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壳聚糖基抑菌抗氧化活性复合膜的制备及其性能研究

刘晓丽 ,  郭曹羽 ,  林锴立 ,  廖文莹 ,  王文燕

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刘晓丽, 郭曹羽, 林锴立, 等. 壳聚糖基抑菌抗氧化活性复合膜的制备及其性能研究[J]. 轻工学报, 2023, 38(4): 27-36. doi: 10.12187/2023.04.004
引用本文: 刘晓丽, 郭曹羽, 林锴立, 等. 壳聚糖基抑菌抗氧化活性复合膜的制备及其性能研究[J]. 轻工学报, 2023, 38(4): 27-36. doi: 10.12187/2023.04.004
shu
LIU Xiaoli, GUO Caoyu, LIN Kaili, et al. Preparation and properties of chitosan-based antibacterial and antioxidative composite films[J]. Journal of Light Industry, 2023, 38(4): 27-36. doi: 10.12187/2023.04.004
Citation: LIU Xiaoli, GUO Caoyu, LIN Kaili, et al. Preparation and properties of chitosan-based antibacterial and antioxidative composite films[J]. Journal of Light Industry, 2023, 38(4): 27-36. doi: 10.12187/2023.04.004
shu

壳聚糖基抑菌抗氧化活性复合膜的制备及其性能研究

  • 江南大学 食品学院/食品科学与技术国家重点实验室/江苏省食品安全与质量控制协同创新中心, 江苏 无锡 214122

    • 作者简介: 刘晓丽(1984-),女,甘肃省天水市人,江南大学副教授,博士,主要研究方向为食品加工及保鲜。E-mail:lxl525j@163.com;

  • 基金项目: 国家重点研发计划项目（2019YFC1606004）

  • 中图分类号: TS206.4

Preparation and properties of chitosan-based antibacterial and antioxidative composite films

  • School of Food Science and Technology/State Key Laboratory of Food Science and Technology/Collaborative Innovation Center of Food Safety and Quality Control in Jiangsu Province, Jiangnan University, Wuxi 214122, China

  • Received Date: 2022-11-05
    Accepted Date: 2023-02-22

    CLC number: TS206.4

  • 摘要: 为获得具有良好功能特性的壳聚糖（CS）基复合膜材料，采用混合溶液浇筑法制备含有纳米细菌纤维素（nBC）、曲酸（KA）和姜黄素（CUR）的CS基抑菌抗氧化活性复合膜（CS/nBC/KA/CUR），考查不同组分复合膜的水分阻隔性能、机械性能、光学性能、抑菌活性和抗氧化活性。结果表明，CS/nBC/KA/CUR复合膜中各组分之间主要是通过氢键与范德华力相互作用，膜内部结晶度明显增强。相较于CS/nBC、CS/nBC/CUR和CS/nBC/KA复合膜，CS/nBC/KA/CUR复合膜的水溶性显著下降，水蒸气透过率比CS/nBC复合膜提升近24%，拉伸强度比CS/nBC/KA复合膜提高近3倍，断裂伸长率比CS/nBC/KA复合膜提高约1.8%，对E.coli的抑菌效果比其余复合膜平均提升约12.2%，ABTS自由基清除率比CS/nBC复合膜最高提升约35.2%。CS/nBC/KA/CUR复合膜结合了各组分的优势，在食品抑菌抗氧化活性包装材料的开发领域具有一定潜在价值。
    Abstract: In order to obtain chitosan (CS) based composite film materials with satisfactory functional properties, CS based antibacterial and antioxidant composite films (CS/nBC/KA/CUR) containing nanobacterium cellulose (nBC), curcumin (CUR) and kojic acid (KA) was prepared by mixed solution casting method. The barrier properties, mechanical properties, optical properties, antibacterial activity, and antioxidant activity of different component composite films were investigated.The results showed that the components of CS/nBC/KA/CUR composite film interacted with each other mainly by hydrogen bonding and van der Waals force, and the interior of the film showed a relatively enhanced crystallinity. Compared with the other composite films, the water solubility of CS/nBC/KA/CUR composite films was decreased significantly. The water vapor transmission rate was increased by nearly 24% compared with CS/nBC composite films. The tensile strength was increased by nearly 3 times, and the elongation at break was increased by about 1.8% compared with CS/nBC/KA composite films. The antibacterial effect against E.coli was increased by about 12.2% compared with the other composite films, and the ABTS free radical scavenging rate was most greatly increased by 35.2% compared with CS/nBC composite films. Therefore, CS/nBC/KA/CUR composite films combined the advantages of each components and showed a certain potential value in the development of active food packaging materials.
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刘晓丽, 郭曹羽, 林锴立, 等. 壳聚糖基抑菌抗氧化活性复合膜的制备及其性能研究[J]. 轻工学报, 2023, 38(4): 27-36. doi: 10.12187/2023.04.004
引用本文: 刘晓丽, 郭曹羽, 林锴立, 等. 壳聚糖基抑菌抗氧化活性复合膜的制备及其性能研究[J]. 轻工学报, 2023, 38(4): 27-36. doi: 10.12187/2023.04.004
shu
LIU Xiaoli, GUO Caoyu, LIN Kaili, et al. Preparation and properties of chitosan-based antibacterial and antioxidative composite films[J]. Journal of Light Industry, 2023, 38(4): 27-36. doi: 10.12187/2023.04.004
Citation: LIU Xiaoli, GUO Caoyu, LIN Kaili, et al. Preparation and properties of chitosan-based antibacterial and antioxidative composite films[J]. Journal of Light Industry, 2023, 38(4): 27-36. doi: 10.12187/2023.04.004
shu

壳聚糖基抑菌抗氧化活性复合膜的制备及其性能研究

    作者简介:刘晓丽(1984-),女,甘肃省天水市人,江南大学副教授,博士,主要研究方向为食品加工及保鲜。E-mail:lxl525j@163.com
  • 江南大学 食品学院/食品科学与技术国家重点实验室/江苏省食品安全与质量控制协同创新中心, 江苏 无锡 214122
  • 收稿日期: 2022-11-05
  • 录用日期: 2023-02-22
基金项目:  国家重点研发计划项目（2019YFC1606004）

摘要: 为获得具有良好功能特性的壳聚糖（CS）基复合膜材料，采用混合溶液浇筑法制备含有纳米细菌纤维素（nBC）、曲酸（KA）和姜黄素（CUR）的CS基抑菌抗氧化活性复合膜（CS/nBC/KA/CUR），考查不同组分复合膜的水分阻隔性能、机械性能、光学性能、抑菌活性和抗氧化活性。结果表明，CS/nBC/KA/CUR复合膜中各组分之间主要是通过氢键与范德华力相互作用，膜内部结晶度明显增强。相较于CS/nBC、CS/nBC/CUR和CS/nBC/KA复合膜，CS/nBC/KA/CUR复合膜的水溶性显著下降，水蒸气透过率比CS/nBC复合膜提升近24%，拉伸强度比CS/nBC/KA复合膜提高近3倍，断裂伸长率比CS/nBC/KA复合膜提高约1.8%，对E.coli的抑菌效果比其余复合膜平均提升约12.2%，ABTS自由基清除率比CS/nBC复合膜最高提升约35.2%。CS/nBC/KA/CUR复合膜结合了各组分的优势，在食品抑菌抗氧化活性包装材料的开发领域具有一定潜在价值。

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