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H2SO4改性凹凸棒土在葡萄糖脱水制备5-羟甲基糠醛过程中的催化性能研究

杨凤丽 ,  梁国斌 ,  顾宇阳

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杨凤丽, 梁国斌, 顾宇阳. H2SO4改性凹凸棒土在葡萄糖脱水制备5-羟甲基糠醛过程中的催化性能研究[J]. 轻工学报, 2019, 34(1): 64-70. doi: 10.3969/j.issn.2096-1553.2019.01.009
引用本文: 杨凤丽, 梁国斌, 顾宇阳. H2SO4改性凹凸棒土在葡萄糖脱水制备5-羟甲基糠醛过程中的催化性能研究[J]. 轻工学报, 2019, 34(1): 64-70. doi: 10.3969/j.issn.2096-1553.2019.01.009
shu
YANG Fengli, LIANG Guobin and GU Yuyang. Study on catalytic performance of H2SO4 modified attapulgite in the process of dehydration of glucose to prepare 5-hydroxymethylfurfural[J]. Journal of Light Industry, 2019, 34(1): 64-70. doi: 10.3969/j.issn.2096-1553.2019.01.009
Citation: YANG Fengli, LIANG Guobin and GU Yuyang. Study on catalytic performance of H2SO4 modified attapulgite in the process of dehydration of glucose to prepare 5-hydroxymethylfurfural[J]. Journal of Light Industry, 2019, 34(1): 64-70. doi: 10.3969/j.issn.2096-1553.2019.01.009
shu

H2SO4改性凹凸棒土在葡萄糖脱水制备5-羟甲基糠醛过程中的催化性能研究

  • 江苏理工学院 化学与环境工程学院, 江苏 常州 213000

    • 作者简介: 杨凤丽(1984-),女,河南省开封市人,江苏理工学院讲师,博士,主要研究方向为固体酸催化生物质转化.;

  • 基金项目: 国家自然科学基金项目（21406020）；江苏省科技厅资助项目（BK20140257）

  • 中图分类号: O643.3

Study on catalytic performance of H2SO4 modified attapulgite in the process of dehydration of glucose to prepare 5-hydroxymethylfurfural

  • Technology School of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou 213000, China

  • Received Date: 2018-07-05

    CLC number: O643.3

  • 摘要: 对经H2SO4改性的凹凸棒土作为固体酸催化剂时，其在葡萄糖脱水制备生物基平台化合物5-羟甲基糠醛（HMF）过程中的催化性能进行研究，结果表明：凹凸棒土经不同浓度H2SO4改性后，Bronsted酸位点显著增加，当H2SO4浓度为1.0 mol/L时，同时具有较多的Bronsted酸位点和Lewis酸位点，此时催化葡萄糖脱水制备HMF效果最好，其收率可达46.6%.该催化剂在含水体系中表现出良好的稳定性，催化剂重复使用4次，HMF收率均在46%以上，活性未发生明显改变.
    Abstract: The attapulgite modified by H2SO4 was used as a solid acid catalyst to study the dehydration of the bio-based platform compound 5-hydroxymethylfurfural (HMF). The results showed that the Bronsted acid sites increased when the attapulgite was modified by different concentrations of H2SO4. When the concentration of H2SO4 was 1.0 mol/L, there were more Bronsted acid sites and Lewis acid sites. The preparation of HMF had the best effect, and the yield could reach 46.6%. The catalyst showed good stability in the aqueous system.Repeated use of the catalyst for 4 times, the HMF yield was above 46%, and the activity did not change significantly.
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杨凤丽, 梁国斌, 顾宇阳. H2SO4改性凹凸棒土在葡萄糖脱水制备5-羟甲基糠醛过程中的催化性能研究[J]. 轻工学报, 2019, 34(1): 64-70. doi: 10.3969/j.issn.2096-1553.2019.01.009
引用本文: 杨凤丽, 梁国斌, 顾宇阳. H2SO4改性凹凸棒土在葡萄糖脱水制备5-羟甲基糠醛过程中的催化性能研究[J]. 轻工学报, 2019, 34(1): 64-70. doi: 10.3969/j.issn.2096-1553.2019.01.009
shu
YANG Fengli, LIANG Guobin and GU Yuyang. Study on catalytic performance of H2SO4 modified attapulgite in the process of dehydration of glucose to prepare 5-hydroxymethylfurfural[J]. Journal of Light Industry, 2019, 34(1): 64-70. doi: 10.3969/j.issn.2096-1553.2019.01.009
Citation: YANG Fengli, LIANG Guobin and GU Yuyang. Study on catalytic performance of H2SO4 modified attapulgite in the process of dehydration of glucose to prepare 5-hydroxymethylfurfural[J]. Journal of Light Industry, 2019, 34(1): 64-70. doi: 10.3969/j.issn.2096-1553.2019.01.009
shu

H2SO4改性凹凸棒土在葡萄糖脱水制备5-羟甲基糠醛过程中的催化性能研究

    作者简介:杨凤丽(1984-),女,河南省开封市人,江苏理工学院讲师,博士,主要研究方向为固体酸催化生物质转化.
  • 江苏理工学院 化学与环境工程学院, 江苏 常州 213000
  • 收稿日期: 2018-07-05
基金项目:  国家自然科学基金项目（21406020）；江苏省科技厅资助项目（BK20140257）

摘要: 对经H2SO4改性的凹凸棒土作为固体酸催化剂时，其在葡萄糖脱水制备生物基平台化合物5-羟甲基糠醛（HMF）过程中的催化性能进行研究，结果表明：凹凸棒土经不同浓度H2SO4改性后，Bronsted酸位点显著增加，当H2SO4浓度为1.0 mol/L时，同时具有较多的Bronsted酸位点和Lewis酸位点，此时催化葡萄糖脱水制备HMF效果最好，其收率可达46.6%.该催化剂在含水体系中表现出良好的稳定性，催化剂重复使用4次，HMF收率均在46%以上，活性未发生明显改变.

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