直链淀粉-番茄红素复合物的氧稳定性及降解动力学研究

孙世东; 赵文红

doi:10.12187/2022.06.009

December 2022

Article Contents

SUN Shidong and ZHAO Wenhong. Oxygen stability and degradation kinetics of amylose-lycopene complexes[J]. Journal of Light Industry, 2022, 37(6): 68-77. doi: 10.12187/2022.06.009

Citation: SUN Shidong and ZHAO Wenhong. Oxygen stability and degradation kinetics of amylose-lycopene complexes[J]. Journal of Light Industry, 2022, 37(6): 68-77. doi: 10.12187/2022.06.009 shu

Oxygen stability and degradation kinetics of amylose-lycopene complexes

College of Food Science and Technology, He'nan University of Technology, Zhengzhou 450001, China

Received Date: 2022-04-11

Abstract

The structure of amylose-lycopene complexes (ALCs) was characterized, and the changes of lycopene retention and antioxidant activity in ALCs treated with N₂ or O₂ were studied, and the kinetic model of lycopene degradation was further developed. Results showed that lycopene encapsulated by amylose formed a V-type helix structure, and the molecular chain winding of lycopene and amylose increased the double helix content of ALCs. The content and antioxidant activity of lycopene in ALCs treated with N₂ were higher than those treated with O₂, and the degradation was slower. After 24 h treatment in N₂, the retention rate of lycopene and the clearance rate of DPPH in ALCs were (85.17±0.42)% and (35.74±0.01)%, respectively, which were significantly higher than those in the control group (59.74±0.06)% and (17.20±0.01)% (P < 0.01). After 24 h treatment in O₂, the retention rate of lycopene and the clearance rate of DPPH in ALCs were (77.09±0.90)% and (33.24±0.03)%, respectively, which were significantly higher than those of lycopene standard (50.32±0.42)% and (16.32±0.09)% in the control group. Under the condition of N₂ and O₂ treatment, the degradation of lycopene in ALCs conformed to the second-order kinetic model, the degradation rate constants were 6.0×10^-4 μg/(mL·h) and 8.0×10^-4 μg/(mL·h), respectively, and the lifetimes of T_1/2 was 115.92 h and 86.94 h, respectively, and the T_9/10 was 17.57 h and 13.18 h, respectively, which were significantly better than those in the control group. Therefore, the ALCs was effective in enhance lycopene stability, and better maintained the content and antioxidant activity of the lycopene.
- amylose-lycopene complexes,
- oxygen stability,
- degradation kinetics,
- structure characterization
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Oxygen stability and degradation kinetics of amylose-lycopene complexes

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