JOURNAL OF LIGHT INDUSTRY

CN 41-1437/TS  ISSN 2096-1553

Volume 32 Issue 4
July 2017
Article Contents
ZHANG Gai-hong, LIU Yu, LI Xue-long, et al. Study on synthesis of α-ionol-β-D-glucoside by phrase transfer catalytic method[J]. Journal of Light Industry, 2017, 32(4): 43-48. doi: 10.3969/j.issn.2096-1553.2017.4.007
Citation: ZHANG Gai-hong, LIU Yu, LI Xue-long, et al. Study on synthesis of α-ionol-β-D-glucoside by phrase transfer catalytic method[J]. Journal of Light Industry, 2017, 32(4): 43-48. doi: 10.3969/j.issn.2096-1553.2017.4.007 shu

Study on synthesis of α-ionol-β-D-glucoside by phrase transfer catalytic method

  • Received Date: 2016-06-08
    Accepted Date: 2016-12-28
    Available Online: 2017-07-15
  • α-ionol was synthesized from α-ionone via the selective reduction.α-ionol-β-D-glucoside was synthesized from α-ionol via the reaction with tetra-O-α-acetyl-D-glucopyranosyl bromide under the phase transfer catalyst to give the corresponding α-ionol-2,3,4,6-tetra-O-acetyl-β-D-glucoside,followed by deacetylation.The appropriate conditions for this glucosidation reaction were as follows:10% tetrabutyl ammonium bromide was added to catalyze a reaction between Br-glucose-tetraacetateand α-ionol at a ratio of 1.6:1 in CHCl3-H2O allowed to proceed for 8 h at 60 ℃.The yield rate of glycosylation reaction was 30%.The target products were characterized β-configuration by FT-IR,1H NMR and ESI-MS.
  • 加载中
    1. [1]

      李有桂,卢梦梦,朱成峰,等.甲基环戊烯醇酮-β-D-吡喃葡糖苷的合成及其热裂解[J].烟草科技,2015(6):45.

    2. [2]

      雷声,杨锡洪,解万翠,等.玫瑰醇-β-D-吡喃葡萄糖苷键合态香料前体的合成及结构表征[J].现代食品科技,2015,31(10):163.

    3. [3]

      XIE W C,GU X H,TAN Z C,et al.Thermal decomposition of two synthetic glycosides by TG,DSC and simultaneous Py-GC-MS analysis[J].J Therm Anal Calorim,2007,87(2):505.

    4. [4]

      孟广宇,曾世通,刘珊,等.β-紫罗兰醇-β-D-葡糖苷的合成及热解性质[J].食品科学,2012,33(20): 21.

    5. [5]

      方嵩.3-氧代-α-紫罗兰醇-β-D-吡喃葡萄糖苷的合成研究[D].合肥:合肥工业大学,2013.

    6. [6]

      陈振玲,张浩博,周宛虹,等.烟草中3-氧代-α-紫罗兰醇-β-D-吡喃葡萄糖苷的分离鉴定及其热解产物分析[J].烟草科技,2008(7):28.

    7. [7]

      王燕,刘志华,刘春波,等.烟草中两种紫罗兰醇葡萄糖苷衍生物的分离鉴定及热分析研究[J].分析测试学报,2012,31(1):22.

    8. [8]

      BRITO-ARIASM.Synthesis and Characterization of Glycosides[M].New York: Springer Science,2007.

    9. [9]

      ZENG S T,SUN S H,LIU S,et al.Synthesis of α-ionyl-β-D-glucoside and its property of flavor release[J].J Therm Anal Calorim,2014,115(2):1049.

Article Metrics

Article views(1353) PDF downloads(52) Cited by()

Ralated
    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return