JOURNAL OF LIGHT INDUSTRY

CN 41-1437/TS  ISSN 2096-1553

Volume 32 Issue 5
September 2017
Article Contents
WANG Pei-yuan, LI Yan-nan, LI Shao-dan, et al. Research on ultrasonic assisted rapid synthesis of zeolitic imidazolate framework-67(ZIF-67) and its supercapacitor performance[J]. Journal of Light Industry, 2017, 32(5): 24-31. doi: 10.3969/j.issn.2096-1553.2017.5.004
Citation: WANG Pei-yuan, LI Yan-nan, LI Shao-dan, et al. Research on ultrasonic assisted rapid synthesis of zeolitic imidazolate framework-67(ZIF-67) and its supercapacitor performance[J]. Journal of Light Industry, 2017, 32(5): 24-31. doi: 10.3969/j.issn.2096-1553.2017.5.004 shu

Research on ultrasonic assisted rapid synthesis of zeolitic imidazolate framework-67(ZIF-67) and its supercapacitor performance

  • Received Date: 2016-10-27
  • A large amount of size tunable zeolitic imidazolate framework-67 (ZIF-67) was synthesized in a shot time with ultrasonic assisted method. The structure and morphology of synthesized materials were characterized with XRD and SEM. Nitrogen adsorption-desorption technique was also used to characterize the synthesized ZIF-67.Results showed that the ZIF-67 prepared by this method had higher crystallinity, regular rhombic dodecahedral morphology, and higher porosity and specific surface area.As supercapacitor electrode materials, cyclic voltammetry (CV) and galvanostatic charge/discharge (GCD) measurements were carried out to test the electrochemical performance of synthesized materials.The results showed that ZIF-67 synthesized by ultrasonic assisted method delivered a specific capacitance of 93 F/g at 0.5 A/g, which was much higher than that of ZIF-67 synthesized under static condition.When current density was 1 A/g,the specific capacitance of ZIF-67 synthesized by ultrasonic assisted mehtod could be retained to 98.6% of the initial value after 1000 cycles, demonstrating the excellent cycling stability.
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