水凝胶在缓/控释肥料中应用的研究进展

王赫; 李晶晶; 魏宏亮; 王刚; 楚晖娟; 朱靖

doi:10.3969/j.issn.2096-1553.2017.6.006

水凝胶在缓/控释肥料中应用的研究进展

河南工业大学化学化工与环境学院, 河南郑州 450001
基金项目: 河南省科技攻关项目（152102110073）；河南工业大学博士基金项目（2016BS024）
中图分类号: TQ440

Applied research progress of hydrogels in slow/controlled fertilizer

School of Chemistry, Chemical and Environmental Engineering, He'nan University of Technology, Zhengzhou 450001, China
Received Date: 2017-07-20
Available Online: 2017-11-15
CLC number: TQ440

摘要: 对水凝胶应用于缓/控释肥料的研究进展进行了综述，发现将水凝胶用于缓/控释肥料制备，可以得到性能优异的保水缓/控释肥料，显著提高肥料和水资源的利用率.但保水缓/控释肥料存在成本高、不适宜工业化生产和不能完全实现肥料的释放周期与农作物的养分需求周期相一致等问题.探索肥料释放的机制与规律，通过控制保水缓/控释肥料特别是水凝胶的结构与组成，调控肥料的释放性能，制备出智能保水缓/控释肥料体系，以满足不同环境变化和不同农作物生长的需求，将是未来研究的重点和方向.
- 水凝胶 /
- 超吸水高分子 /
- 保水缓/控释肥料 /
- 复合凝胶 /
- 原位包埋 /
- 天然高分子
Abstract: The research progresses of hydrogels applied to slow/controlled release fertilizers were reviewed.It was found that water retention and slow/controlled fertilizer with distinguished properties could be obtained by applying hydrogels to slow/controlled fertilizer, resulting in raising utilization rate of fertilizer and water resources at the same time; and the limitations to the wide application of water retention and slow/controlled fertilizer were high cost, unsuitable to industrial production and difficult to realize the complete accord between release circle of fertilizer and demand circle of crops to nutrients. By exploring mechanism and laws of fertilizer release and controlling structure and component of fertilizer, especially structure and component of hydrogels, tuning its release properties, smart retention and slow/controlled fertilizer system could be fabricated. The fertilizer system can satisfy the need of different surroundings and the growth of different crops, which will be the further focus and direction of research.
- hydrogel /
- superabsor-bent polymer /
- water retention and slow/controlled release fertilizer /
- composite gel /
- in situ encapsulation /
- natural polymer
1. [1]
  ZHANG M Y,CHENG Z Q,ZHAO T Q,et al.Synthesis,characterization,and swelling behaviors of salt-sensitive maize branpoly(acrylic acid) superabsorbent hydrogel[J].Journal of Agricultural and Food Chemistry,2014,62(35):8867.
2. [2]
  WANG X,WANG C P,WANG X Y,et al.A polydopamine nanoparticle-knotted poly(ethylene glycol) hydrogel for on-demand drug delivery and chemo-photothermal therapy[J].Chemistry of Materials,2017,29(3):1370.
3. [3]
  JORDAN A M,KIM S E,DE VAN VOORDE K,et al.In situ fabrication of fiber reinforced three-dimensional hydrogel tissue engineering scaffolds[J].ACS Biomaterials Science & Engineering,2017,3(8):1869.
4. [4]
  LIAN M L,CHEN X,LU Y L,et al.Self-assembled peptide hydrogel as a smart biointerface for enzyme-based electrochemical biosensing and cell monitoring[J].ACS Applied Materials & Interfaces,2016,8(38):25036.
5. [5]
  LI D K,LI Q,BAI N N,et al.One-step synthesis of cationic hydrogel for efficient dye adsorption and its second use for emulsified oil separation[J].ACS Sustainable Chemistry & Engineering,2017,5(6):5598.
6. [6]
  IM K,DUONG NGUYEN N,KIM S,et al.Graphene-embedded hydrogel nanofibers for detection and removal of aqueous-phase dyes[J].ACS Applied Materials & Interfaces,2017,9(12):10768.
7. [7]
  AZEEM B,KUSHAARI K,MAN Z B,et al.Review on materials & methods to produce controlled release coated urea fertilizer[J].Journal of Controlled Release,2014,181:11.
8. [8]
  RABAT N E,HASHIM S,MAJID R A.Effect of different monomers on water retention properties of slow release fertilizer hydrogel[J].Procedia Engineering,2016,148:201.
9. [9]
  NI B L,LIU M,LYU S.Multifunctional slow-release urea fertilizer from ethylcellulose and superabsorbent coated formulations[J].Chemical Engineering Journal 2009,155(3):892.
10. [10]
  ESSAWY H A,GHAZY M B M,ABD EL-HAI F,et al.Superabsorbent hydrogels via graft polymerization of acrylic acid from chitosan-cellulose hybrid and their potential in controlled release of soil nutrients[J].International Journal of Biological Macromolecules,2016,89:144.
11. [11]
  SIAFU S I.Silicone doped chitosan-acrylamide coencapsulated urea fertilizer:an approach to controlled release fertilizers[J].Journal of Nanotechnology,2017,2017:1.
12. [12]
  RATTANAMANEE A,NIAMSUP H,SRISOMBAT L O,et al.Role of chitosan on some physical properties and the urea controlled release of the silk fibroin/gelatin hydrogel[J].Journal of Polymers and the Environment,2015,23(3):334.
13. [13]
  XIAO X M,YU L,XIE F W,et al.One-step method to prepare starch-based superabsorbent polymer for slow release of fertilizer[J].Chemical Engineering Journal,2017,309:607.
14. [14]
  ZHONG K,LIN Z T,ZHENG X L,et al.Starch derivative-based superabsorbent with integration of water-retaining and controlled-release fertilizers[J].Carbohydrate Polymers,2013,92(2):1367.
15. [15]
  QIAO D L,LIU H S,YU L,et al.Preparation and characterization of slow-release fertilizer encapsulated by starch-based superabsorbent polymer[J].Carbohydrate Polymers,2016,147:146.
16. [16]
  IBRAHIM S,NAGIEB Z A,SULTAN M.Eco-friendly hydrogel based on cellulose as controlled-urea release packaging system[J].Annals of Advanced Sciences,2017,1(1):18.
17. [17]
  NI B L,LIU M Z,LU S Y,et al.Environmentally friendly slow-release nitrogen fertilizer[J].Journal of Agricultural and Food Chemistry,2011,59(18):10169.
18. [18]
  BAJPAI S K,SWARNKAR M P,AHUJA S.On-demand release of urea from a cellulosic hydrogel using a sprinkler based irrigation (SBI) model[J].Journal of Macromolecular Science Part A-Pure and Applied Chemistry,2015,52(10):779.
19. [19]
  IBRAHIM S,NAWWAR G A M,SULTAN M.Development of bio-based polymeric hydrogel:green,sustainable and low cost plant fertilizer packaging material[J].Journal of Environmental Chemical Engineering,2016,4(1):203.
20. [20]
  XIE L H,LIU M Z,NI B L,et al.Utilization of wheat straw for the preparation of coated controlled-release fertilizer with the function of water retention[J].Journal of Agricultural and Food Chemistry,2012,60(28):6921.
21. [21]
  YANG Y C,TONG Z H,GENG Y Q,et al.Biobased polymer composites derived from corn stover and feather meals as double-coating materials for controlled-release and water-retention urea fertilizers[J/OL].Journal of Agricultural and Food Chemistry,2013,61(34):8166.
22. [22]
  周昌.棉秆基保熵缓/控释肥料的制备及其应用研究[D].昌吉:昌吉学院,2016.
23. [23]
  BORTOLIN A,AOUADA F A,MATTOSO L H C,et al.Nanocomposite paam/methyl cellulose/montmorillonite hydrogel:evidence of synergistic effects for the slow release of fertilizers[J].Journal of Agricultural and Food Chemistry,2013,61(31):7431.
24. [24]
  XIE L H,LIU M Z,NI B L,et al.New environment-friendly use of wheat straw in slow-release fertilizer formulations with the function of superabsorbent[J].Industrial & Engineering Chemistry Research,2012,51(10):3855.
25. [25]
  RASHIDZADEH A,OLAD A,SALARI D,et al.On the preparation and swelling properties of hydrogel nanocomposite based on sodium alginate-g-poly (acrylic acid-co-acrylamide)/clinoptilolite and its application as slow release fertilizer[J].Journal of Polymer Research,2014,21(2):1.
26. [26]
  OLAD A,GHAREKHANI H,MIRMOHSENI A,et al.Superabsorbent nanocomposite based on maize bran with integration of water-retaining and slow-release NPK fertilizer[J/OL].Advances in Polymer Technology[2017-03-12].DOI:10.1002/adv.21825.
27. [27]
  SENNA A M,BOTARO V R.Biodegradable hydrogel derived from cellulose acetate and EDTA as a reduction substrate of leaching NPK compound fertilizer and water retention in soil[J].Journal of Controlled Release,2017,260:194.
28. [28]
  BAJPAI S K,SWARNKAR M P,AHUJA S.On-demand release of urea from a cellulosic hydrogel using a sprinkler based irrigation (SBI) model[J].Journal of Macromolecular Science Part A-Pure and Applied Chemistry,2015,52(10):779.
29. [29]
  MOHAMMADI-KHOO S,MOGHADAM P N,FAREGHI A R,et al.Synthesis of a cellulose-based hydrogel network:characterization and study of urea fertilizer slow release[J].Journal of Applied Polymer Science,2016,133:42935.
30. [30]
  姜安龙,易晶晶,余晓青,等.海藻酸钠水凝胶对尿素的缓释效果研究[J].现代化工,2015,35(7):86.
31. [31]
  DAVIDSON D W,VERMA M S,GU F X.Controlled root targeted delivery of fertilizer using an ionically crosslinked carboxymethyl cellulose hydrogel matrix[J].Springer Plus,2013,2(1):318.
32. [32]
  JIN S P,YUE G R,FENG L,et al.Preparation and properties of a coated slow-release and water-retention biuret phosphoramide fertilizer with superabsorbent[J].Journal of Agricultural and Food Chemistry,2011,59(1):322.
33. [33]
  ZHANG Y,LIANG X Y,YANG X G,et al.An eco-friendly slow-release urea fertilizer based on waste mulberry branches for potential agriculture and horticulture applications[J].ACS Sustainable Chemistry & Engineering,2014,2(7):1871.
34. [34]
  MAZIAD N A,ABOU E L FADL F I,ELKELESH N A,et al.Radiation synthesis and characterization of super absorbent hydrogels for controlled release of some agrochemicals[J].Journal of Radioanalytical and Nuclear Chemistry,2016,307(1):513.
35. [35]
  WEN P,WU Z S,HE Y H,et al.Microwave-assisted synthesis of a semi-interpenetrating polymer network slow-release nitrogen fertilizer with water absorbency from cotton stalks[J].ACS Sustainable Chemistry & Engineering,2016,4(12):6572.
36. [36]
  LI X D,LI Q,XU X,et al.Characterization,swelling and slow-release properties of a new controlled release fertilizer based on wheat straw cellulose hydrogel[J].Journal of the Taiwan Institute of Chemical Engineers,2016,60:564.
37. [37]
  GHAZALI S,JAMARI S,NOORDIN N,et al.Properties of controlled-release-water-retention fertilizer coated with carbonaceous-g-poly (acrylic acid-co-acrylamide) superabsorbent polymer[J].International Journal of Chemical Engineering and Applications,2017,8(2):141.
38. [38]
  LU S Y,F C,G C,et al.Multifunctional environmental smart fertilizer based on Laspartic acid for sustained nutrient release[J].Journal of Agricultural and Food Chemistry,2016,64(24):4965.
39. [39]
  RASHIDZADEH A,OLAD A.Slow-released NPK fertilizer encapsulated by NaAlg-g-poly(AA-co-AAm)/MMT superabsorbent nanocomposite[J].Carbohydrate Polymers,2014,114:269.
40. [40]
  GUNES A,KITIR N,TURAN M,et al.Evaluation of effects of water-saving superabsorbent polymer on corn (Zea mays L.) yield and phosphorus fertilizer efficiency[J].Turkish Journal of Agriculture and Forestry,2016,40(3):365.
41. [41]
  POURJAVADI A,DOULABI M,SOLEYMAN R,et al.Synthesis and characterization of a novel (salep phosphate)-based hydrogel as a carrier matrix for fertilizer release[J].Reactive & Functional Polymers,2012,72(10):667.
42. [42]
  OLAD A,GHAREKHANI H,MIRMOHSENI A,et al.Synthesis,characterization,and fertilizer release study of the salt and pH-sensitive NaAlg-g-poly(AA-co-AAm)/RHA superabsorbent nanocomposite[J].Polymer Bulletin,2017,74(8):3353.
43. [43]
  WEN P,HAN Y J,WU Z S,et al.Rapid synthesis of a corncob-based semi-interpenetrating polymer network slow-release nitrogen fertilizer by microwave irradiation to control water and nutrient losses[J/OL].Arabian Journal of Chemistry,2017(3):2.[2017-03-12].DOI:10.1016/j.arabjc.
44. [44]
  赵利.磷酸酯双淀粉复合保水剂及其缓释肥的制备与性能研究[D].长春:吉林农业大学,2015.
45. [45]
  杨鸿嘉.玉米芯高吸水树脂的制备及在缓释肥中的应用[D].长春:吉林农业大学,2016.
46. [46]
  SHEN Y Z,ZHAO C,ZHOU J M,et al.Application of waterborne acrylic emulsions in coated controlled release fertilizer using reacted layer technology[J].Chinese Journal of Chemical Engineering,2015,23(1):309.
47. [47]
  RASHIDZADEH A,OLAD A,REYHANITABAR A.Hydrogel/clinoptilolite nanocomposite-coated fertilizer:swelling,water-retention and slow-release fertilizer properties[J].Polymer Bulletin,2015,72(10):2667.
48. [48]
  NOPPAKUNDILOGRAT S,PHEATCHARAT N,KIATKAMJORNWONG S.Multilayer-coated NPK compound fertilizer hydrogel with controlled nutrient release and water absorbency[J].Journal of Applied Polymer Science,2015,132:41249.
49. [49]
  NI B L,LU S Y,LIU M Z.Novel multinutrient fertilizer and its effect on slow release,water holding,and soil amending[J].Industrial & Engineering Chemistry Research,2012,51(40):12993.
50. [50]
  LU S Y,GAO C M,WANG X G,et al.Synthesis of a starch derivative and its application in fertilizer for slow nutrient release and water holding[J].Royal Society of Chemistry,2014,4:51208.
51. [51]
  WANG X G,LU S Y,GAO C M,et al.Biomass-based multifunctional fertilizer system featuring controlled-release nutrient,waterretention and amelioration of soil[J].RSC Advances,2014,4(35):18382.
52. [52]
  QIAO D L,LIU H S,YU L,et al.Preparation and characterization of slow-release fertilizer encapsulated by starch-based superabsorbent polymer[J].Carbohydrate Polymers,2016,147:146.
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沈阳化工大学材料科学与工程学院沈阳 110142

水凝胶在缓/控释肥料中应用的研究进展

Applied research progress of hydrogels in slow/controlled fertilizer

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通讯作者: 陈斌, bchen63@163.com

水凝胶在缓/控释肥料中应用的研究进展

English Abstract

Applied research progress of hydrogels in slow/controlled fertilizer

目录

水凝胶在缓/控释肥料中应用的研究进展

Applied research progress of hydrogels in slow/controlled fertilizer

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通讯作者: 陈斌, bchen63@163.com

水凝胶在缓/控释肥料中应用的研究进展

English Abstract

Applied research progress of hydrogels in slow/controlled fertilizer

目录