烟用水基胶中苯系物和邻苯二甲酸酯类化合物的GC-MS/MS同时测定

王立云; 陈莉莎; 芦楠; 蒋成勇; 林琳; 严莉红

doi:10.3969/j.issn.2096-1553.2019.03.007

May 2019

Article Contents

WANG Liyun, CHEN Lisha, LU Nan, et al. Simultaneous determination of benzene series and phthalates in water-borne adhesives for cigarette by gas chromatography tandem mass spectrometry[J]. Journal of Light Industry, 2019, 34(3): 60-67. doi: 10.3969/j.issn.2096-1553.2019.03.007

Citation: WANG Liyun, CHEN Lisha, LU Nan, et al. Simultaneous determination of benzene series and phthalates in water-borne adhesives for cigarette by gas chromatography tandem mass spectrometry[J]. Journal of Light Industry, 2019, 34(3): 60-67. doi: 10.3969/j.issn.2096-1553.2019.03.007 shu

Simultaneous determination of benzene series and phthalates in water-borne adhesives for cigarette by gas chromatography tandem mass spectrometry

1. Beijing Research Station of Technical Center, Shanghai Tobacco Group Co., Ltd., Beijing 101121, China;
2. Beijing Tobacco Quality Control & Supervision Station, Beijing 100029, China

Received Date: 2019-01-04

Abstract

Using a polar DB-WAX capillary column as the column, n-hexane as the extract, and n-tetradecane as the internal standard, the simultaneous determination of the waterborne adhesives by gas chromatography-tandem mass spectrometry (GC-MS/MS) was established. The method for the content of benzene series and phthalate compounds was investigated and the performance of the method was examined. The results showed that the complete separation of 13 components of benzene series and phthalate compounds was achieved by MRM mode and optimal collision energy conditions at the optimum extraction time of 20 min. The correlation coefficient of this method was >0.999, the detection limit of benzene series was 0.000 8~0.001 0 μg/mL, the limit of quantification was 0.002 5~0.003 0 μg/mL; the detection limit of phthalate compounds was 0.003 0~0.008 0 μg/mL, the limit of quantification was 0.010 0~0.030 0 μg/mL; the recoveries of the two classes of compounds at each spiked concentration level were between 83.2%~99.8%, and the relative standard deviation was less than 7.00%. This indicated that the method had good repeatability and high recovery rate, which could meet the requirements of quantitative analysis, and the limit of quantitation was lower than the industry standard.
- water-borne adhesive for cigarette,
- gas chro-matography tandem mass spectrometry,
- ben-zene series,
- phthalate compound
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沈阳化工大学材料科学与工程学院沈阳 110142

Simultaneous determination of benzene series and phthalates in water-borne adhesives for cigarette by gas chromatography tandem mass spectrometry

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