贮存环境对甜味接装纸中纽甜衰减行为的影响
Effect of storage environment on the decay behavior of neotame in sweet tipping paper
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摘要: 利用高效液相色谱-二极管阵列检测器(HPLC-DAD)建立了烟用甜味接装纸中纽甜的检测方法,基于该方法分析了不同贮存环境(低温常湿、常温常湿、常温干燥)对纽甜含量的影响,并采用反应动力学模型对不同品牌接装纸在各环境下的衰减行为进行拟合。结果表明:1)所建立的检测方法在1.00~800.00 μg/mL质量浓度范围内线性良好,回收率和精密度较高,能够用于甜味接装纸中纽甜的检测分析;2)不同环境下,各品牌接装纸中纽甜衰减率均随贮存时间的延长而增加,低温常湿环境更利于甜味接装纸的稳定贮存,而常温干燥环境能促进甜味剂的衰减;3)不同品牌接装纸中纽甜的衰减行为分别符合不同的反应动力学模型,其衰减动力学过程受环境影响不同,这可能与接装纸的微观组织结构或纽甜与载体间的相互作用有关。Abstract: A method for the determination of neotame in tobacco sweet tipping paper was established by high performance liquid chromatography with diode array detector (HPLC-DAD). Based on this method, the effects of different storage environments (low temperature and normal humidity, normal temperature and normal humidity, normal temperature and dry) on the content of neotame were analyzed, and the decay behavior of different brands of tipping paper in various environments was fitted by reaction kinetics model. The results showed that the established analytical method exhibited good linearity in the concentration range of 1.00~800.00 μg/mL. The method had high recovery rate and precision, which could be applied for the detection and analysis of neotame in sweet tipping paper. Under different environments, the decay rate of neotame in all brands of tipping paper increased with the prolonged storage time. The low temperature and normal humidity environment was more conducive to the stable storage of sweet tipping paper, while the normal temperature and dry environment could promote the decay of neotame. The decay behavior of neotame in different brand tipping papers conformed to different reaction kinetic models.The decay kinetic process of different tipping paper was affected by the environment, which may be related to the microstructure of the tipping paper or the interaction between neotame and the carrier.
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Key words:
- sweet tipping paper /
- neotame /
- high performance liquid chromatography /
- decay rate /
- decay kinetics
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