二元共晶糖醇颗粒的制备及其作为降温材料在传统卷烟中的应用
Preparation of binary eutectic sugar alcohol particles and their application as cooling materials in traditional cigarettes
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摘要: 为拓宽传统卷烟用降温材料的筛选范围,利用木糖醇和赤藓糖醇的二元相图计算糖醇共晶点温度,通过熔融法制备木糖醇与赤藓糖醇二元共晶糖醇颗粒,将其作为降温材料应用于传统卷烟中,并评价其吸热降温效果。结果表明:二元共晶糖醇共晶点处的木糖醇与赤藓糖醇物质的量之比为7.6∶2.4,命名为木7.6赤2.4共晶糖醇颗粒,共晶点温度约为89 ℃;该共晶糖醇颗粒的制备过程中未发生化学反应,其形貌特征与木糖醇颗粒相似,表面较为光滑,将其应用于中短支卷烟时,较空白卷烟的主流烟气温度降低了6.8 ℃;木糖醇颗粒可有效截留主流烟气中的水分,所添加二元共晶糖醇颗粒中的木糖醇含量越多,卷烟出口处所捕集到的水分越少;二元共晶糖醇颗粒可截留部分主流烟气中的焦油,其中木7.6赤2.4共晶糖醇颗粒卷烟出口端捕集到的焦油量最少,但二元共晶糖醇颗粒对主流烟气中的烟碱含量和CO含量均未产生明显影响;添加木7.6赤2.4共晶糖醇颗粒的卷烟其烟气的甜感有所提升,但吸阻略有增加,且卷烟的烟气热感有所下降,感官品质整体评价最高。Abstract: In order to expand the screening range of cooling materials for traditional cigarettes, the eutectic point of xylitol and erythritol was calculated through the binary phase diagram of xylitol and erythritol. A binary eutectic sugar alcohols particles of xylitol and erythritol were prepared by melting method and applied as a cooling material in traditional cigarettes, and their heat absorption and cooling effects were evaluated. The results showed that the ratio of the amount of xylitol to erythritol at the eutectic point of binary eutectic sugar alcohol was 7.6∶2.4, which was named as X7.6E2.4 eutectic sugar alcohol particles, and the eutectic temperature was approximately 89 ℃. The preparation process of the eutectic sugar alcohol particles did not undergo any chemical reaction, and their morphological characteristics were similar to those of xylitol particles, with a relatively smooth surface. When applied to medium and short length cigarettes, the mainstream smoke temperature of the cigarette was reduced by 6.8 ℃ compared to blank cigarettes. Xylitol particles could effectively retain moisture from mainstream smoke. The more xylitol content was added to binary eutectic sugar alcohol particles, the less moisture was captured at the cigarette outlet. Binary eutectic sugar alcohol particles could intercept some of the tar in mainstream smoke, among which X7.6E2.4 eutectic sugar alcohol particle cigarettes capture the least amount of tar at the outlet, but binary eutectic sugar alcohol particles had no significant effect on the nicotine and CO content in mainstream smoke. The cigarette with added X7.6E2.4 eutectic sugar alcohol particles showed an improvement in the sweetness of the smoke, but the suction resistance slightly increased. In addition, the heat sensation of the smoke of cigarettes was decreased, resulting in the highest the overall sensory quality evaluation.
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[1]
郭新月,杨占平,宋晓梅,等.加热不燃烧卷烟烟气降温技术研究进展[J].中国烟草学报,2020,26(3):24-32.
-
[2]
吕彦力,王建军,郝亚萍,等.太阳能蓄热单元蓄热过程的数值模拟与优化[J].轻工学报,2016,31(2):74-80.
-
[3]
陈秋平,谢国勇,罗玮,等.二十烷/膨胀石墨复合相变材料的制备及其对卷烟滤嘴温度的调控[J].烟草科技,2017,50(3):65-72.
-
[4]
邵雪峰.面向中低温储热的糖醇相变材料储热性能综合评价及性能提升研究[D].杭州:浙江大学,2020.
-
[5]
杨生,邵雪峰,范利武.面向中温储热的D-半乳糖醇/肌糖醇二元共晶相变材料热稳定性研究[J].化工学报,2020,71(2):864-870.
-
[6]
陈涛,孙寒雪,朱照琪,等.(准)共晶系相变储能材料的研究进展[J].化工进展,2019,38(7):3265-3273.
-
[7]
王成君,段志英,王爱军,等.基于共晶系相变材料的研究进展[J].材料导报,2021,35(13):13058-13066.
-
[8]
车海山.赤藓糖醇基相变储热材料的制备及性能研究[D].南京:南京理工大学,2018.
-
[9]
WANG L J,MENG D.Fatty acid eutectic/polymethyl methacrylate composite as form-stable phase change material for thermal energy storage[J].Applied Energy,2010,87(8):2660-2665.
-
[10]
次恩达,王会,李晓卿,等.六水硝酸镁-硝酸锂共晶盐/膨胀石墨复合相变材料的制备及性能强化[J].储能科学与技术,2022,11(1):30-37.
-
[11]
国家质量监督检验检疫总局.卷烟 总粒相物中水分的测定 第1部分 气相色谱法:GB/T 23203.1—2013[S].北京:中国标准出版社,2014.
-
[12]
国家质量监督检验检疫总局.卷烟 总粒相物中烟碱的测定 气相色谱法:GB/T 23355—2009[S].北京:中国标准出版社,2009.
-
[13]
国家质量监督检验检疫总局卷烟 用常规分析用吸烟机测定 总粒相物和焦油:GB/T 19609—2004[S].北京:中国标准出版社,2004.
-
[14]
国家质量监督检验检疫总局.卷烟 第4部分:感官技术要求:GB 5606.4—2005[S].北京:中国标准出版社,2005.
-
[15]
邵雪峰,冯飙,胡楠,等.糖醇及二元共晶混合物储释热特性的非等温测试[J].浙江大学学报(工学版),2018,52(1):50-58.
-
[16]
张瑞瑞,王宁,高志,等.赤藻糖醇/甘露醇过冷特性分析[J].化工进展,2022,41(6):2959-2966.
-
[17]
赵杨,申钦鹏,李世卫,等.基于造纸法的加热卷烟降温材料的制备及应用[J].烟草科技,2023,56(1):82-91.
-
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