基于非共价键作用构筑的白光凝胶研究进展

樊凯奇; 苏振宁; 王书元; 赵帅; 韩光鲁; 余述燕; 张宝浩; 尹志刚; 宋健

doi:10.3969/j.issn.2096-1553.2018.01.008

January 2018

Article Contents

FAN Kaiqi, SU Zhenning, WANG Shuyuan, et al. Research progress of white light gel construction based on non-covalent bond[J]. Journal of Light Industry, 2018, 33(1): 56-71. doi: 10.3969/j.issn.2096-1553.2018.01.008

Citation: FAN Kaiqi, SU Zhenning, WANG Shuyuan, et al. Research progress of white light gel construction based on non-covalent bond[J]. Journal of Light Industry, 2018, 33(1): 56-71. doi: 10.3969/j.issn.2096-1553.2018.01.008 shu

Research progress of white light gel construction based on non-covalent bond

College of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China;
School of Chemical Engineering, Tianjin University, Tianjin 300072, China

Received Date: 2017-11-30

Abstract

Based on the formation mode of white light gel, the research status of constructing white light gel with non-covalent interactions such as hydrogen bonding, π-π stacking and metal complexing was reviewed. It was pointed out that the non-covalent bonding of white light gel could make different chromophore compounds produce a dynamic and reversible one-dimensional assembly, self-assembly of aggregates could help regulate the distance between donor and acceptor molecules and dipole direction to improve the energy transfer efficiency between molecules to obtain a tunable white light gel material.This white light gel had obvious stimulus response characteristics and flexible phase transition to the outside world as well as good plastic workability, and had great potential applications in the fields of display materials, lighting equipment and the like prospect. However, the existing white light gel system had the problems of being destroyed under strong mechanical or high temperature, low gel strength and long preparation period of the dry gel. In the future,the structure-activity relationship research between the gel factor structure and the donor and acceptor energy transfer efficiency should be strengthened to promote the industrialization application of white gel as soon as possible.
- non-covalent bond,
- white light gel,
- self-assembly,
- energy transfer,
- chromophore
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沈阳化工大学材料科学与工程学院沈阳 110142

Research progress of white light gel construction based on non-covalent bond

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