香紫苏油主成分含量测定及其香气贡献评价

白冰; 楚首道; 杨靖; 张改红; 贾春晓; 毛多斌

doi:10.3969/j.issn.2096-1553.2018.01.002

CN 41-1437/TS ISSN 2096-1553

“关于规范使用生成式人工智能工具的启事

香紫苏油主成分含量测定及其香气贡献评价

白冰 , 楚首道 , 杨靖 , 张改红 , 贾春晓 , 毛多斌

白冰, 楚首道, 杨靖, 等. 香紫苏油主成分含量测定及其香气贡献评价[J]. 轻工学报, 2018, 33(1): 7-12. doi: 10.3969/j.issn.2096-1553.2018.01.002

引用本文: 白冰, 楚首道, 杨靖, 等. 香紫苏油主成分含量测定及其香气贡献评价[J]. 轻工学报, 2018, 33(1): 7-12. doi: 10.3969/j.issn.2096-1553.2018.01.002

BAI Bing, CHU Shoudao, YANG Jing, et al. Main components determination and their contribution to odor in clary sage (Salvia sclarea L.) oil[J]. Journal of Light Industry, 2018, 33(1): 7-12. doi: 10.3969/j.issn.2096-1553.2018.01.002

Citation: BAI Bing, CHU Shoudao, YANG Jing, et al. Main components determination and their contribution to odor in clary sage (Salvia sclarea L.) oil[J]. Journal of Light Industry, 2018, 33(1): 7-12. doi: 10.3969/j.issn.2096-1553.2018.01.002

香紫苏油主成分含量测定及其香气贡献评价

白冰 ¹ ,
楚首道 ¹ ,
杨靖 ¹ ,
张改红 ¹ ,
贾春晓 ² ,
毛多斌 ^{1

,}

郑州轻工业学院食品与生物工程学院, 河南郑州 450001;
郑州轻工业学院材料与化学工程学院, 河南郑州 450001

通讯作者: 毛多斌

基金项目: 中国烟草总公司重点科技项目（110201402033）
中图分类号: TS47

Main components determination and their contribution to odor in clary sage (Salvia sclarea L.) oil

College of Food and Bioengineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China;
College of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China

Corresponding author: MAO Duobin,

Received Date: 2017-04-24
Available Online: 2018-01-15
CLC number: TS47

摘要: 以苯甲醇为内标物，选用HP-5MS毛细管色谱柱，采用GC-MS法对香紫苏油中10种主要成分进行含量测定，并对其香气阈值和香气活力值进行测定和计算.结果表明：该方法可使样品中各组分很好地分离，线性方程相关系数大于0.999，加标回收率为90.6%~97.2%，检出限为9.5~232.8 ng/L，说明该方法重复性和灵敏度良好；香紫苏油中芳樟醇和乙酸芳樟酯的含量分别为20.3%和42.7%，香气阈值较低且香气活力值远高于其他成分，对香紫苏油香气贡献最大，与嗅香评价结果一致.
- 香紫苏油 /
- 气相色谱-质谱联用 /
- 香气阈值 /
- 香气活力值
Abstract: The selected ion monitoring (SIM) was used as the mass spectrum signal acquisition mode. UsingHP-5MS capillary column, a method for determination of ten compounds in clary sage (Salvia sclarea L.) oil has been developed.Odor threshold values of ten compounds were determined,and odor active values were obtained.The results showed that:Benzyl alcohol was used as an internal standard.The samples were separated on a DB-5 capillary column.The selected ion monitoring (SIM) was used as the mass spectrum signal acquisition mode.The components of the sample were well separated in the experimental conditions above,and had good linearity with the correlation coefficients higher than 0.999.The average recoveries were in the range of 90.6%~97.2%.The limits of detection (S/N ≥ 10) were in the range of 9.5~232.8 ng/L, which illustrated the good repetability and sensibility of the method.The compounds in clary sage oil with high odor active value were linaloolwith the content of 20.3% and linalyl acetate with the content of 42.7%.
- clary sage oil /
- gas chromatography-mass spectrometry(GC-MS) /
- odor threshold value /
- odor active value
1. [1]
  SIENKIEWICZ M,GŁOWACKA A,POZNA Ń-SKA-KUROWSKA K,et al.The effect of clary sage oil on staphylococci responsible for wound infections[J].Postepy Dermatologii I Alergologii,2015,32(1):21.
2. [2]
  HRISTOVA Y,GOCHEV V,WANNER J,et al.Chemical composition and antifungal activity of essential oil of Salvia sclarea L.from Bulgaria against isolates of Candida species[J].Journal of Bioscience & Biotechnology,2013,2(1):161.
3. [3]
  胡忆雪,张楠,杨森艳,等.4种芳香植物精油抗焦虑作用的评价[J].上海交通大学学报(农业科学版),2013,31(4):58.
4. [4]
  鲁文华,许松林,王燕飞.从香紫苏油中分离提纯芳樟醇和乙酸芳樟酯工艺的研究[J].香料香精化妆品,2006(5):5.
5. [5]
  权美平.唇形科植物精油化学成分分析及提取工艺研究进展[J].食品工业,2013,34(10):193.
6. [6]
  范秉琳,史政海.香紫苏油化学成分的GC-MS分析[J].阜阳师范学院学报(自然科学版),2004,21(1):27.
7. [7]
  马松涛,赵继飚,党俊伟,等.用GC/MS联用技术分析香紫苏挥发油成分[J].河南科学,2003,21(6):725.
8. [8]
  李智宇,冒德寿,徐世娟,等.全二维气相色谱-飞行时间质谱分析香紫苏油中的挥发性成分[J].香料香精化妆品,2011,12(6):1.
9. [9]
  CAI J B,LIN P,ZHU X L.Comparative analysis of clary sage (S.sclarea L.) oil volatiles by GC-FTIR and GC-MS[J].Food Chemistry,2006,99:401.
10. [10]
  毛多斌,陈欢,杨靖,等.阈值测定在食品特征香气分析中的应用综述[J].郑州轻工业学院学报(自然科学版),2012,27(4):52.
11. [11]
  杨靖,毛多斌,陈芝飞,等.GC-MS/O技术测定卷烟烟气中巨豆三烯酮的香气活力值[J].中国烟草学报,2016,22(6):11.
1. [1]
  张丽华 , 陈云莉 , 石勇 , 李顺峰 , 查蒙蒙 , 李昌文 , 纵伟 , 王小媛 . 植物乳杆菌发酵对红枣汁挥发性香气成分的影响. 轻工学报, 2024, 0(0): -.
2. [2]
  李敏 , 贺姗姗 , 杨钰雯 . 改良QuEChERS方法结合超高效液相色谱测定火腿肠中杂环胺类化合物. 轻工学报, 2024, 39(5): 60-70. doi: 10.12187/2024.05.007
3. [3]
  吴晓东 , 刘畅 , 李俊 , 胡良志 , 贺凌晨 , 袁海霞 , 李强 , 黄锦标 . 基于高光谱检测的烟丝加香均匀性表征方法. 轻工学报, 2024, 39(5): 95-101. doi: 10.12187/2024.05.011
4. [4]
  张改红 , 许航 , 杜帅 , 徐月莹 , 石栋栋 , 薛晶晶 , 尚紫博 , 毛多斌 . 麦芽酚-β-D-葡萄糖苷的稳定性及其在卷烟加香中的应用. 轻工学报, 2024, 39(5): 102-108. doi: 10.12187/2024.05.012
5. [5]
  朱晓兰 , 李宽 , 赵勇 , 袁广翔 , 汪金玲 , 俞京 . 酶萃取及组氨酸Heyns化合物加香对再造梗丝品质的影响. 轻工学报, 2024, 0(0): -.
6. [6]
  张新龙 , 赵尔婉 , 黄家乐 , 冯媛 , 于国锋 , 许春平 . 基于美拉德反应的红茶茶末烟用香料的制备及加香效果研究. 轻工学报, 2024, 39(6): 57-69. doi: 10.12187/2024.06.007
7. [7]
  朱晓兰 , 李宽 , 赵勇 , 袁广翔 , 汪金玲 , 俞京 . 酶萃取及组氨酸Heyns化合物加香对再造梗丝品质的影响. 轻工学报, 2024, 39(6): 77-83. doi: 10.12187/2024.06.009
8. [8]
  吴启贤 , 陈子杰 , 崔要强 , 伍锦鸣 , 赵谋明 , 任胜超 , 冯云子 . 不同产地烟叶碱提香料卷烟加香效果及化学成分差异分析. 轻工学报, 2025, 40(1): 98-106,119. doi: 10.12187/2025.01.012
9. [9]
  史清照 , 范武 , 任瑞冰 , 柴国璧 , 张文龙 , 张启东 , 张建勋 , 李河霖 . 基于膜分离及柱色谱技术的烟草提取物精加工产品的制备. 轻工学报, 2025, 0(0): -.
10. [10]
  胡新楠 , 朱成凯 , 胡中泽 , 纪执立 , 金伟平 , 郭城 , 沈汪洋 . 复配比对明胶-羟丙基甲基纤维素双水相体系微观结构和流变特性的影响. 轻工学报, 2024, 0(0): -.
11. [11]
  胡新楠 , 朱成凯 , 胡中泽 , 纪执立 , 金伟平 , 郭城 , 沈汪洋 . 复配比对明胶-羟丙基甲基纤维素双水相体系微观结构和流变特性的影响. 轻工学报, 2025, 40(1): 11-20. doi: 10.12187/2025.01.002

点击查看大图

计量

PDF下载量: 134
文章访问数: 11034
引证文献数: 0

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

白冰, 楚首道, 杨靖, 等. 香紫苏油主成分含量测定及其香气贡献评价[J]. 轻工学报, 2018, 33(1): 7-12. doi: 10.3969/j.issn.2096-1553.2018.01.002

引用本文: 白冰, 楚首道, 杨靖, 等. 香紫苏油主成分含量测定及其香气贡献评价[J]. 轻工学报, 2018, 33(1): 7-12. doi: 10.3969/j.issn.2096-1553.2018.01.002

香紫苏油主成分含量测定及其香气贡献评价

通讯作者: 毛多斌

郑州轻工业学院食品与生物工程学院, 河南郑州 450001;
郑州轻工业学院材料与化学工程学院, 河南郑州 450001

收稿日期: 2017-04-24
网络出版日期: 2018-01-15

基金项目: 中国烟草总公司重点科技项目（110201402033）

关键词:

摘要: 以苯甲醇为内标物，选用HP-5MS毛细管色谱柱，采用GC-MS法对香紫苏油中10种主要成分进行含量测定，并对其香气阈值和香气活力值进行测定和计算.结果表明：该方法可使样品中各组分很好地分离，线性方程相关系数大于0.999，加标回收率为90.6%~97.2%，检出限为9.5~232.8 ng/L，说明该方法重复性和灵敏度良好；香紫苏油中芳樟醇和乙酸芳樟酯的含量分别为20.3%和42.7%，香气阈值较低且香气活力值远高于其他成分，对香紫苏油香气贡献最大，与嗅香评价结果一致.

English Abstract

Main components determination and their contribution to odor in clary sage (Salvia sclarea L.) oil

Corresponding author: MAO Duobin,

College of Food and Bioengineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China;
College of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China

Received Date: 2017-04-24
Available Online: 2018-01-15

Abstract: The selected ion monitoring (SIM) was used as the mass spectrum signal acquisition mode. UsingHP-5MS capillary column, a method for determination of ten compounds in clary sage (Salvia sclarea L.) oil has been developed.Odor threshold values of ten compounds were determined,and odor active values were obtained.The results showed that:Benzyl alcohol was used as an internal standard.The samples were separated on a DB-5 capillary column.The selected ion monitoring (SIM) was used as the mass spectrum signal acquisition mode.The components of the sample were well separated in the experimental conditions above,and had good linearity with the correlation coefficients higher than 0.999.The average recoveries were in the range of 90.6%~97.2%.The limits of detection (S/N ≥ 10) were in the range of 9.5~232.8 ng/L, which illustrated the good repetability and sensibility of the method.The compounds in clary sage oil with high odor active value were linaloolwith the content of 20.3% and linalyl acetate with the content of 42.7%.