基于实时直接分析-高分辨质谱-独立成分分析法的改性聚硫橡胶的热解行为研究

刘应凡; 李腾飞; 彩倩杰; 孙晓丽; 孙雨安; 刘绍文; 王国庆

doi:10.3969/j.issn.2096-1553.2016.2.004

CN 41-1437/TS ISSN 2096-1553

基于实时直接分析-高分辨质谱-独立成分分析法的改性聚硫橡胶的热解行为研究

刘应凡 , 李腾飞 , 彩倩杰 , 孙晓丽 , 孙雨安 , 刘绍文 , 王国庆

刘应凡, 李腾飞, 彩倩杰, 等. 基于实时直接分析-高分辨质谱-独立成分分析法的改性聚硫橡胶的热解行为研究[J]. 轻工学报, 2016, 31(2): 29-34. doi: 10.3969/j.issn.2096-1553.2016.2.004

引用本文: 刘应凡, 李腾飞, 彩倩杰, 等. 基于实时直接分析-高分辨质谱-独立成分分析法的改性聚硫橡胶的热解行为研究[J]. 轻工学报, 2016, 31(2): 29-34. doi: 10.3969/j.issn.2096-1553.2016.2.004

LIU Ying-fan, LI Teng-fei, CAI Qian-jie, et al. Investigation of thermal decomposition behavior of modified polysulfide rubber based on DART-HRMS-ICA[J]. Journal of Light Industry, 2016, 31(2): 29-34. doi: 10.3969/j.issn.2096-1553.2016.2.004

Citation: LIU Ying-fan, LI Teng-fei, CAI Qian-jie, et al. Investigation of thermal decomposition behavior of modified polysulfide rubber based on DART-HRMS-ICA[J]. Journal of Light Industry, 2016, 31(2): 29-34. doi: 10.3969/j.issn.2096-1553.2016.2.004

基于实时直接分析-高分辨质谱-独立成分分析法的改性聚硫橡胶的热解行为研究

郑州轻工业学院材料与化学工程学院, 河南郑州 450001;
郑州裕昌实业有限公司, 河南郑州 450123

通讯作者: 王国庆

基金项目: 国家自然科学基金项目(21171115,21576248)
中图分类号: O657

Investigation of thermal decomposition behavior of modified polysulfide rubber based on DART-HRMS-ICA

College of Material and Chemical Enginnering, Zhengzhou University of Light Industry, Zhengzhou 450001, China;
Zhengzhou Yuchang Industrial Co., Ltd., Zhengzhou 450123, China

Corresponding author: WANG Guo-qing,

Received Date: 2015-09-13
Available Online: 2016-03-15
CLC number: O657

摘要: 采用实时直接分析-高分辨质谱-独立成分分析(DART-HRMS-ICA)法对改性聚硫橡胶样品的热解行为进行研究.首先进行DART检测条件的优化,然后在该优化条件下,对在不同离子源温度条件下得到的2个独立成分(IC-1和IC-2)进行ICA解析.结果表明,当样品传输速度为0.5 mm/s,离子源栅极电压为150 V时,样品的离子采集效果和离子化的信号强度都较好;样品在200℃以下时较为稳定;IC-1在200℃时开始受热分解,在350℃时可持续分解为以IC-2为表征的其他较小分子量组成的特征组分.改性聚硫橡胶在常温环境中具有很好的热稳定性,能够广泛应用于工业生产.
- 实时直接分析-高分辨质谱-独立成分分析法 /
- 改性聚硫橡胶 /
- 热解行为
Abstract: The thermal decomposition behavior of modified polysulfide rubber (MPR) was investigated by direct analysis in real time-high resolution mass spectrometry (DART-HRMS) independent component analysis (ICA). The DART conditions were optimized, and then two independent component (IC-1 and IC-2) obtained with different ion source temperature under the optimal conditions were processed by ICA. The results showed that ion collection effect of the sample and ionization signal strength were better when sample transmission speed was 0.5 mm/s and ion source grid voltage was 150 V. The sample had good stability when the temperature was lower than 200℃. IC-1 began to decompose at 200℃, and the sample could be decomposed as IC-2 which could characterize the components with lower molecular weights at 350℃. Modified polysulfide rubber had good thermal stability at room temperature environment, and could be widely used in industrial production.
1. [1]
  宋英红,杨晓东,吴松华.液体聚硫橡胶的改性技术研究进展[J].合成橡胶工业,2013,36(2):158.
2. [2]
3. [3]
4. [4]
  王国庆,彩倩杰,刘云,等.顶空-气相色谱-质谱法测定改性聚硫橡胶中挥发性成分[J].郑州轻工业学院学报(自然科学版),2015, 30(2):1.
5. [5]
  张佳玲,霍飞凤,周志贵,等.实时直接分析质谱的原理及应用[J].化学进展,2012,24(1):101.
6. [6]
  GROSS J H.Direct analysis in real time-a critical review on DART-MS[J].Analytical and bioanalytical chemistry, 2014, 406(1):63.
7. [7]
  廖杰,刘娜,刘春胜.DART-质谱及其在药物分析中的应用[J].药物分析杂志, 2011,31(10):2008.
8. [8]
  WANG G Q,HOU Z Y,SUN Y A,et al.Investigation of pyrolysis behavior of carbofuran by pyrolysis-gas chromatography-mass spectrometry[J].Journal of hazardous materials,2006,129(1/3):22.
9. [9]
  王国庆,彭杨,刘绍文,等.基于自适应核独立成分分析的活性二氧化锰助剂光谱信息的提取[J].光谱学与光谱分析,2011,31(5):1340.
10. [10]
  孙晓丽,王艳军,彩倩杰,等.基于高分辨质谱独立成分分析的黄芩炮制过程分析[J].河南师范大学学报(自然科学版),2014,42(3):70.
11. [11]
  王建玲,赵建波,刘应凡,等.基于相依成分分析-红外光谱法的黄芩炮制过程分析[J].光谱学与光谱分析,2013,33(8):2096.
1. [1]
  章存勇 , 庄海锋 , 时雅琪 , 邹鹏 , 丁乃红 , 纵坤 , 贾良元 , 郭东锋 . 国内外雪茄烟叶热解产物差异性研究. 轻工学报, 2024, 0(0): -.
2. [2]
  章存勇 , 庄海锋 , 时雅琪 , 邹鹏 , 丁乃红 , 纵坤 , 贾良元 , 郭东锋 . 国内外雪茄烟叶热解产物差异性研究. 轻工学报, 2024, 39(5): 118-126. doi: 10.12187/2024.05.014
3. [3]
  刘广超 , 邓莎 , 高峄涵 , 吴涛 , 邓锐杰 . 加热卷烟辊压法薄片丝吸湿性影响因素研究. 轻工学报, 2024, 39(5): 109-117. doi: 10.12187/2024.05.013
4. [4]
  池哲翔 , 廖敏 , 史尚 , 李声毅 , 廖芸 , 丁冬 . 国外烟草活性成分提取及纤维材料利用现状与展望. 轻工学报, 2024, 0(0): -.

点击查看大图

计量

PDF下载量: 46
文章访问数: 1247
引证文献数: 0

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

基于实时直接分析-高分辨质谱-独立成分分析法的改性聚硫橡胶的热解行为研究

通讯作者: 王国庆

郑州轻工业学院材料与化学工程学院, 河南郑州 450001;
郑州裕昌实业有限公司, 河南郑州 450123

收稿日期: 2015-09-13
网络出版日期: 2016-03-15

基金项目: 国家自然科学基金项目(21171115,21576248)

关键词:

摘要: 采用实时直接分析-高分辨质谱-独立成分分析(DART-HRMS-ICA)法对改性聚硫橡胶样品的热解行为进行研究.首先进行DART检测条件的优化,然后在该优化条件下,对在不同离子源温度条件下得到的2个独立成分(IC-1和IC-2)进行ICA解析.结果表明,当样品传输速度为0.5 mm/s,离子源栅极电压为150 V时,样品的离子采集效果和离子化的信号强度都较好;样品在200℃以下时较为稳定;IC-1在200℃时开始受热分解,在350℃时可持续分解为以IC-2为表征的其他较小分子量组成的特征组分.改性聚硫橡胶在常温环境中具有很好的热稳定性,能够广泛应用于工业生产.

English Abstract

Investigation of thermal decomposition behavior of modified polysulfide rubber based on DART-HRMS-ICA

Corresponding author: WANG Guo-qing,

College of Material and Chemical Enginnering, Zhengzhou University of Light Industry, Zhengzhou 450001, China;
Zhengzhou Yuchang Industrial Co., Ltd., Zhengzhou 450123, China

Received Date: 2015-09-13
Available Online: 2016-03-15

Abstract: The thermal decomposition behavior of modified polysulfide rubber (MPR) was investigated by direct analysis in real time-high resolution mass spectrometry (DART-HRMS) independent component analysis (ICA). The DART conditions were optimized, and then two independent component (IC-1 and IC-2) obtained with different ion source temperature under the optimal conditions were processed by ICA. The results showed that ion collection effect of the sample and ionization signal strength were better when sample transmission speed was 0.5 mm/s and ion source grid voltage was 150 V. The sample had good stability when the temperature was lower than 200℃. IC-1 began to decompose at 200℃, and the sample could be decomposed as IC-2 which could characterize the components with lower molecular weights at 350℃. Modified polysulfide rubber had good thermal stability at room temperature environment, and could be widely used in industrial production.

参考文献 (11) 相关文章 (4)