JOURNAL OF LIGHT INDUSTRY

CN 41-1437/TS  ISSN 2096-1553

酸碱改性木质活性炭对棕榈油中3-MCPD酯的吸附脱除效果

侯杰 ,  纪俊敏 ,  孙尚德

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侯杰, 纪俊敏, 孙尚德. 酸碱改性木质活性炭对棕榈油中3-MCPD酯的吸附脱除效果[J]. 轻工学报, 2024, 39(1): 48-56. doi: 10.12187/2024.01.006
引用本文: 侯杰, 纪俊敏, 孙尚德. 酸碱改性木质活性炭对棕榈油中3-MCPD酯的吸附脱除效果[J]. 轻工学报, 2024, 39(1): 48-56. doi: 10.12187/2024.01.006
shu
HOU Jie, JI Junmin and SUN Shangde. Adsorptive removal efficiency of 3-MCPD esters from palm oil by acid-base modified wood-activated carbon[J]. Journal of Light Industry, 2024, 39(1): 48-56. doi: 10.12187/2024.01.006
Citation: HOU Jie, JI Junmin and SUN Shangde. Adsorptive removal efficiency of 3-MCPD esters from palm oil by acid-base modified wood-activated carbon[J]. Journal of Light Industry, 2024, 39(1): 48-56. doi: 10.12187/2024.01.006
shu

酸碱改性木质活性炭对棕榈油中3-MCPD酯的吸附脱除效果

  • 1. 河南工业大学 粮油食品学院, 河南 郑州 450001;

  • 2. 中原食品实验室, 河南 漯河 462300

    • 作者简介: 侯杰(1998-),男,河南省驻马店市人,河南工业大学硕士研究生,主要研究方向为油脂加工理论与技术。E-mail:hj187396@163.com;

  • 基金项目: 河南工业大学自科创新基金项目(2021ZKCJ02)
    国家“十四五”重点研发课题项目(2021YFD2100302)
    河南工业大学高层次人才科研启动基金项目(2021BS042)

  • 中图分类号: TS221

Adsorptive removal efficiency of 3-MCPD esters from palm oil by acid-base modified wood-activated carbon

  • 1. College of Food Science and Technology, Henan University of Technology, Zhengzhou 450001, China;

  • 2. Food Laboratory of Zhongyuan, Luohe 462300, China

  • Received Date: 2023-08-02
    Accepted Date: 2023-10-05

    CLC number: TS221

  • 摘要: 以精炼棕榈油为研究对象,研究4种碳纳米吸附剂(木质活性炭粉末、椰壳活性炭粉末、煤质活性炭粉末和多壁碳纳米管)对3-氯丙醇(3-MCPD)酯的吸附脱除效果,并对最佳吸附剂进行酸碱改性,探究改性后吸附剂添加量、吸附时间和吸附温度对棕榈油中3-MCPD酯吸附脱除效果的影响。结果表明:对3-MCPD酯的脱除效果为木质活性炭粉末＞多壁碳纳米管＞椰壳活性炭粉末＞煤质活性炭粉末,整体脱除效果欠佳;经4 mol/L H3PO4改性后的木质活性炭粉末,吸附性能增强,在吸附剂添加量为5.85% 、吸附时间为47 min、吸附温度为103 ℃的最佳吸附条件下,对棕榈油中3-MCPD酯的脱除率可达71.82% 。使用H3PO4改性木质活性炭可作为脱除食用油中3-MCPD酯的一个有效方法。
    Abstract: The adsorptive removal effects of four adsorbents (wood-activated carbon powder, coconut shell-activated carbon powder, coal-activated carbon powder, and multi-walled carbon nanotubes) on 3-monochloropropane-1,2-diol (3-MCPD) esters were probed using refined palm oil as the research object. And acid-base modification was carried out on the optimum adsorbent to investigate the effects of adsorbent addition amount, adsorption time, and adsorption temperature on the adsorptive removal efficiency of 3-MCPD esters in palm oil. The results showed that the removal efficiency of 3-MCPD esters was as follows: wood-activated carbon powder >multi-walled carbon nanotubes>coconut shell-activated carbon powder >coal-activated carbon powder, but the overall removal effects were poor. The adsorption performance of the wood-activated carbon powder modified with 4 mol/L H3PO4 was improved. Under the optimal adsorption conditions of 5.85% addition, 47 min, and 103 ℃, the removal efficiency of 3-MCPD esters from palm oil could reach 71.82% . Wood-activated carbon modified by H3PO4 could be an effective strategy for the removal of 3-MCPD esters from edible oil.
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侯杰, 纪俊敏, 孙尚德. 酸碱改性木质活性炭对棕榈油中3-MCPD酯的吸附脱除效果[J]. 轻工学报, 2024, 39(1): 48-56. doi: 10.12187/2024.01.006
引用本文: 侯杰, 纪俊敏, 孙尚德. 酸碱改性木质活性炭对棕榈油中3-MCPD酯的吸附脱除效果[J]. 轻工学报, 2024, 39(1): 48-56. doi: 10.12187/2024.01.006
shu
HOU Jie, JI Junmin and SUN Shangde. Adsorptive removal efficiency of 3-MCPD esters from palm oil by acid-base modified wood-activated carbon[J]. Journal of Light Industry, 2024, 39(1): 48-56. doi: 10.12187/2024.01.006
Citation: HOU Jie, JI Junmin and SUN Shangde. Adsorptive removal efficiency of 3-MCPD esters from palm oil by acid-base modified wood-activated carbon[J]. Journal of Light Industry, 2024, 39(1): 48-56. doi: 10.12187/2024.01.006
shu

酸碱改性木质活性炭对棕榈油中3-MCPD酯的吸附脱除效果

    作者简介:侯杰(1998-),男,河南省驻马店市人,河南工业大学硕士研究生,主要研究方向为油脂加工理论与技术。E-mail:hj187396@163.com
  • 1. 河南工业大学 粮油食品学院, 河南 郑州 450001;
  • 2. 中原食品实验室, 河南 漯河 462300
  • 收稿日期: 2023-08-02
  • 录用日期: 2023-10-05
基金项目:  河南工业大学自科创新基金项目(2021ZKCJ02)国家“十四五”重点研发课题项目(2021YFD2100302)河南工业大学高层次人才科研启动基金项目(2021BS042)

摘要: 以精炼棕榈油为研究对象,研究4种碳纳米吸附剂(木质活性炭粉末、椰壳活性炭粉末、煤质活性炭粉末和多壁碳纳米管)对3-氯丙醇(3-MCPD)酯的吸附脱除效果,并对最佳吸附剂进行酸碱改性,探究改性后吸附剂添加量、吸附时间和吸附温度对棕榈油中3-MCPD酯吸附脱除效果的影响。结果表明:对3-MCPD酯的脱除效果为木质活性炭粉末＞多壁碳纳米管＞椰壳活性炭粉末＞煤质活性炭粉末,整体脱除效果欠佳;经4 mol/L H3PO4改性后的木质活性炭粉末,吸附性能增强,在吸附剂添加量为5.85% 、吸附时间为47 min、吸附温度为103 ℃的最佳吸附条件下,对棕榈油中3-MCPD酯的脱除率可达71.82% 。使用H3PO4改性木质活性炭可作为脱除食用油中3-MCPD酯的一个有效方法。

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