JOURNAL OF LIGHT INDUSTRY

CN 41-1437/TS  ISSN 2096-1553

Volume 37 Issue 2
May 2022
Article Contents
YANG Xuzhao, BAI Yarong, ZHANG Chenlong, et al. Preparation of mesoporous silica with piperidinium-based ionic liquid surfactant as templates[J]. Journal of Light Industry, 2022, 37(2): 110-118. doi: 10.12187/2022.02.015
Citation: YANG Xuzhao, BAI Yarong, ZHANG Chenlong, et al. Preparation of mesoporous silica with piperidinium-based ionic liquid surfactant as templates[J]. Journal of Light Industry, 2022, 37(2): 110-118. doi: 10.12187/2022.02.015 shu

Preparation of mesoporous silica with piperidinium-based ionic liquid surfactant as templates

  • Received Date: 2021-04-17
    Accepted Date: 2021-06-17
  • Ionic liquid surfactant N-hexadecyl-N-methylpiperidinium bromide ([C16MPip]Br) was used as a template to prepare mesoporous silica with controllable morphology in alkaline medium via hydrothermal method. The influence of the [C16MPip]Br/TEOS and NH4OH/TEOS molar ratios, hydration temperature and calcination temperature on the synthesis of mesoporous silica were analyzed. Small angle X-ray diffraction (XRD), nitrogen adsorption-desorption, Fourier transform infrared (FTIR) and transmission electron microscopy (TEM) were respectively employed to characterize the structure of prepared mesoporous silica. The results showed that the structure of mesoporous silica could be changed by the reaction conditions. Ordered mesoporous silica MCM-41 could be prepared with [C16MPip]Br as templates, and the specific surface area and pore diameter were about 1000 m2/g and 2.5 nm when the molar ratio of [C16MPip]Br/TEOS and NH4OH/TEOS were 0.32 and 13, the hydration temperature was 25 ℃, and the calicination temperature was 550 ℃.
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