H<sub>2</sub>SO<sub>4</sub>改性凹凸棒土在葡萄糖脱水制备5-羟甲基糠醛过程中的催化性能研究

杨凤丽; 梁国斌; 顾宇阳

doi:10.3969/j.issn.2096-1553.2019.01.009

January 2019

Article Contents

YANG Fengli, LIANG Guobin and GU Yuyang. Study on catalytic performance of H2SO4 modified attapulgite in the process of dehydration of glucose to prepare 5-hydroxymethylfurfural[J]. Journal of Light Industry, 2019, 34(1): 64-70. doi: 10.3969/j.issn.2096-1553.2019.01.009

Citation: YANG Fengli, LIANG Guobin and GU Yuyang. Study on catalytic performance of H2SO4 modified attapulgite in the process of dehydration of glucose to prepare 5-hydroxymethylfurfural[J]. Journal of Light Industry, 2019, 34(1): 64-70. doi: 10.3969/j.issn.2096-1553.2019.01.009 shu

Study on catalytic performance of H₂SO₄ modified attapulgite in the process of dehydration of glucose to prepare 5-hydroxymethylfurfural

Technology School of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou 213000, China

Received Date: 2018-07-05

Abstract

The attapulgite modified by H₂SO₄ was used as a solid acid catalyst to study the dehydration of the bio-based platform compound 5-hydroxymethylfurfural (HMF). The results showed that the Bronsted acid sites increased when the attapulgite was modified by different concentrations of H₂SO₄. When the concentration of H₂SO₄ was 1.0 mol/L, there were more Bronsted acid sites and Lewis acid sites. The preparation of HMF had the best effect, and the yield could reach 46.6%. The catalyst showed good stability in the aqueous system.Repeated use of the catalyst for 4 times, the HMF yield was above 46%, and the activity did not change significantly.
- sulfuric acid modification,
- attapulgite,
- 5-hydroxymethylfurfural,
- solid acid catalyst
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