膜分离精制薄片叶膏挥发性成分分析及卷烟纸加香应用研究
Analysis of volatile components of reconstitution tobacco extract refined by membrane separation and application of cigarette paper flavoring
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摘要: 分别采用50 nm陶瓷膜、100 kD有机膜和10 kD有机膜对薄片叶膏进行分级分离,将得到的组分进行气相色谱质谱技术(GC-MS)分析、挥发性成分主成分分析、卷烟纸加香评吸及加香卷烟烟气挥发性成分分析。结果表明:1)未分离组分(M0)、50 nm陶瓷膜截留组分(M2)、100 kD有机膜截留组分(M4)、10 kD有机膜透过组分(M5)和10 kD有机膜截留组分(M6)中分别检测出68种、45种、45种、7种和36种挥发性成分,其挥发性成分总量分别为1 109.03 μg/mL、1 042.14 μg/mL、828.02 μg/mL、92.00 μg/mL、762.42 μg/mL,广泛存在于5个组分中的成分有烟碱、2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚);M5组分特有的成分为2-乙基己醇、顺式-1-(环己基甲基)-4-乙基-环己烷;2) M5组分主成分分析结果与M2有一定程度上的相似性,与其他3种组分有明显差异,影响M5组分香味的主成分主要为2-乙基己醇、顺式-1-(环己基甲基)-4-乙基-环己烷;3) M5组分加入卷烟纸后,卷烟的感官评吸效果最好,烟气中酚类、烷烃类和苯类成分增加较多,个别香味成分(如甲基环戊烯醇酮、(+)-香橙烯等)也明显增多,加香效果显著。Abstract: 50 nm ceramic membrane and 100 kD and 10 kD organic membrane were used to separate the reconstitution tobacco extract, the obtained fractions were analyzed by GC-MS analysis, principal component analysis of volatile components, evaluation cigarette paper flavoring, and particle composition analysis of flavoring cigarette smoke. The results showed that 68, 45, 45, 7 and 36 volatile components were detected in the unseparated component (M0), 50 nm ceramic membrane interception component (M2), 100 kD organic membrane interception component (M4), 10 kD organic membrane permeation component (M5) and 10 kD organic membrane interception component (M6), respectively, and the total volatile components were 1 109.03 μg/mL,1 042.14 μg/mL,828.02 μg/mL,92.00 μg/mL,762.42 μg/mL, widely existing in the five components were nicotine, 2,2'-methylene bis-(4-methyl-6-tert-butylpheno. The unique components of M5 were 2-ethylhexanol and cis-1-(cyclohexylmethyl)-4-ethyl cyclohexane. The results of principal component analysis of M5 component were similar to M2 to a certain extent, but there were obvious differences with the other three components. The main components that affected the flavor of M5 were 2-ethylhexanol, cis-1-(cyclohexylmethyl)-4-ethyl cyclohexane. When M5 were added to cigarette paper, the sensory evaluation effect of cigarette was the best, the phenolic, alkane and benzene components in the smoked significantly increased, and the individual flavor components (such as methyl cyclopentaenol ketone, (+)-vanorene, etc.) also increased, which had a significant flavoring effect.
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[1]
BHADOURIA A S,SORCI M,GU M,et al.Optimization of membrane separation processes for protein fractionation[J].Industrial&Engineering Chemistry Research,2014,53(13):5103-5109.
-
[2]
MUOZ-ALMAGRO N,PRODANOV M,WILDE P J,et al.Obtainment and characterisation of pectin from sunflower heads purified by membrane separation techniques[J].Food Chemi-stry,2020,318:126476.
-
[3]
高猛峰,赵黎明.膜集成技术在烟草薄片萃取液分离浓缩中的应用[C]//中国食品科学技术学会.中国食品科学技术学会第十七届年会论文集.西安:[出版者不详],2020:481-482.
-
[4]
杜锐,李猷,袁润蕾,等.膜技术提高造纸法再造烟叶的感官品质[J].烟草科技,2008(2):39-41.
-
[5]
张静楠,张峻松.基于膜分离技术提高碎片浓缩液质量的研究[J].福建分析测试,2015,24(2):27-29.
-
[6]
吴彦,俞金伟,黄东业,等.膜分离技术精制罗汉果香味成分及应用[J].烟草科技,2019,52(7):51-60.
-
[7]
中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.卷烟第4部分感官技术要求:GB 5606.4-2005[S].北京:中国标准出版社,2005.
-
[8]
中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.卷烟用常规分析用吸烟机测定总粒相物和焦油:GB/T 19609-2004[S].北京:中国标准出版社,2004.
-
[9]
许春平,曲利利,杜欢哲,等.云烟精油陶瓷膜分离组分的关键香气成分与感官属性的相关性分析[J].轻工学报,2021,36(3):45-53.
-
[10]
张峻松,贾春晓,毛多斌,等.金合欢基丙酮的合成与表征[J].化学世界,2004(2):86-88.
-
[11]
李媛媛,高彦祥.膜分离技术纯化栀子黄色素的研究[J].食品科学,2006(6):113-117.
-
[12]
苏加坤,罗娟敏,徐达,等.基于PLSR分析蛋白质与淀粉对市售卷烟感官品质的影响[J].食品与机械,2015,31(5):16-20.
-
[13]
杨艳芹,袁凯龙,夏琛,等.分子蒸馏分离废次烟末致香成分及在烟草中的应用[J].应用化学,2015,32(12):1448-1454.
-
[14]
郑建宇,刘晶,周桂园,等.超滤膜组合技术对烟草提取物化学成分的影响[J].烟草科技,2019,52(12):70-78.
-
[15]
叶晓青.新型甜味剂在卷烟配方中的作用[J].烟草科技,2000(2):3-4.
-
[16]
曹晓玉,杨佳玫,杨虹琦,等.烟草萜烯类化合物种类及其分析方法研究进展[J].作物研究,2013,27(3):296-301.
-
[17]
朱显灵,潘文杰,陈懿,等.不同品种烤烟鲜叶表面提取物的主要成分分析[J].中国烟草科学,2011,32(3):51-56.
-
[18]
温俊峰.3-甲基吲哚的合成研究进展[J].榆林学院学报,2011,21(6):13-17.
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