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CN 41-1437/TS  ISSN 2096-1553

5种新疆特色植物色素的理化特性及其降解动力学研究

宋丽军 ,  龙勇益 ,  李中旭 ,  刘世琦 ,  张丽 ,  孙江怡

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宋丽军, 龙勇益, 李中旭, 等. 5种新疆特色植物色素的理化特性及其降解动力学研究[J]. 轻工学报, 2023, 38(3): 1-10. doi: 10.12187/2023.03.001
引用本文: 宋丽军, 龙勇益, 李中旭, 等. 5种新疆特色植物色素的理化特性及其降解动力学研究[J]. 轻工学报, 2023, 38(3): 1-10. doi: 10.12187/2023.03.001
shu
SONG Lijun, LONG Yongyi, LI Zhongxu, et al. Physicochemical properties and degradation kinetics of five Xinjiang characteristic plant pigments[J]. Journal of Light Industry, 2023, 38(3): 1-10. doi: 10.12187/2023.03.001
Citation: SONG Lijun, LONG Yongyi, LI Zhongxu, et al. Physicochemical properties and degradation kinetics of five Xinjiang characteristic plant pigments[J]. Journal of Light Industry, 2023, 38(3): 1-10. doi: 10.12187/2023.03.001
shu

5种新疆特色植物色素的理化特性及其降解动力学研究

  • 1. 河北科技师范学院 食品科技学院, 河北 秦皇岛 066600;

  • 2. 广西科技师范学院 食品与生化工程学院, 广西 来宾 546199;

  • 3. 塔里木大学 食品科学与工程学院, 新疆 阿拉尔 843300

    • 作者简介: 宋丽军(1982-),男,河北省保定市人,河北科技师范学院副教授,博士,主要研究方向为农产品精深加工。E-mail:slj176@163.com;

  • 基金项目: 河北科技师范学院科学研究基金资助项目(2023YB020)
    中央引导地方专项资金项目(兵财教2020-23号)
    广西科技师范学院科研基金项目(GXKS2022QN003)

  • 中图分类号: TS201.4

Physicochemical properties and degradation kinetics of five Xinjiang characteristic plant pigments

  • 1. College of Food Science and Technology, Hebei Normal University of Science & Technology, Qinhuangdao 066600, China;

  • 2. College of Food and Biochemical Engineering, Guangxi Science & Technology Normal University, Laibin 546199, China;

  • 3. College of Food Science and Engineering, Tarim University, Alar 843300, China

  • Received Date: 2022-12-17
    Accepted Date: 2023-02-17

    CLC number: TS201.4

  • 摘要: 对提取自5种新疆特色植物的花青素类色素进行理化特性、抗氧化活性和降解动力学研究,结果表明:不同色素提取物的颜色响应差异显著(P<0.05);黑枸杞色素(BWP)含有5种单体化合物,以锦葵素3-O-葡萄糖苷含量最高(23.18 μg/g DW);桑葚色素(MMP)含有4种单体化合物,以矢车菊素3-O-半乳糖苷含量最高(300.87 μg/g DW);玫瑰花色素(RFP)含有7种单体化合物,以飞燕草素3-O-葡萄糖苷含量最高(144.34 μg/g DW);葡萄皮色素(GPP)含有7种单体化合物,以飞燕草素3-O-葡萄糖苷含量最高(116.45 μg/g DW);紫苏叶色素(PLP)含有3种单体化合物,以矢车菊素含量最高(144.10 μg/g DW)。其中,GPP耐热性最好,降解初始温度为165.71℃。不同色素提取物热降解过程均符合一级反应动力学模型;当pH值为3.0时,PLP最稳定,活化能(Ea)为22.539 kJ/mol;当pH值为7.0时,RFP最稳定,Ea为13.851 kJ/mol。相关性分析表明色素提取物中花青素的含量与其抗氧化活性有显著相关性(P<0.05);RFP的体外抗氧化活性最强,其IC50DPPH和IC50ABTS分别为7.32 μg/mL和71.50 μg/mL,总抗氧化活性(T-AOC)为4 073.00 U/g DW。
    Abstract: In this study, five anthocyanin pigments were extracted from Xinjiang characteristic plants, and the physicochemical properties, antioxidant activities and degradation kinetics of these pigment extracts were explored. The results showed that there were significant differences in color responses of different pigment extracts (P<0.05). The black wolfberry pigments (BWP), medicine mulberry pigments (MMP), rose flower pigments (RFP), grape peel pigments (GPP), and perilla leaf pigments (PLP) mainly contained 5 compounds, 4 compounds, 7 compounds, 7 compounds, and 3 compounds, respectively. The compounds with the highest content in five pigment extracts were malvidin 3-O-glucoside (23.18 μg/g DW), cyanidin-3-galactoside (300.87 μg/g DW), delphinidin-3-O-glucoside (144.34 μg/g DW), delphinidin-3-O-glucoside (116.45 μg/g DW), and cyanidin (144.10 μg/g DW), respectively. Furthermore, GPP showed the highest heat resistance with a degradation temperature of 165.71 ℃. The thermal degradation of different pigment extracts conformed to the first-order reaction kinetics. Meanwhile, PLP showed the highest stability at pH 3.0, with a corresponding energy of activation (Ea) was 22.539 kJ/mol. RFP was the most stable at pH 7.0 (Ea=13.851 kJ/mol). Correlation analysis showed that there was a significant correlation between the content of anthocyanins in pigment extracts and their antioxidant activity (P<0.05). In addition, RFP exhibited the strongest antioxidant activities in vitro, and its 50% inhibiting concentration (IC50) on DPPH and ABTS radicals were 7.32 μg/mL and 71.50 μg/mL, respectively, the total antioxidant activity (T-AOC) was 4 073.00 U/g DW.
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宋丽军, 龙勇益, 李中旭, 等. 5种新疆特色植物色素的理化特性及其降解动力学研究[J]. 轻工学报, 2023, 38(3): 1-10. doi: 10.12187/2023.03.001
引用本文: 宋丽军, 龙勇益, 李中旭, 等. 5种新疆特色植物色素的理化特性及其降解动力学研究[J]. 轻工学报, 2023, 38(3): 1-10. doi: 10.12187/2023.03.001
shu
SONG Lijun, LONG Yongyi, LI Zhongxu, et al. Physicochemical properties and degradation kinetics of five Xinjiang characteristic plant pigments[J]. Journal of Light Industry, 2023, 38(3): 1-10. doi: 10.12187/2023.03.001
Citation: SONG Lijun, LONG Yongyi, LI Zhongxu, et al. Physicochemical properties and degradation kinetics of five Xinjiang characteristic plant pigments[J]. Journal of Light Industry, 2023, 38(3): 1-10. doi: 10.12187/2023.03.001
shu

5种新疆特色植物色素的理化特性及其降解动力学研究

    作者简介:宋丽军(1982-),男,河北省保定市人,河北科技师范学院副教授,博士,主要研究方向为农产品精深加工。E-mail:slj176@163.com
  • 1. 河北科技师范学院 食品科技学院, 河北 秦皇岛 066600;
  • 2. 广西科技师范学院 食品与生化工程学院, 广西 来宾 546199;
  • 3. 塔里木大学 食品科学与工程学院, 新疆 阿拉尔 843300
  • 收稿日期: 2022-12-17
  • 录用日期: 2023-02-17
基金项目:  河北科技师范学院科学研究基金资助项目(2023YB020)中央引导地方专项资金项目(兵财教2020-23号)广西科技师范学院科研基金项目(GXKS2022QN003)

摘要: 对提取自5种新疆特色植物的花青素类色素进行理化特性、抗氧化活性和降解动力学研究,结果表明:不同色素提取物的颜色响应差异显著(P<0.05);黑枸杞色素(BWP)含有5种单体化合物,以锦葵素3-O-葡萄糖苷含量最高(23.18 μg/g DW);桑葚色素(MMP)含有4种单体化合物,以矢车菊素3-O-半乳糖苷含量最高(300.87 μg/g DW);玫瑰花色素(RFP)含有7种单体化合物,以飞燕草素3-O-葡萄糖苷含量最高(144.34 μg/g DW);葡萄皮色素(GPP)含有7种单体化合物,以飞燕草素3-O-葡萄糖苷含量最高(116.45 μg/g DW);紫苏叶色素(PLP)含有3种单体化合物,以矢车菊素含量最高(144.10 μg/g DW)。其中,GPP耐热性最好,降解初始温度为165.71℃。不同色素提取物热降解过程均符合一级反应动力学模型;当pH值为3.0时,PLP最稳定,活化能(Ea)为22.539 kJ/mol;当pH值为7.0时,RFP最稳定,Ea为13.851 kJ/mol。相关性分析表明色素提取物中花青素的含量与其抗氧化活性有显著相关性(P<0.05);RFP的体外抗氧化活性最强,其IC50DPPH和IC50ABTS分别为7.32 μg/mL和71.50 μg/mL,总抗氧化活性(T-AOC)为4 073.00 U/g DW。

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