卷烟滤棒中降焦减害功能多孔吸附材料的研究进展
Research process of functional porous adsorbent materials in cigarette filter rod for tar and harm reduction
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摘要: 多孔吸附材料是卷烟滤棒中的一类功能材料,其结构和种类直接影响卷烟烟气有害物质的截留效率。系统综述了用于卷烟滤棒的功能多孔材料的吸附作用机制及研究进展;卷烟烟气有害成分的吸附去除是动力学传质和热力学吸附协同作用的过程,主要受吸附材料孔道结构、分子结构及功能吸附位点的影响;通过多级孔道设计、表面功能化修饰、分子特异性识别位点锚定及多元复合等策略,可对无机、有机和有机-无机杂化这三类多孔吸附材料进行功能化构筑,以提高对卷烟烟气有害成分的选择性吸附截留效率。未来需更深入地研究卷烟烟气复杂基质的动态吸附机制,以实现对卷烟滤棒吸附材料的精准可控制备,及烟气有害组分的精准高效截留,为烟草行业降焦减害技术的开发提供参考。Abstract: Porous adsorbent materials are a type of functional materials in cigarette filter rods, whose structures and types directly affect the retention efficiency of harmful substances in cigarette smoke. This paper systematically reviews the adsorption mechanism and research progress of functional porous materials used in cigarette filter rods; the adsorption and removal of harmful components in cigarette smoke is a synergistic process of kinetic mass transfer and thermodynamic adsorption, which is mainly affected by the pore structure, molecular structure and functional adsorption sites of adsorbent materials. Through strategies such as multi-level pore design, surface functionalization modification, anchoring of molecular specific recognition sites, and multi-component composite, we can functionally construct these three types of porous adsorbent materials, namely inorganic, organic, and organic-inorganic hybrids, to improve the selective adsorption and retention efficiency of harmful components in cigarette smoke. In the future, it is necessary to conduct more in-depth research on the dynamic adsorption mechanism of the complex matrix of cigarette smoke to realize the precise and controlled preparation of adsorbent materials for cigarette filter rods and the precise and efficient retention of harmful smoke components, as well as provide a reference for the development of tar and harm reduction technologies in the tobacco industry.
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