用于分离废水中苯酚/苯胺的渗透汽化膜材料研究进展

韩光鲁; 陈哲; 樊凯奇; 张学波; 郝彬; 任静怡

doi:10.3969/j.issn.2096-1553.2019.05.010

September 2019

Article Contents

HAN Guanglu, CHEN Zhe, FAN Kaiqi, et al. Research progress on pervaporation membrane materials for separation of phenol/aniline from wastewater[J]. Journal of Light Industry, 2019, 34(5): 68-77. doi: 10.3969/j.issn.2096-1553.2019.05.010

Citation: HAN Guanglu, CHEN Zhe, FAN Kaiqi, et al. Research progress on pervaporation membrane materials for separation of phenol/aniline from wastewater[J]. Journal of Light Industry, 2019, 34(5): 68-77. doi: 10.3969/j.issn.2096-1553.2019.05.010 shu

Research progress on pervaporation membrane materials for separation of phenol/aniline from wastewater

College of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China

Received Date: 2018-12-21

Abstract

Starting from polymer membranes, inorganic membranes and organic-inorganic mixed matrix membranes, the progress of membrane materials for the separation of phenol-water and aniline-water systems by pervaporation technology in the past 20 years was reviewed. It was pointed out that the flux and separation factor of polymer membrane materials were low, and the trade-off effect was common, while the flux and separation factor of polyether copolyamide (PEBA) were kept at a high level, hybridization and other modification methods could be used to improve the separation performance; inorganic membrane materials had the disadvantages of poor mechanical properties, difficult processing and high cost, and related research contents were less; organic-inorganic mixed matrix membranes could combine the advantages of polymer membranes and inorganic membranes. The trade-off effect of the polymer membranes was effectively solved, but the compatibility of the inorganic particles with the polymer was not good, so that the membranes was prone to defects and the separation factor was lowered. In the future, the matrix membranes will become a hot research topic.By searching for particles that interact more strongly with the polymer, the compatibility of the doped particles with the polymer will be better, the dispersion will be more uniform, and the separation performance of the mixed matrix membranes will be improved.As the selection of porous materials, in addition to the development of new metal-organic framework MOFs materials, the modification of MOFs, the design of more efficient transport channels and so on are also a trend/development.
- phenol,
- aniline,
- pervaporation technology,
- separation,
- membrane material,
- metal-organic frame material
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沈阳化工大学材料科学与工程学院沈阳 110142

Research progress on pervaporation membrane materials for separation of phenol/aniline from wastewater

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