,2011(12):34.
-
Proportional views
-
-