进口沉香挥发性成分的HS-GC-MS分析

孙雨安; 于文浩; 王国庆; 李振兴; 王珂; 张钰珠

doi:10.3969/j.issn.2096-1553.2019.02.009

CN 41-1437/TS ISSN 2096-1553

孙雨安 , 于文浩 , 王国庆 , 李振兴 , 王珂 , 张钰珠

孙雨安, 于文浩, 王国庆, 等. 进口沉香挥发性成分的HS-GC-MS分析[J]. 轻工学报, 2019, 34(2): 63-70. doi: 10.3969/j.issn.2096-1553.2019.02.009

引用本文: 孙雨安, 于文浩, 王国庆, 等. 进口沉香挥发性成分的HS-GC-MS分析[J]. 轻工学报, 2019, 34(2): 63-70. doi: 10.3969/j.issn.2096-1553.2019.02.009

SUN Yu, YU Wenhao, WANG Guoqing, et al. HS-GC-MS analysis of volatile components in imported agilawood[J]. Journal of Light Industry, 2019, 34(2): 63-70. doi: 10.3969/j.issn.2096-1553.2019.02.009

Citation: SUN Yu, YU Wenhao, WANG Guoqing, et al. HS-GC-MS analysis of volatile components in imported agilawood[J]. Journal of Light Industry, 2019, 34(2): 63-70. doi: 10.3969/j.issn.2096-1553.2019.02.009

进口沉香挥发性成分的HS-GC-MS分析

郑州轻工业大学材料与化学工程学院, 河南郑州 450001

作者简介: 孙雨安(1964-),男,河南省郑州市人,郑州轻工业大学教授,主要研究方向为色谱分析.;

基金项目: 国家自然科学基金项目（81373462）；国家自然科学基金国际合作与交流基金中泰合作项目（8151101082）
中图分类号: O657.63;R282

HS-GC-MS analysis of volatile components in imported agilawood

College of Materials and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China
Received Date: 2018-08-06

CLC number: O657.63;R282

摘要: 采用顶空气相色谱-质谱联用（HS-GC-MS）技术对产自5个国家（加里曼丹、马来西亚、孟加拉国、印度、印度尼西亚）的10个沉香样品的挥发性成分进行分析.结果表明，10个沉香样品的挥发性成分主要是芳香族类和倍半萜类化合物，相同产地但形态不同的沉香样品的挥发性组分种类和相对含量均存在一定差异，不同产地沉香样品的挥发性组分也呈现不同的差异，甘香烯、（+）-环苜蓿烯只在马来西亚沉香样品中检出，可作为该产地沉香的特征性成分；α-古芸烯和β-愈创木烯只在印度尼西亚沉香样品中检出，可作为该产地沉香的特征性成分；（+）-α-长叶蒎烯和α-荜澄茄油烯只在印度沉香样品中检出，可作为该产地沉香的特征性成分；产自印度尼西亚的沉香样品中醇类的种类和含量明显低于其他产地.该研究结果为沉香挥发性成分的快速检测和产地鉴别提供了新的思路.
- 进口沉香 /
- 挥发性成分 /
- 顶空气相色谱-质谱联用
Abstract: The volatile components of 10 agarwood samples from 5 countries (Kalimantan, Malaysia, Bangladesh, India, Indonesia) were analyzed by headspace gas chromatography-mass spectrometry (HS-GC-MS). The results showed that the volatile components of 10 agarwood samples were mainly aromatic and sesquiterpenoids. The types and relative contents of volatile components of agarwood samples with the same origin but different morphology were different. The volatile components of the samples also showed certain differences. The mannene and (+)-cyclodecene were only detected in the agarwood samples of Malaysia and could be used as the characteristic components of the agarwood in the producing area; α-cluene and β-Guaiacrox were only detected in Indonesian agarwood samples and could be used as the characteristic component of the agarwood in this area; (+)-α-long-leafene and α-carboene were only detected in Indian agarwood samples and could be used as the characteristic component of agarwood in this area; the types and contents of alcohols in agarwood samples from Indonesia were significantly lower than those in other places. The results could provide a new idea for the rapid detection and identification of the agarwood production area.
- imported agilawood /
- volatile component /
- headspace gas chromatography-mass spectrum
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沈阳化工大学材料科学与工程学院沈阳 110142

孙雨安, 于文浩, 王国庆, 等. 进口沉香挥发性成分的HS-GC-MS分析[J]. 轻工学报, 2019, 34(2): 63-70. doi: 10.3969/j.issn.2096-1553.2019.02.009

引用本文: 孙雨安, 于文浩, 王国庆, 等. 进口沉香挥发性成分的HS-GC-MS分析[J]. 轻工学报, 2019, 34(2): 63-70. doi: 10.3969/j.issn.2096-1553.2019.02.009

SUN Yu, YU Wenhao, WANG Guoqing, et al. HS-GC-MS analysis of volatile components in imported agilawood[J]. Journal of Light Industry, 2019, 34(2): 63-70. doi: 10.3969/j.issn.2096-1553.2019.02.009

进口沉香挥发性成分的HS-GC-MS分析

作者简介:孙雨安(1964-),男,河南省郑州市人,郑州轻工业大学教授,主要研究方向为色谱分析.

郑州轻工业大学材料与化学工程学院, 河南郑州 450001

收稿日期: 2018-08-06

基金项目: 国家自然科学基金项目（81373462）；国家自然科学基金国际合作与交流基金中泰合作项目（8151101082）

关键词:

摘要: 采用顶空气相色谱-质谱联用（HS-GC-MS）技术对产自5个国家（加里曼丹、马来西亚、孟加拉国、印度、印度尼西亚）的10个沉香样品的挥发性成分进行分析.结果表明，10个沉香样品的挥发性成分主要是芳香族类和倍半萜类化合物，相同产地但形态不同的沉香样品的挥发性组分种类和相对含量均存在一定差异，不同产地沉香样品的挥发性组分也呈现不同的差异，甘香烯、（+）-环苜蓿烯只在马来西亚沉香样品中检出，可作为该产地沉香的特征性成分；α-古芸烯和β-愈创木烯只在印度尼西亚沉香样品中检出，可作为该产地沉香的特征性成分；（+）-α-长叶蒎烯和α-荜澄茄油烯只在印度沉香样品中检出，可作为该产地沉香的特征性成分；产自印度尼西亚的沉香样品中醇类的种类和含量明显低于其他产地.该研究结果为沉香挥发性成分的快速检测和产地鉴别提供了新的思路.

English Abstract

HS-GC-MS analysis of volatile components in imported agilawood

College of Materials and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China

Received Date: 2018-08-06

Abstract: The volatile components of 10 agarwood samples from 5 countries (Kalimantan, Malaysia, Bangladesh, India, Indonesia) were analyzed by headspace gas chromatography-mass spectrometry (HS-GC-MS). The results showed that the volatile components of 10 agarwood samples were mainly aromatic and sesquiterpenoids. The types and relative contents of volatile components of agarwood samples with the same origin but different morphology were different. The volatile components of the samples also showed certain differences. The mannene and (+)-cyclodecene were only detected in the agarwood samples of Malaysia and could be used as the characteristic components of the agarwood in the producing area; α-cluene and β-Guaiacrox were only detected in Indonesian agarwood samples and could be used as the characteristic component of the agarwood in this area; (+)-α-long-leafene and α-carboene were only detected in Indian agarwood samples and could be used as the characteristic component of agarwood in this area; the types and contents of alcohols in agarwood samples from Indonesia were significantly lower than those in other places. The results could provide a new idea for the rapid detection and identification of the agarwood production area.

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