JOURNAL OF LIGHT INDUSTRY

CN 41-1437/TS  ISSN 2096-1553

Volume 31 Issue 5
September 2016
Article Contents
LI Shi-ping, MA Lin, ZHU Dong-liang, et al. Amadori compounds of dipeptides: synthesis,characterization and application in cigarettes[J]. Journal of Light Industry, 2016, 31(5): 8-14. doi: 10.3969/j.issn.2096-1553.2016.5.002
Citation: LI Shi-ping, MA Lin, ZHU Dong-liang, et al. Amadori compounds of dipeptides: synthesis,characterization and application in cigarettes[J]. Journal of Light Industry, 2016, 31(5): 8-14. doi: 10.3969/j.issn.2096-1553.2016.5.002 shu

Amadori compounds of dipeptides: synthesis,characterization and application in cigarettes

  • Corresponding author: MA Lin, 
  • Received Date: 2016-01-23
    Available Online: 2016-09-15
  • Three dipeptide Amadori intermediates (APs) were prepared by three representative dipeptide Gly-Gln, Ala-Gln and Gly-Gly as the nitrogen source, and glucose as sugar sources. The reaction process was monitored by HPLC to compare reactivity of dipeptides, the reactivity order is Ala-Gln> Gly-Gln> Gly-Gly. The purity and fracture modes of three dipeptide APs were characterized and analysis using LC-MS/MS and ESI-MS/MS.The results showed that the LC/MS purity of three dipeptide APs was up to 95% (Gly-Gln-APs), 97% (Ala-Gln-APs) and 98% (Gly-Gly-APs). Three fracture pattern of dipeptide APs was similar, the main fragment ions including loss of sugar molecules formed [M-162]+ and [M-180]+ fragment ions; and loss of water molecule is formed [M-36]+ and [M-84]+ ions.The cigarette application evaluation showed that the three dipeptide APs have encountered with incense smoke harmonize and improve the aroma and the amount of gas concentration, wherein Ala-Gln-APs shows the best effects. An obvious positive effect could be found both in aroma and taste characteristics.
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