JOURNAL OF LIGHT INDUSTRY

CN 41-1437/TS  ISSN 2096-1553

Ag/g-C3N4可见光催化技术降解水中磺胺嘧啶的研究

宋亚丽 ,  张肖静 ,  朱艺博 ,  金雅霖 ,  张硕 ,  张宏忠

downloadPDF
宋亚丽, 张肖静, 朱艺博, 等. Ag/g-C3N4可见光催化技术降解水中磺胺嘧啶的研究[J]. 轻工学报, 2019, 34(6): 72-79. doi: 10.3969/j.issn.2096-1553.2019.06.010
引用本文: 宋亚丽, 张肖静, 朱艺博, 等. Ag/g-C3N4可见光催化技术降解水中磺胺嘧啶的研究[J]. 轻工学报, 2019, 34(6): 72-79. doi: 10.3969/j.issn.2096-1553.2019.06.010
shu
SONG Yali, ZHANG Xiaojing, ZHU Yibo, et al. Study on degradation of sulfadiazine in water by visible-light catalytic technology of Ag/g-C3N4[J]. Journal of Light Industry, 2019, 34(6): 72-79. doi: 10.3969/j.issn.2096-1553.2019.06.010
Citation: SONG Yali, ZHANG Xiaojing, ZHU Yibo, et al. Study on degradation of sulfadiazine in water by visible-light catalytic technology of Ag/g-C3N4[J]. Journal of Light Industry, 2019, 34(6): 72-79. doi: 10.3969/j.issn.2096-1553.2019.06.010
shu

Ag/g-C3N4可见光催化技术降解水中磺胺嘧啶的研究

  • 郑州轻工业大学 材料与化学工程学院/环境污染治理与生态修复河南省协同创新中心, 河南 郑州 450001

    • 作者简介: 宋亚丽(1988-),女,河南省开封市人,郑州轻工业大学讲师,博士,主要研究方向为光催化技术在水体修复中的应用.;

  • 基金项目: 国家自然科学基金项目（41701569）；郑州轻工业大学博士基金项目（2018BSJJ023）；河南省重点研发与推广专项（192102310243）；河南省创新型科技团队项目（CXTD2015023）

  • 中图分类号: X703

Study on degradation of sulfadiazine in water by visible-light catalytic technology of Ag/g-C3N4

  • College of Material and Chemical Engineering/He'nan Collaborative Innovation Centre of Environmental Pollution Control and Ecological Restoration, Zhengzhou University of Light Industry, Zhengzhou 450001, China

  • Received Date: 2019-06-13

    CLC number: X703

  • 摘要: 将Ag/g-C3N4（银/石墨相氮化碳）可见光催化技术应用于废水中磺胺嘧啶的去除，考察Ag/g-C3N4对磺胺嘧啶的降解效果、水质因素对降解效果的影响、降解机理、中间产物及其应用于实际水体时磺胺嘧啶的降解情况.结果表明：1）质量分数为5%的Ag/g-C3N4在可见光照射下能将磺胺嘧啶有效降解，去除率高达98.3%，且降解过程符合拟一级动力学模型；2）溶液的pH值和碱度对Ag/g-C3N4降解磺胺嘧啶的效果影响不大，但溶液中腐殖酸的存在对磺胺嘧啶的降解起抑制作用；3）在磺胺嘧啶的降解过程中，·O2-和光生空穴是主要的活性物种；4）降解过程主要产生4种中间产物，分别为2-氨基嘧啶、对氨基苯磺酸、羟基化磺胺嘧啶和硝基化磺胺嘧啶；5）以松花江水和生活污水的二级出水为水质背景时，Ag/g-C3N4对磺胺嘧啶的去除率分别为95.4%和77.5%.
    Abstract: Visible-light catalysis technology of Ag/g-C3N4 (silver/graphite carbon nitride) was applied to the removal of sulfadiazine in wastewater. The degradation effect of Ag/g-C3N4 on sulfadiazine and water quality factors,degradation mechanism,intermediate products and its degradation effect on sulfadiazine in actual water were investigated. The results showed that Ag/g-C3N4 with a mass fraction of 5% could effectively degrade sulfadiazine under visible-light irradiation,with a removal rate of up to 98.3%,and the degradation process conformed to the pseudo-first-order kinetic model; the pH and alkalinity of the solution Ag/g-C3N4 had little effect on the degradation of sulfadiazine,but the presence of humic acid in the solution inhibited the degradation of sulfadiazine; during the degradation of sulfadiazine,·O2- and photogenerated holes were the main activities species; the degradation process mainly produced 4 kinds of intermediate products,which were 2-aminopyrimidine,p-aminobenzenesulfonic acid,hydroxylated sulfadiazine,and nitrated sulfadiazine. When the Songhua River water and the secondary effluent of domestic sewage were used as the water quality background,the removal rates of Ag/g-C3N4 for sulfadiazine were 95.4% and 77.5%,respectively.
    1. [1]

      苟玺莹,张盼月,钱锋,等.UV/H2O2降解水中磺胺嘧啶影响因素及机理[J].环境工程学报,2017,11(11):5810.

    2. [2]

      KVMMERER K.Antibiotics in the aquatic environment-a review-part Ⅱ[J].Chemosphere,2009,75(4):435.

    3. [3]

      BU Q,WANG B,HUANG J,et al.Pharmaceuticals and personal care products in the aquatic environment in China:a review[J] Journal of Hazardous Materials,2013,262:189.

    4. [4]

      ZHANG T,LI B.Occurrence,transformation,and fate of antibiotics in municipal wastewater treatment plants[J].Critical Reviews in Environmental Science and Technology,2011,41:951.

    5. [5]

      王国庆,刘云,柯玮,等.超高效液相色谱-静电场轨道离子阱高分辨质谱联用筛查分析饲料中抗菌类药物[J].轻工学报,2016,31(4):15.

    6. [6]

      CLARA M,STRENN B,GANS O,et al.Removal of selected pharmaceuticals,fragrances and endocrine disrupting compounds in a membrane bioreactor and conventional wastewater treatment plants[J].Water Research,2005,39(19):4797.

    7. [7]

      DEWIL R,MANTZAVINOS D,POULIOS I,et al.New perspectives for advanced oxidation processes[J].Journal of Environmental Management,2017,195:93.

    8. [8]

      AO X,LIU W.Degradation of sulfamethoxazole by medium pressure UV and oxidants:Peroxymonosulfate,persulfate,and hydrogen peroxide[J].Chemical Engineering Journal,2017,313:629.

    9. [9]

      魏红,杨小雨,李克斌,等.UVA紫外辐射下H2O2/KI降解水中磺胺嘧啶[J].环境科学学报,2016,36(5):1697.

    10. [10]

      IOANNIDOU E,FRONTISTIS Z,ANTONOPOULOU M,et al.Solar photocatalytic degradation of sulfamethoxazole over tungsten modified TiO2[J].Chemical Engineering Journal,2017,318:143.

    11. [11]

      邵鹏辉.纳米氧化铁的优化制备及其可见光芬顿降解水中的双酚S[D].哈尔滨:哈尔滨工业大学,2017.

    12. [12]

      SONG Y,QI J,TIAN J,et al.Construction of Ag/g-C3N4 photocatalysts with visible-light photocatalytic activity for sulfamethoxazole degradation[J].Chemical Engineering Journal,2018,341:547.

    13. [13]

      BAI X,WANG L,WANG Y,et al.Enhanced oxidation ability of g-C3N4 photocatalyst via C60 modification[J].Applied Catalysis B:Environmental,2014(152/153):262.

    14. [14]

      宋亚丽,张光明,常爱敏,等.US/Zn0体系降解水中的对硝基苯甲酸[J].环境工程学报, 2014,8(5):1797.

    15. [15]

      WANG J,YANG Z,GAO X,et al.Core-shell g-C3N4@ZnO composites as photoanodes with double synergistic effects for enhanced visible-light photoelectrocatalytic activities[J].Applied Catalysis B:Environmental,2017,217:169.

    16. [16]

      宋亚丽.g-C3N4基可见光催化剂降解水中典型磺胺类抗生素的研究[D].哈尔滨:哈尔滨工业大学,2018.

    17. [17]

      CUI Y,DING Z,LIU P,et al.Metal-free activation of H2O2 by g-C3N4 under visible light irradiation for the degradation of organic pollutants[J].Physical Chemistry Chemical Physics,2012,14(4):1455.

    18. [18]

      YANG Y,LU X,JIANG J,et al.Degradation of sulfamethoxazole by UV,UV/H2O2 and UV/persulfate (PDS):Formation of oxidation products and effect of bicarbonate[J].Water Research,2017,118:196.

    19. [19]

      江进.高价态锰、铁氧化降解水中典型有机物的特性与机理研究[D].哈尔滨:哈尔滨工业大学,2009.

    20. [20]

      CHAN K,CHU W.Effect of humic acid on the photolysis of the pesticide atrazine in a surfactant-aided soil-washing system in acidic condition[J].Water Research,2005,39(10),2154.

  • 加载中
WeChat 点击查看大图
计量
  • PDF下载量:  6
  • 文章访问数:  1168
  • 引证文献数: 0
文章相关
  • 收稿日期:  2019-06-13
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
宋亚丽, 张肖静, 朱艺博, 等. Ag/g-C3N4可见光催化技术降解水中磺胺嘧啶的研究[J]. 轻工学报, 2019, 34(6): 72-79. doi: 10.3969/j.issn.2096-1553.2019.06.010
引用本文: 宋亚丽, 张肖静, 朱艺博, 等. Ag/g-C3N4可见光催化技术降解水中磺胺嘧啶的研究[J]. 轻工学报, 2019, 34(6): 72-79. doi: 10.3969/j.issn.2096-1553.2019.06.010
shu
SONG Yali, ZHANG Xiaojing, ZHU Yibo, et al. Study on degradation of sulfadiazine in water by visible-light catalytic technology of Ag/g-C3N4[J]. Journal of Light Industry, 2019, 34(6): 72-79. doi: 10.3969/j.issn.2096-1553.2019.06.010
Citation: SONG Yali, ZHANG Xiaojing, ZHU Yibo, et al. Study on degradation of sulfadiazine in water by visible-light catalytic technology of Ag/g-C3N4[J]. Journal of Light Industry, 2019, 34(6): 72-79. doi: 10.3969/j.issn.2096-1553.2019.06.010
shu

Ag/g-C3N4可见光催化技术降解水中磺胺嘧啶的研究

    作者简介:宋亚丽(1988-),女,河南省开封市人,郑州轻工业大学讲师,博士,主要研究方向为光催化技术在水体修复中的应用.
  • 郑州轻工业大学 材料与化学工程学院/环境污染治理与生态修复河南省协同创新中心, 河南 郑州 450001
  • 收稿日期: 2019-06-13
基金项目:  国家自然科学基金项目（41701569）；郑州轻工业大学博士基金项目（2018BSJJ023）；河南省重点研发与推广专项（192102310243）；河南省创新型科技团队项目（CXTD2015023）

摘要: 将Ag/g-C3N4（银/石墨相氮化碳）可见光催化技术应用于废水中磺胺嘧啶的去除，考察Ag/g-C3N4对磺胺嘧啶的降解效果、水质因素对降解效果的影响、降解机理、中间产物及其应用于实际水体时磺胺嘧啶的降解情况.结果表明：1）质量分数为5%的Ag/g-C3N4在可见光照射下能将磺胺嘧啶有效降解，去除率高达98.3%，且降解过程符合拟一级动力学模型；2）溶液的pH值和碱度对Ag/g-C3N4降解磺胺嘧啶的效果影响不大，但溶液中腐殖酸的存在对磺胺嘧啶的降解起抑制作用；3）在磺胺嘧啶的降解过程中，·O2-和光生空穴是主要的活性物种；4）降解过程主要产生4种中间产物，分别为2-氨基嘧啶、对氨基苯磺酸、羟基化磺胺嘧啶和硝基化磺胺嘧啶；5）以松花江水和生活污水的二级出水为水质背景时，Ag/g-C3N4对磺胺嘧啶的去除率分别为95.4%和77.5%.

English Abstract

参考文献 (20)

目录

/

返回文章

网站版权 © 轻工学报编辑部

地址：河南省郑州市科学大道136号邮编：450001

本系统由北京仁和汇智信息技术有限公司开发 技术支持： info@rhhz.net