JOURNAL OF LIGHT INDUSTRY

CN 41-1437/TS  ISSN 2096-1553

Volume 37 Issue 2
May 2022
Article Contents
YANG Guang, WANG Ruijuan, ZHANG Jianqiang, et al. Study on cationic gemini surfactant coacervate phase for the extraction of methyl orange[J]. Journal of Light Industry, 2022, 37(2): 102-109. doi: 10.12187/2022.02.014
Citation: YANG Guang, WANG Ruijuan, ZHANG Jianqiang, et al. Study on cationic gemini surfactant coacervate phase for the extraction of methyl orange[J]. Journal of Light Industry, 2022, 37(2): 102-109. doi: 10.12187/2022.02.014 shu

Study on cationic gemini surfactant coacervate phase for the extraction of methyl orange

  • Received Date: 2021-11-30
    Accepted Date: 2021-12-14
  • Two coacervate phases with different microstructures were constructed with cationic quaternary ammonium gemini surfactant hexamethylene-1,6-bis(dodecyldimethylammonium bromide) (12-6-12), sodium benzoate (NaBz) and sodium carboxymethylcellulose (NaCMC), and the anionic dye methyl orange (MO) was extracted from aqueous solution. The experiments results showed that the coacervate phases of 12-6-12/NaBz and 12-6-12/NaBz/NaCMC were respectively worm-like micelle entanglement and three-dimensional network structure, and they had great efficiency in the extraction of MO from water. Moreover, the two coacervate phases could selectively extract anionic dye MO in the presence of cationic dye methylene blue. The possible extraction mechanism could be that after adding MO into the coacervate phase, some MO molecules were embedded into the 12-6-12 micellar core through the benzene ring structure, and some MO molecules were adsorbed on the 12-6-12 micellar surface, which participated in the formation of the coacervate phase with network structure.
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