丙烯酸酯类聚氨酯材料耐候性的研究

李敏; 周立明; 高丽君; 王刚强; 方少明

doi:10.3969/j.issn.2095-476X.2014.06.011

CN 41-1437/TS ISSN 2096-1553

丙烯酸酯类聚氨酯材料耐候性的研究

李敏 , 周立明 , 高丽君 , 王刚强 , 方少明

李敏, 周立明, 高丽君, 等. 丙烯酸酯类聚氨酯材料耐候性的研究[J]. 轻工学报, 2014, 29(6): 43-47. doi: 10.3969/j.issn.2095-476X.2014.06.011

引用本文: 李敏, 周立明, 高丽君, 等. 丙烯酸酯类聚氨酯材料耐候性的研究[J]. 轻工学报, 2014, 29(6): 43-47. doi: 10.3969/j.issn.2095-476X.2014.06.011

LI Min, ZHOU Li-ming, GAO Li-jun, et al. Research on the weathering resistance of poly (urethane-methacrylate) materials[J]. Journal of Light Industry, 2014, 29(6): 43-47. doi: 10.3969/j.issn.2095-476X.2014.06.011

Citation: LI Min, ZHOU Li-ming, GAO Li-jun, et al. Research on the weathering resistance of poly (urethane-methacrylate) materials[J]. Journal of Light Industry, 2014, 29(6): 43-47. doi: 10.3969/j.issn.2095-476X.2014.06.011

丙烯酸酯类聚氨酯材料耐候性的研究

郑州轻工业学院河南省表界面科学重点实验室, 河南郑州 450001
基金项目: 国家自然科学基金项目(21271159)
郑州轻工业学院博士基金项目(2011BSJJ003)
河南省基础与前沿技术研究计划项目(112300410143,132300410182)
中图分类号: O633.4;TB34

Research on the weathering resistance of poly (urethane-methacrylate) materials

He'nan Province Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry,Zhengzhou 450001,China
Received Date: 2014-09-05
Available Online: 2014-11-15
CLC number: O633.4;TB34

摘要: 以异佛尔酮-二异氰酸酯(IPDI)、聚四氢呋喃1000(PTMEG-1000)、聚乙二醇400(PEG-400)、甲基丙烯酸-β-羟乙酯(HEMA)为基本原料,合成了一类丙烯酸酯类聚氨酯大单体,然后用偶氮二异丁腈(AIBN)引发大单体聚合制备了一种高透明性的耐候性聚氨酯(PU)材料.利用FT-IR,XRD对所制备的PU材料进行表征和分析;通过冷冻和紫外光老化处理实验,研究了PU材料的耐候性.结果表明,PTMEG-1000含量的增加能显著提高PU材料的光学性能和热稳定性,PU材料在冷冻和紫外光照射条件下,综合性能与常温下相差不大,表明其具有良好的耐候性.其中PU-3材料的综合性能较佳,其常温下透光率为92.1%,拉伸强度为13.1 MPa;在-26℃下透光率为84.7%,拉伸强度为15.7 MPa;经紫外光辐射后其透光率为74.3%,拉伸强度为11.5 MPa.
- 丙烯酸酯类聚氨酯 /
- 耐候性 /
- 透明性
Abstract: Poly (urethane-methacrylate) macromonomers were synthesized based on isophorone diisocyanate (IPDI), poly (tetrahydrofuran) 1000 (PTMEG-1000), poly (ethylene glycol) 400 (PEG-400) and β-hydroxyethyl methacrylate (HEMA). Then high transparent poly (urethane-methacrylate) materials with weathering resistance were prepared by the polymerization of the macromonomers using 2,2-azo-bis-iso-butyro-nitrile (AIBN) as initiator. The obtained PU materials were characterized by FT-IR and XRD.The weathering resistance of PU materials was characterized under the condition of freezing and UV-irradiation. The results showed that the thermal stability and optical performance of PU materials increased with increasing PTMEG-1000 content, and comprehensive performance in freezing and UV-irradiation conditions were almost the same results as at room temperature, which indicated the materials owned good weatherability. PU-3 exhibited outstanding performance. The tensile strength and the transmittance of PU-3 were 13.1 MPa and 92.1% at room temperature, respectively. Its tensile strength and transmittance were 15.7 MPa and 84.7% at -26℃, respectively. And its tensile strength and transmittance were 11.5 MPa and 74.3% after UV-irradiation, respectively.
- poly (urethane-methacrylate) /
- weathering resistance /
- transparent
1. [1]
  张军瑞,戴子林,涂伟萍,等.高性能透明聚氨酯的研究进展[J].材料导报,2013,27(17):91.
2. [2]
  方少明,周立明,张留城,等.IPDI/HEMA/PEG大单体的合成及其聚合物的制备[J].高分子材料科学与工程,2004,20(5):109.
3. [3]
  Harrison J R.The use of PTMEG in polyurethane coatings[J].Journal of Elastomers and Plastics,1985,17(1):6.
4. [4]
  Yi Y H,Ma R Y.Study of the main influence factors on compression set of PTMG based polyurethane elastomer[J].Advanced Materials Research,2012,630:67.
5. [5]
  Daud F N,Ahmad A,Badri K H.Preparation and characterization of plasticized palm-based polyurethane solid polymer electrolyte[J].AIP Conference Proceedings,2013,1571:775.
6. [6]
  Bonfi M,Sirkecioglu A,Bingol-Ozakpinar O,et al.Castor oil and PEG-based shape memory polyurethane films for biomedical applications[J].Journal of Applied Polymer Science,2014,131(15):686.
7. [7]
  Decker C,Masson F,Schwalm R.Weathering resistance of waterbased UV-cured polyurethane-acrylate coatings[J].Polymer Degradation and Stability,2004,83(2):309.
8. [8]
  王鹏,罗建斌,杜民慧,等.以PEG和PTMG为混合软段的聚氨酯的合成、表征及血液相容性研究[J].生物医学工程学杂志,2005,22(4):734.
9. [9]
  方少明,高丽君,周立明,等.聚醚的种类对丙烯酸酯类聚氨酯材料性能的影响[J].塑料,2005,34(3):46.
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

李敏, 周立明, 高丽君, 等. 丙烯酸酯类聚氨酯材料耐候性的研究[J]. 轻工学报, 2014, 29(6): 43-47. doi: 10.3969/j.issn.2095-476X.2014.06.011

引用本文: 李敏, 周立明, 高丽君, 等. 丙烯酸酯类聚氨酯材料耐候性的研究[J]. 轻工学报, 2014, 29(6): 43-47. doi: 10.3969/j.issn.2095-476X.2014.06.011

丙烯酸酯类聚氨酯材料耐候性的研究

郑州轻工业学院河南省表界面科学重点实验室, 河南郑州 450001

收稿日期: 2014-09-05
网络出版日期: 2014-11-15

基金项目: 国家自然科学基金项目(21271159)郑州轻工业学院博士基金项目(2011BSJJ003)河南省基础与前沿技术研究计划项目(112300410143,132300410182)

关键词:

摘要: 以异佛尔酮-二异氰酸酯(IPDI)、聚四氢呋喃1000(PTMEG-1000)、聚乙二醇400(PEG-400)、甲基丙烯酸-β-羟乙酯(HEMA)为基本原料,合成了一类丙烯酸酯类聚氨酯大单体,然后用偶氮二异丁腈(AIBN)引发大单体聚合制备了一种高透明性的耐候性聚氨酯(PU)材料.利用FT-IR,XRD对所制备的PU材料进行表征和分析;通过冷冻和紫外光老化处理实验,研究了PU材料的耐候性.结果表明,PTMEG-1000含量的增加能显著提高PU材料的光学性能和热稳定性,PU材料在冷冻和紫外光照射条件下,综合性能与常温下相差不大,表明其具有良好的耐候性.其中PU-3材料的综合性能较佳,其常温下透光率为92.1%,拉伸强度为13.1 MPa;在-26℃下透光率为84.7%,拉伸强度为15.7 MPa;经紫外光辐射后其透光率为74.3%,拉伸强度为11.5 MPa.

English Abstract

Research on the weathering resistance of poly (urethane-methacrylate) materials

He'nan Province Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry,Zhengzhou 450001,China

Received Date: 2014-09-05
Available Online: 2014-11-15

Abstract: Poly (urethane-methacrylate) macromonomers were synthesized based on isophorone diisocyanate (IPDI), poly (tetrahydrofuran) 1000 (PTMEG-1000), poly (ethylene glycol) 400 (PEG-400) and β-hydroxyethyl methacrylate (HEMA). Then high transparent poly (urethane-methacrylate) materials with weathering resistance were prepared by the polymerization of the macromonomers using 2,2-azo-bis-iso-butyro-nitrile (AIBN) as initiator. The obtained PU materials were characterized by FT-IR and XRD.The weathering resistance of PU materials was characterized under the condition of freezing and UV-irradiation. The results showed that the thermal stability and optical performance of PU materials increased with increasing PTMEG-1000 content, and comprehensive performance in freezing and UV-irradiation conditions were almost the same results as at room temperature, which indicated the materials owned good weatherability. PU-3 exhibited outstanding performance. The tensile strength and the transmittance of PU-3 were 13.1 MPa and 92.1% at room temperature, respectively. Its tensile strength and transmittance were 15.7 MPa and 84.7% at -26℃, respectively. And its tensile strength and transmittance were 11.5 MPa and 74.3% after UV-irradiation, respectively.